Production process for tail gas catalytic reducer

A production process and reducing agent technology, applied in the direction of physical/chemical process catalyst, organic compound/hydride/coordination complex catalyst, air quality improvement, etc., can solve the problem that ordinary urea cannot be used as tail gas catalytic reducer, etc., to achieve Guaranteed stability and controllability, simple operation, and low-cost effects

Active Publication Date: 2010-08-25
KELAS ENVIRONMENTAL PROTECTION TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved in the present invention is: Aiming at the defects that ordinary urea cannot be used as tail gas catalytic reducing agent and the existing domestic production process, a tail gas catalytic reducing agent production process is proposed to replace the crystallization process and produce tail gas catalytic reducing agent at low cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] In the present embodiment, the steps of preparing tail gas catalytic reducing agent-vehicle urea solution are as follows:

[0027] a. Dissolve, mix 1 ton of agricultural urea with 1.5 tons of ultrapure water with a resistivity of 13MΩ cm in a 3000L dissolving tank, heat up to 60°C, stir for 20min, and make a 50% urea solution;

[0028] b. Tank-type continuous purification, the above-mentioned urea solution is pumped to the continuous purification module of the tank. The purification module is composed of a 10μ bag filter, an activated carbon filter tower, and a 0.45μ precision filter element filter (PP material), all of which are sealed. Urea solution at 2m 3 The flow rate of / h passes through this purification module to obtain a clear filtrate of 0.22μ;

[0029] c. Ion exchange purification, pump the clarified filtrate to the ion exchange purification module, and use ion adsorption exchange to remove anions and cations in the urea aqueous solution. Among them, the an...

Embodiment 2

[0036] In the present embodiment, the steps of preparing tail gas catalytic reducing agent-vehicle urea solution are as follows:

[0037] a. Dissolving, mix 1 ton of industrial urea with 2 tons of ultrapure water with a resistivity of 13.7MΩ·cm in a 3000L dissolving tank, heat up to 70°C, stir for 20min, and make a 45% urea solution;

[0038] b. Tank continuous purification, pump the above urea solution to the continuous purification module of the tank. The purification module is composed of a 10μ bag filter, an activated carbon filter tower, and a 0.45μ precision filter element filter (PP material), all of which are sealed. solution at 3m 3 The flow rate of / h passes through this purification module to obtain a clear filtrate of 0.37μ;

[0039] c. Ion exchange purification, pump the clarified filtrate to the ion exchange purification module, and use ion adsorption exchange to remove anions and cations in the urea aqueous solution. Among them, the anion resin is 201×7 (717) ...

Embodiment 3

[0046] a. Dissolving, mix 1 ton of agricultural urea with 1.5 tons of ultrapure water with a resistivity of 14MΩ·cm in a 3000L dissolving tank, heat up to 75°C, stir for 20min, and make a 40% urea solution;

[0047] b. Tank continuous purification, pump the above urea solution to the continuous purification module of the tank. The purification module is composed of a 10μ bag filter, an activated carbon filter tower, and a 0.45μ precision filter element filter (PP material), all of which are sealed. solution at 2.5m 3 The flow rate of / h passes through this purification module to obtain a clear filtrate of 0.45μ;

[0048] c. Ion exchange purification, pump the clarified filtrate to the ion exchange purification module, and use ion adsorption exchange to remove anions and cations in the urea aqueous solution. Among them, the anion resin Purolie A600 anion exchange resin, the resin volume is 0.65m3 ; The cation resin is Purolie C100 cation exchange resin, the resin volume is 0.6...

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PUM

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Abstract

The invention relates to a production process for a tail gas catalytic reducer, in particular a production process for a tail gas catalytic reducer of vehicles, and belongs to the technical field of chemical engineering. In the production process, the continuous filtration and ion exchange technology is adopted; attributes of different impurities of the traditional urea are utilized; through continuous purification and exchange adsorption of metallic and nonmetallic ions, the common urea is subjected to vehicle-grade purification, so that the common urea is prepared into the high-purificationtail gas catalytic reducer through trough-type continuous purification and ion exchange process to ensure normal work of an SCR system. Compared with the traditional crystallization process, the production process has the advantages that: the innovative process method is adopted, chemical agents are not needed, zero emission is achieved, the production is continuous and the operation is simple. On the premise of ensuring low cost, energy conservation and environmental protection, the tail gas catalytic reducer, namely AUS32, with stable quality can be produced, and a foundation for supplying raw materials is laid for wide-range promotion of the domestic SCR system.

Description

technical field [0001] The invention relates to a production process of a catalytic reducing agent, in particular to a production process of a catalytic reducing agent for vehicle tail gas, and belongs to the technical field of chemical industry. Background technique [0002] At present, the tail gas catalytic reduction agent suitable for SCR technology-vehicle urea solution (AUS32) has high requirements on a series of indicators such as metal elements, while the content of metal elements in ordinary urea is relatively high, and direct use of ordinary urea aqueous solution will quickly make SCR System failure, or even irreversible damage to the entire system. Therefore, ordinary urea solution cannot meet the requirements of SCR technology as an exhaust gas catalytic reducer. In foreign countries, the preparation of tail gas catalytic reducing agent begins with the synthesis of urea, and various indicators are strictly controlled to ensure that the technical indicators of ta...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J31/02B01D53/94
CPCY02T10/24Y02A50/20Y02T10/12
Inventor 石俊峰秦建严军表
Owner KELAS ENVIRONMENTAL PROTECTION TECH CO LTD
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