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Treatment method for acidic organic chemical wastewater with high COD (chemical oxygen demand) and high sulfate radical concentration

A technology of organic chemical industry and wastewater treatment, applied in the field of environmental engineering and microbiology, can solve the problems that cannot be promoted and widely used, and achieve the effect of easy transformation, less process and cost reduction

Inactive Publication Date: 2011-09-21
ZHEJIANG UNIV
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AI Technical Summary

Problems solved by technology

Although the above technologies have made valuable explorations on the treatment of wastewater with high organic concentration containing high sulfate radicals, they are still unable to be promoted and widely used due to their own technical limitations.

Method used

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  • Treatment method for acidic organic chemical wastewater with high COD (chemical oxygen demand) and high sulfate radical concentration

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Embodiment 1

[0026] Such as figure 1 Shown is a schematic flow chart of wastewater treatment using the method of the present invention.

[0027] A chemical factory is mainly engaged in the production of cosmetic raw materials, lubricating oil additives and other products. The main pollutants in its wastewater are organic substances such as alcohols, fatty acid sodium salts and fatty acid esters. Production wastewater has complex components, high pollution load and acidity. The original process uses caustic soda to adjust the pH, which is costly, and has a large inhibition on the anaerobic stage, and the effluent is unqualified.

[0028] Adopt method of the present invention, press Ca(OH) 2 :H + Add Ca(OH) to chemical wastewater with a molar ratio of 1:2 2 , stirring the reaction, adjusting the pH value to 6.7-7.5, removing most of the sulfate and H + , after standing still for one hour, the precipitation was removed, and the supernatant was transported to the anaerobic reactor. Contr...

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Abstract

The invention discloses a treatment method for acidic organic chemical wastewater with high COD (chemical oxygen demand) and high sulfate radical concentration, which mainly comprises the following steps: Ca(OH)2 pretreatment, anaerobic treatment, two-stage aerobic treatment, etc. After Ca(OH)2 pretreatment of the acidic organic chemical industry wastewater to remove most of sulfate radicals and H<+>, wastewater treatment microorganism main body and operation parameter factors are controlled so as to form an anaerobic wastewater treatment method with anaerobic bacteria being dominant and an aerobic aeration treatment method mainly using halophilic and haloduric aerobic microorganism treatment, and the anaerobic wastewater treatment method and the aerobic aeration treatment method are especially suitable for treating organic chemical industry wastewater with high COD, high sulfate radical concentration and low pH value.

Description

technical field [0001] The invention belongs to the field of environmental engineering and microorganism technology, in particular to a method for treating acidic organic chemical waste water with high COD and high concentration of sulfate radicals by combining chemistry and biology. Background technique [0002] A large amount of high-concentration sulfate wastewater exists in mining, metallurgy, food and pharmaceutical industries. If the wastewater is directly discharged into the water body without treatment, it will cause a series of hazards, such as: ① Corrosion of pipes. In all kinds of water pipes, it will directly reduce the resistance of water and increase corrosion, and indirectly affect the circulation of sulfate-reducing bacteria and the spread of biological corrosion; ② Excessive sulfate radicals can cause foul odor in the water body and affect the sense of water Characters and its use; ③Excessive sulfate radicals are not conducive to crop growth and salinize the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14C02F3/30
Inventor 吴敏郑刚张勇朱旭芬
Owner ZHEJIANG UNIV
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