Organic electroluminescent device
An electroluminescence device and a luminescence technology, which are applied in the direction of electric solid-state devices, electrical components, semiconductor devices, etc., can solve problems such as low luminous efficiency, environmental pollution, and short service life
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Embodiment 1-7
[0039] Embodiment 1 provides a white OLED device with three luminescent centers. The three light-emitting layers are red, blue, and green light-emitting layers, and the red phosphorescent light-emitting layer is made of hole-transporting host material NPB, doped with red dye Ir(piq) 3 ; The blue fluorescent layer adopts Bepp 2 ; The main body of the green phosphorescent layer adopts the same material Bepp as the blue fluorescent layer 2 , doped green dye Ir(ppy) 3 . The device structure of this embodiment is as follows:
[0040] ITO / NPB / NPB: Ir(piq) 3 / Bepp 2 / Bepp 2 : Ir(ppy) 3 / Bepp 2 / LiF / Al (1)
[0041] The specific preparation method for preparing an OLED device with the above structure (1) is as follows:
[0042] ① Clean the glass substrate 01 by using boiling detergent ultrasound and deionized water ultrasound, and place it under an infrared lamp for drying. Evaporate a layer of ITO on the glass as the anode 02, with a film thickness of 180nm;
[0043] ②Plac...
Embodiment 8-14
[0073] Compared with Examples 1-7, Examples 8-14 add a hole injection layer, and the hole transport material, the host material of the red phosphorescent layer and the phosphorescent dye are also different.
[0074] The device structure of embodiment 8-11:
[0075] ITO / HIL: HD / TAPC / TCTA: Ir(mdq) 2 (acac) / Bepp 2 / Bepp 2 : Ir(ppy) 3 / Bepp 2 / LiF / Al (3)
[0076] The device structure of embodiment 12-14 is respectively:
[0077] ITO / HIL: HD / TAPC / TAPC: Ir(mdq) 2 (acac) / Bepp 2 / Bepp 2 : Ir(ppy) 3 / Bepp 2 / LiF / Al (4)
[0078] ITO / HIL: HD / TAPC / TPD: Ir(mdq) 2 (acac) / Bepp 2 / Bepp 2 : Ir(ppy) 3 / Bepp 2 / LiF / Al (5)
[0079] ITO / HIL: HD / TAPC / NPB: Ir(mdq) 2 (acac) / Bepp 2 / Bepp 2 : Ir(ppy) 3 / Bepp 2 / LiF / Al (6)
[0080] The device structure of comparative examples 3-4:
[0081] ITO / HIL: HD / TAPC / TCTA: Ir(mdq) 2 (acac) / TCTA / Bepp 2 : BD / Bepp 2 / Bepp 2 : Ir(ppy) 3 / Bepp 2 / LiF / Al (7)
[0082] table 3
[0083]
Embodiment 15-20
[0085] Examples 15-20 have adopted different materials for the blue light-emitting layer and the electron transport layer, and the device structure is as follows:
[0086] ITO / HIL: HD / TAPC / TCTA: Ir(mdq) 2 (acac) / Blu-ray layer / Bepp 2 : Ir(ppy) 3 / Electron transport layer / LiF / Al (8)
[0087] Table 4
[0088]
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