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Method for preparing microcrystalline foam glass from ceramic polishing waste

A technology of ceramic polishing waste and microcrystalline foam glass, which is applied in glass molding, glass manufacturing equipment, manufacturing tools, etc., and can solve the problems of not being able to grasp the grain size and the uniformity of grain distribution.

Active Publication Date: 2012-05-02
LIAONING LIMENG HI TECH NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to process the operation, the foaming process is mainly used, and the microcrystallization process is supplemented, and the grain size and the uniformity of the grain distribution cannot be well grasped.

Method used

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  • Method for preparing microcrystalline foam glass from ceramic polishing waste

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0015] 1. Use ceramic polishing waste as the basic raw material, introduce other raw materials appropriately, and adjust the ingredients. Its silicon oxide content is 62.76%, sodium oxide content is 15.20%, and calcium oxide content is 6.5%. Then the batch was fired at 1350°C for 3 hours and then water quenched to obtain the basic glass.

[0016] 2. Grind the basic glass to 180 mesh, then add additives with a particle size of 200 mesh, and grind together for 10 minutes. The types and amounts of the additives are respectively: foaming agent calcium carbonate 0.5%, foam stabilizer sodium phosphate 5%, fluxing agent borax 5%.

[0017] 3. Raise the batch material to 900°C at a heating rate of 10°C / min, keep it warm for 15 minutes, and then lower it to room temperature with the furnace to obtain foam glass.

[0018] 4. Heat the prepared foam glass to 760°C at a heating rate of 10°C / min and keep it warm for 120 minutes; then raise the temperature to 890°C at a heating rate of 15°C...

example 2

[0021] 1. Use ceramic polishing waste as the basic raw material, introduce other raw materials appropriately, and adjust the ingredients. Its silicon oxide content is 61.57%, sodium oxide content is 15.22%, and calcium oxide content is 6.92%. Then the batch was fired at 1350°C for 3 hours and then water quenched to obtain the basic glass.

[0022] 2. Grind the basic glass to 180 mesh, then add additives with a particle size of 200 mesh, and grind together for 10 minutes. The types and dosages of the additives are respectively: 1.0% of calcium carbonate, 6% of sodium phosphate, and 6% of borax.

[0023] 3. Raise the batch material to 900°C at a heating rate of 10°C / min, keep it warm for 15 minutes, and then lower it to room temperature with the furnace to obtain foam glass.

[0024] 4. Heat the prepared foam glass to 740°C at a heating rate of 10°C / min, and keep it warm for 100 minutes; then raise the temperature to 890°C at a heating rate of 15°C / min, and keep it warm for 10...

example 3

[0027] 1. Use ceramic polishing waste as the basic raw material, introduce other raw materials appropriately, and adjust the ingredients. Its silicon oxide content is 59.78%, sodium oxide content is 15.24%, and calcium oxide content is 7.55%. Then the batch was fired at 1350°C for 3 hours and then water quenched to obtain the basic glass.

[0028] 2. Grind the basic glass to 180 mesh, then add additives with a particle size of 200 mesh, and grind together for 10 minutes. The types and amounts of the additives are respectively: 1.5% of calcium carbonate, 8% of sodium phosphate, and 8% of borax.

[0029] 3. Raise the batch material to 890°C at a heating rate of 10°C / min, keep it warm for 20 minutes, and then lower it to room temperature with the furnace to obtain foam glass.

[0030] 4. Heat the prepared foam glass to 730°C at a heating rate of 10°C / min and keep it warm for 80 minutes; then raise the temperature to 900°C at a heating rate of 15°C / min and keep it warm for 80 mi...

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Abstract

The invention discloses a method for preparing microcrystalline foam glass from ceramic polishing waste, and belongs to the field of resource comprehensive utilization and material preparation. The method comprises the following steps of: adjusting an appropriate proportioning point, firing the ceramic polishing waste serving as a basic material at a high temperature, and performing water quenching to obtain basic glass; adding an appropriate amount of additive, grinding, uniformly mixing, and performing specific heat treatment to prepare foam glass; and performing micro-crystallization heat treatment on the prepared foam glass, and performing precision annealing to obtain the microcrystalline foam glass. The method has the advantages of low production cost, high product quality, no secondary pollution and the like, and is easy to operate during production; and the volume density of a product is only about 2 / 3 of that of the common foam microcrystalline glass, and the product has other high properties.

Description

technical field [0001] The invention belongs to the technical field of resource comprehensive utilization and material preparation, and in particular relates to a method for preparing microcrystalline foam glass by using ceramic polishing waste. Background technique [0002] Microcrystalline foam glass consists of three parts: glass phase, crystal and pores. In the glass phase matrix with a large number of pores evenly distributed, there are a large number of tiny crystals distributed, so that the glass and the crystal network are linked together to form a glass crystal interweaving structure. It is a new multifunctional material with superior performance. Most of these multifunctional materials use waste glass as the main raw material to prepare microceramic foam glass. [0003] Since a small amount of phase-separated oxides in ceramic polishing waste is an excellent crystal nucleating agent, in recent years, many researchers have tried to prepare microceramic foam glass f...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C11/00C03C6/00C03B19/08
Inventor 马明龙韩绍娟许壮志薛健张明高琳琳
Owner LIAONING LIMENG HI TECH NEW MATERIAL