The invention discloses environment-friendly polymer cement waterproof coating which is characterized in that the coating is prepared by mixing a liquid material and a powder material according to a mass ratio of 1:(0.9-2); the liquid material is prepared from the following raw materials in parts by weight: 40-60 parts of a vinyl-terminated waterborne polyurethane emulsion, 10-20 parts of 2,6-diaminopurine riboside/5,5-dimethyl-1,3-bis(oxiranyl methyl)imidazolidine-2,4-dione polycondensate, 1 to 3 parts of allyl 2-chloro-1,1,2-trifluoroethyl ether, 1 to 4 parts of a cosolvent, 2 to 5 parts ofan emulsifier, 0.1 to 0.3 part of a dispersing agent, 0.1 to 0.3 part of a defoaming agent, 1 to 3 parts of a coupling agent and 20-30 parts of water; the powder material comprises the following components in parts by weight: 30-40 parts of cement, 10-20 parts of palygorskite powder, 10-20 parts of cordierite powder, 5-10 parts of zircon powder, 5-10 parts of waste gypsum, 1-2 parts of lignin and0.3-0.6 part of a photoinitiator. The coating is excellent in comprehensive performance, good in performance stability, large in adhesive force, not easy to fall off, good in corrosion resistance, wear resistance and mechanical property, and safe and environment-friendly to use.