Method and device for separating surfactant from dilute solution

A technology for surface active substances and separation methods, applied in the field of separation of surface active substances, can solve the problems of lowering the concentration of active substances, affecting the efficiency of foam separation, and decreasing the driving force of mass transfer, achieving high foam separation, improving the retention rate, eliminating the The effect of bubble backmixing

Inactive Publication Date: 2011-11-09
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the back-mixing phenomenon in the foam column seriously affects the efficiency of foam separation.
At the same time, as the separation process progresses, the concentration of surface active substances in the bulk phase decreases, and the driving force for mass transfer decreases, resulting in a decrease in separation efficiency.
[0003] Membrane separation technology is also an energy-saving and environmentally friendly separation technology, but the main disadvantages in the membrane separation process are concentration polarization and membrane pollution.

Method used

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  • Method and device for separating surfactant from dilute solution
  • Method and device for separating surfactant from dilute solution

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] The tubular membrane module adopts an ultrafiltration membrane. At a pressure of 0.05MPa and a volume ratio of gas to liquid of 0.4:1, the aqueous solution of sodium dodecylbenzenesulfonate with a concentration of 25ppm is treated with a rejection rate of 64.9%.

Embodiment 2

[0022] The tubular membrane module adopts a nanofiltration membrane. At a pressure of 0.6MPa and a volume ratio of gas to liquid of 0.35:1, the aqueous solution of ammonium perfluorooctanoate with a concentration of 1200ppm is treated with a rejection rate of 98.1%.

Embodiment 3

[0024] The tubular membrane module adopts reverse osmosis membrane, under the pressure of 1.2MPa, the volume ratio of gas and liquid is 0.3:1, and the aqueous solution containing divalent lead ion with a concentration of 80ppm is complexed with sodium lauryl sulfate surfactant , The rejection rate reaches 99.9%.

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Abstract

The invention discloses a method and a device for separating surfactant from dilute solution. A raw material tank filled with dilute solution containing surfactant is connected from the bottom of a vertically arranged tubular membrane module via a solution pump, a first valve and a liquid flowmeter; a compressor is also connected from the bottom of the vertically arranged tubular membrane module via a second valve and a gas flowmeter; the top part of the vertically arranged tubular membrane module is connected to a foam collecting groove via a third valve; the middle part of the vertically arranged tubular membrane module is connected with a liquid storage tank. The adoption of the membrane and foam separation inner coupling method can reduce the concentration polarization of the membranesurface effectively, reduce membrane pollution, prolong the service life of the membrane, and simultaneously can eliminate back mixing phenomenon in the membrane and foam separation process, improve mass transfer rate of membrane and foam separation, and achieve separation efficiency. The rejection of the surfactant is 64.9% to 99.9%, thus saving more energy.

Description

technical field [0001] The invention relates to a separation method and device for surface active substances in dilute solution. Background technique [0002] Foam separation is an energy-saving and environmentally friendly separation technology that can be used to recover (or remove) surface-active substances in dilute solutions, or other substances that can combine with surface-active substances. However, the back-mixing phenomenon in the foam column seriously affects the efficiency of foam separation. At the same time, with the progress of the separation process, the concentration of surface active substances in the bulk phase decreases, and the driving force for mass transfer decreases, resulting in a decrease in separation efficiency. [0003] Membrane separation technology is also an energy-saving and environmentally friendly separation technology, but the main disadvantages in the membrane separation process are concentration polarization and membrane pollution. [...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D61/00B01D65/00C02F1/44
Inventor 南碎飞王斐窦梅
Owner ZHEJIANG UNIV
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