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Reaction-regeneration device for preparing low-carbon olefin from methanol

A low-carbon olefin and regeneration device technology, which is applied in the direction of ethylene production, hydrocarbon production from oxygen-containing organic compounds, biological raw materials, etc., can solve the problems of long start-up period of the device and large catalyst loss, etc., to shorten the start-up period and increase selectivity , fast drying effect

Active Publication Date: 2014-05-28
CHINA PETROLEUM & CHEM CORP +1
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  • Claims
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Problems solved by technology

[0007] The technical problem to be solved by the present invention is the problem of relatively large catalyst loss and long device start-up period in the prior art

Method used

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  • Reaction-regeneration device for preparing low-carbon olefin from methanol

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Embodiment 1

[0018] Such as figure 1In the methanol-to-light olefin reaction-regeneration system shown, the reaction zone of the reactor is a fast fluidized bed with a gas phase velocity of 1.25 m / s, the regeneration zone of the regenerator is a dense bed with a gas phase velocity of 0.6 m / s, and the catalyst It is SAPO-34 molecular sieve, the feed rate of methanol is 4.2 tons / hour, fuel gas is fed into the two auxiliary combustion chambers to ignite to heat the air, the air is heated and enters the reactor and regenerator, after the drying of the lining, the reaction The air in the reactor is cut out, the auxiliary combustion chamber of the reactor is disabled, a blind plate is added to the outlet of the auxiliary combustion chamber, and the reactor is cut into the steam heated by the auxiliary heating furnace. The steam temperature is about 380°C, and the reactor temperature can be controlled at 250°C. At the same time, heat the regenerator to about 450°C, transfer the catalyst from the ...

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Abstract

The invention provides a reaction-regeneration device for preparing low-carbon olefin from methanol. The device mainly solves the problems of high catalyst loss and long driving cycle of the device in the prior art. The reaction-regeneration device for preparing the low-carbon olefin from the methanol comprises a reactor 18, a regenerator 23, a reactor auxiliary combustion chamber 5, a regenerator auxiliary combustion chamber 30, a reactor tertiary cyclone separator 36, a regenerator tertiary cyclone separator 33, a reactor external heater 14, a regenerator external heater 27 and a degassing tank 21; the reactor 18 is connected with the regenerator 23 through a regenerating oblique pipe 10; the degassing tank 21 is connected with the reactor external heater 14 through a regenerated catalyst delivery pipe 8; the lower part of the reactor external heater 14 is provided with a catalyst outlet connected with the reactor 18; a product gas outlet 19 is connected with the reactor tertiary cyclone separator 36; and a flue gas outlet 24 is connected with the regenerator tertiary cyclone separator 33. According to the technical scheme, the problems are well solved; and the device can be used for industrial production of the low-carbon olefin.

Description

technical field [0001] The invention relates to a methanol-to-low-carbon olefin reaction-regeneration device. technical background [0002] Low-carbon olefins, namely ethylene and propylene, are two important basic chemical raw materials, and their demand is increasing. Generally, ethylene and propylene are produced through petroleum routes, but due to the limited supply and high price of petroleum resources, the cost of producing ethylene and propylene from petroleum resources continues to increase. In recent years, people have begun to vigorously develop the technology of converting alternative raw materials into ethylene and propylene. Among them, an important class of alternative raw materials for the production of light olefins are oxygenates, such as alcohols (methanol, ethanol), ethers (dimethyl ether, methyl ethyl ether), esters (dimethyl carbonate, methyl formate Esters), etc., these oxygenated compounds can be converted from coal, natural gas, biomass and other e...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07C1/20C07C11/04C07C11/06
CPCY02P20/584Y02P30/20Y02P30/40
Inventor 齐国祯张惠明杨远飞俞志楠
Owner CHINA PETROLEUM & CHEM CORP
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