Non-oxidized seawater bactericide and preparation method thereof

A fungicide and non-oxidizing technology, which is applied in the field of non-oxidizing seawater fungicide and its production, can solve the problems of chlorine gas irritating odor, strong corrosion and high toxicity, low cost of chlorine gas sterilization, and large amount of equipment maintenance. Achieve safe, economical, reliable operation, reduce work burden, and high safety performance

Active Publication Date: 2011-05-25
天津海得润滋食品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the use of chlorine gas for sterilization has many serious problems in application. The first is safety issues. Chlorine gas has a strong pungent odor and strong corrosiveness, is highly toxic, and is easy to leak. Once chlorine gas leaks, it will cause harm to the surrounding environment and personnel. great damage and harm
The second is the large amount of equipment maintenance. There must be two people on duty for each shift of chlorination equip

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0027] Example 1: A non-oxidizing seawater bactericide is prepared according to the weight ratio of the following formula components:

[0028] Polyhydroxypropyl polyene polyamine 30 kg,

[0029] Dodecyl triphenyl phosphorus chloride 10 kg,

[0030] 10 kg of quaternary ammonium dication,

[0031] 5 kg of isopropanol.

[0032] Production process method:

[0033] First add polyhydroxypropyl polyene polyamine and isopropanol into the reaction kettle, slowly heat to 80°C, stir for 30 minutes, then add dodecyltriphenylphosphine chloride, and keep the temperature at 80°C Continue to stir for 30 minutes, then add the quaternary ammonium salt dication, stir for 10 minutes, let it stand and cool naturally until the material temperature is 20-35°C.

example 2

[0034] Example 2: Non-oxidizing seawater bactericide, prepared according to the weight ratio of the following formula components:

[0035] Polyhydroxypropyl polyene polyamine 80 kg,

[0036] Dodecyl triphenyl phosphorus chloride 30 kg,

[0037] 20 kg of quaternary ammonium dication,

[0038] Isopropanol 10 kg.

example 3

[0039] Example 3: Non-oxidizing seawater bactericide, prepared according to the weight ratio of the following formula components:

[0040] 30-80 kg of polyhydroxypropyl polyene polyamine,

[0041] 10-30 kg of dodecyl triphenyl phosphorus chloride,

[0042] 10-20 kg of quaternary ammonium dication,

[0043] 5-10 kg of isopropanol.

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PUM

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Abstract

The invention discloses a non-oxidized seawater bactericide, which comprises the following components in part by weight: 30 to 80 parts of poly(hydroxypropyl) polyene polyamine, 10 to 30 parts of dodecyl triphenyl phosphorus chloride, 10 to 20 parts of dication quaternary ammonium salt and 5 to 10 parts of isopropanol. A method of a production process comprises the following steps of: adding the poly(hydroxypropyl) polyene polyamine and the isopropanol into a reaction kettle; slowly heating to 80 DEG C; stirring for 30 minutes; adding the dodecyl triphenyl phosphorus chloride; continuously stirring at the constant temperature of 80 DEG C for 30 minutes; adding the dication quaternary ammonium salt; stirring for 10 minutes; and standing and naturally cooling until material temperature is between 20 and 35 DEG C. The production process is simple, an operation process is simple and convenient, and safety performance is very high.

Description

technical field [0001] The invention belongs to fungicides, in particular to a non-oxidizing seawater fungicide and a preparation method thereof. Background technique [0002] In the Bohai Sea area, the seawater desalination supplementary water system and the generator set that uses seawater as circulating cooling water, the key problem is the adhesion and fouling of marine molluscs, especially the adhesion and fouling of "sea oysters". Sea oysters belong to hermaphroditic crustaceans. Its carapace forms a shell and is fixed on the substrate by mucus, and the substrate is also fixed on rocks or ship walls and pipe walls by mucus. This kind of mucus is calcite in protein, which is similar to colloid. According to analysis, it is composed of 24 kinds of amino acids and amino sugars. It won't be washed away either. Sea oysters are hermaphrodites, live in groups, and have a very strong reproductive capacity. When sea oysters find a relatively suitable place to live, they quick...

Claims

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Application Information

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IPC IPC(8): A01N57/34A01N33/08A01N33/12A01P1/00A01P9/00A01P17/00
Inventor 杜春元李瑞欣王仕龙周明莉马凯东刘伯东刘金英刘永智
Owner 天津海得润滋食品有限公司
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