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Resin special for anchoring agent and preparation method thereof

An anchoring agent and resin technology, applied in the field of unsaturated polyester resin and its preparation, can solve the problems of short storage period, slow strength development, poor high temperature resistance, etc., and achieve good thermal stability, fast strength development, and stability Good results

Active Publication Date: 2011-10-12
淮南舜天合成材料有限责任公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The application of resin anchoring agent in coal mines in my country has a history of more than 50 years. With the country's high attention to coal mine safety and the continuous increase in the amount of anchoring agent, the scope of application continues to expand, and higher and higher requirements are put forward for the performance of anchoring agent. , There are many problems in using traditional general-purpose unsaturated resin as anchoring agent products: such as the short storage period of anchoring agent, it can only be stored for 3-6 months at room temperature, especially in summer, some storage periods are less than 2 months The cement part of the anchoring agent will harden; the gel time of the anchoring agent is slow; the gel time is greatly affected by the temperature; the final strength after curing is low, and the early strength development is also relatively slow. The resin has poor adaptability to stone powder and poor adhesion. It is also poor, the amount of stone powder is low, the high temperature resistance is poor, and the price of resin is also high.

Method used

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  • Resin special for anchoring agent and preparation method thereof
  • Resin special for anchoring agent and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0015] A preparation method of special resin for anchoring agent, comprising the following steps:

[0016] (1) Put terephthalic acid, abietic acid, oxalic acid, glycerin, diethylene glycol, and catalyst into the reaction kettle according to the weight ratio of raw materials, stir, and electric heating to dissolve the raw materials, heat to 160 ° C for 1 hour, and continue to heat up , the temperature rise rate is controlled at no more than 15°C per hour, and the column temperature does not exceed 105°C. When the material rises to 230°C and the column temperature is 70-80°C, measure the acid value. If the acid value is ≤10mgKOH / g, proceed to the next step;

[0017] (2) Cool down to 200°C, put maleic anhydride and fumaric acid into the reactor according to the weight ratio, slowly raise the temperature, the heating rate is controlled at no more than 15°C per hour, the column temperature does not exceed 105°C, when the material rises to 220°C When the column temperature is 75-80°...

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Abstract

The invention discloses a resin special for an anchoring agent and a preparation method thereof. The resin is mainly prepared from terephthalic acid, fumaric acid, abietic acid, maleic anhydride, oxalic acid, glycerol, diglycol, a catalyst, a polymerization inhibitor, a stabilizing additive and styrene according to a certain proportion. A special resin which is most suitable to serve as an anchoring agent product is provided through means such as the adoption of a reasonable production process design formula, the adding of some chemical additives and the like. The gel time of the resin is short and is slightly affected by the temperature, the final curing strength is high, the early strength is quickly developed, the storage stability is high, the resin has high adhesion to mountain flourand has high adaptability to the mountain flour, and the doping amount of the mountain flour is large; and the cost is low, and each ton of the resin is 10 to 20 percent cheaper than each ton of an ordinary unsaturated resin.

Description

technical field [0001] The invention belongs to the technical field of unsaturated polyester resin, and in particular relates to an unsaturated polyester resin used as an anchoring agent and a preparation method thereof. Background technique [0002] Anchoring agent is the most widely used adhesive anchoring material in modern times. It is composed of high-performance unsaturated polyester resin and curing agent, accelerator, filler and other chemical additives. The application of resin anchoring agent in coal mines in my country has a history of more than 50 years. With the country's high attention to coal mine safety and the continuous increase in the amount of anchoring agent, the scope of application continues to expand, and higher and higher requirements are put forward for the performance of anchoring agent. , There are many problems in using traditional general-purpose unsaturated resin as anchoring agent products: such as the short storage period of anchoring agent, i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/01C08G63/676C08G63/78C04B26/18
Inventor 王雪礼朱宗君赵剑
Owner 淮南舜天合成材料有限责任公司
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