Carrier for use in developer developing electrostatic image and developer using the carrier
A developer and electrostatic latent image technology, which is applied to the field of electrostatic image developer carriers, can solve the problems such as the change of the charge amount of the developer, the large amount of failed toners, the pollution of color toners, etc., and achieves good charging stability and difficulty in drawing amount. Changes, less effect of ineffective toner
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[0275] Below, examples and comparative examples are enumerated, and the present invention is more specifically described. In the following examples, although various limitations are made to constituent elements, types, combinations, etc., these are merely examples, and the present invention is not limited here. In addition, unless otherwise specified, "parts" herein represent parts by weight.
Synthetic example
[0277] [Synthesis of polyaddition polymer]
[0278] Hereinafter, the present invention will be specifically described using examples.
[0279] The weight-average molecular weight is a value converted to standard polystyrene using a gel purification system. The viscosity is a measured value of JIS-K2283 at 25°C. In addition, the non-volatile content is the weight measured after weighing 1 g of the coating agent composition in an aluminum container and heating at 150° C. for 1 hour, and calculated by the following formula.
[0280] Non-volatile components (%) = weight after heating × 100 / weight before heating
[0281] Synthesis examples of resins used in the present invention are shown below.
Synthetic example 1
[0283] 300 g of toluene was placed in a flask equipped with a stirring device, and the temperature was raised to 90° C. under a nitrogen stream. Next, add to it:
[0284] The chemical formula is CH 2 =CMe-COO-C 3 h 6 -Si(OSiMe 3 ) 3 (In the formula, Me is a methyl group) 84.4 g (200 mmol, manufactured by Thyraplane TM-0701T / CHISSO Corporation) of 3-methacryloyloxypropyl tris(trimethylsilyloxy) silanol represented;
[0285] 3-methacryloyloxypropyltrimethoxysilane 37.2g (150mmol);
[0286] Methyl methacrylate 65.0 g (650 mmol); and
[0287] 2,2'-diazobis-2-methylbutyronitrile 0.58g (3mmol);
[0288] The above mixture was added dropwise over 1 hour. Then add 2,2'-diazobis-2-methylbutyronitrile 0.06g (0.3mmol) solution in toluene 15g (2,2'-diazobis-2-methylbutyronitrile total amount 0.64 g=3.3 mmol), mixed at 90 to 100° C. for 3 hours to carry out radical polymerization to obtain an acrylic addition polymer. The weight average molecular weight of the obtained acrylic add...
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