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Thin film solid lithium ion secondary battery and manufacturing method thereof

A secondary battery and solid-state lithium technology, applied in the field of lithium-ion batteries, can solve problems such as reduced activity, deterioration of battery characteristics, and durability problems

Active Publication Date: 2011-12-28
MURATA MFG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

That is, in the case where Li is deposited on the metal surface on the negative electrode side, Li grows in the form of needles, activity decreases, battery characteristics deteriorate rapidly, and there are problems with durability

Method used

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  • Thin film solid lithium ion secondary battery and manufacturing method thereof
  • Thin film solid lithium ion secondary battery and manufacturing method thereof
  • Thin film solid lithium ion secondary battery and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach (1

[0093] figure 1 is a view illustrating a schematic structure of a solid-state lithium ion battery in an embodiment of the present invention. figure 1 (A) is a floor plan, figure 1 (B) is a X-X cross-sectional view, figure 1 (C) is a Y-Y cross-sectional view.

[0094] Such as figure 1 As shown, the solid-state lithium ion battery has a positive electrode side current collector film 30, a positive electrode active material film 40, a solid electrolyte film 50, a negative electrode side current collector protection film 68, and a negative electrode side current collector film 70 are sequentially formed on a substrate A laminate on (organic insulating substrate) 10 . A total protective film 80 made of, for example, an ultraviolet curing resin is formed to entirely cover the laminated body.

[0095] figure 1The battery film structure shown in is substrate / positive electrode side current collector film / positive electrode active material film / solid electrolyte film / negati...

Embodiment approach (2

[0099] figure 2 is a view illustrating a schematic structure of a solid-state lithium ion battery in an embodiment of the present invention. figure 2 (A) is a floor plan, figure 2 (B) is an X-X cross-sectional view.

[0100] figure 2 is a view illustrating a schematic structure of a solid-state lithium ion battery in Embodiment (2) of the present invention. figure 2 (A) is a floor plan, figure 2 (B) is an X-X cross-sectional view.

[0101] Such as figure 2 As shown, the solid-state lithium ion battery includes a laminate composed of a positive electrode side current collector film 30 and a positive electrode active material film 40 formed on a substrate (organic insulating substrate) 10 and a negative electrode side current collector film 70 and a negative electrode side collector film. A laminated body composed of an electrical protection film 68 . The solid electrolyte film 50 is formed to entirely cover the above-mentioned two laminated bodies arranged in line...

Embodiment approach (3

[0105] image 3 is a view illustrating a schematic structure of a solid-state lithium ion battery in an embodiment of the present invention. image 3 (A) is a floor plan, image 3 (B) is a X-X cross-sectional view, image 3 (C) is a Y-Y cross-sectional view.

[0106] Such as image 3 As shown, the solid-state lithium ion battery has an inorganic insulating film 20 formed on the face of a substrate (organic insulating substrate) 10 . The solid state lithium ion battery has a positive electrode side current collector film 30, a positive electrode active material film 40, a solid electrolyte film 50, a negative electrode side current collector protective film 68, and a negative electrode side current collector film 70 are sequentially formed on the inorganic insulating film 20. layer on top. A total protective film 80 made of, for example, an ultraviolet curing resin is formed to entirely cover the laminated body and the inorganic insulating film 20 .

[0107] image 3 The...

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Abstract

The present invention discloses a high-performance and inexpensive thin-film solid-state lithium ion secondary battery and a method of manufacturing the battery, which can be charged and discharged in the air and can be stably manufactured with a satisfactory yield. The thin-film solid-state lithium ion secondary battery has: an electrically insulating substrate (10) formed of an organic resin; an inorganic insulating film arranged on a surface of the substrate; a positive electrode side current collector film (30); a positive electrode active material film (40) ; a solid electrolyte membrane (50); a negative electrode side current collector protective film (68); and a negative electrode side current collector film (70). In this thin-film solid-state lithium ion secondary battery, the positive-electrode-side current collector film and / or the negative-electrode-side current collector film are formed on the surface of the inorganic insulating film. The negative electrode side current collector protection film is formed of a conductive oxide including at least any one of Sn oxide, In oxide, and Zn oxide, and keeps the total amount of lithium related to charge and discharge substantially constant. The thickness of the negative electrode side current collector protection film is greater than or equal to 2 nm and less than or equal to 22 nm. The thickness of the inorganic insulating film is greater than or equal to 5 nm and less than or equal to 500 nm. The inorganic insulating film contains at least one of oxides, nitrides, and sulfides containing any one of Si, Al, Cr, Zr, Ta, Ti, Mn, Mg, and Zn.

Description

technical field [0001] The present invention relates to a lithium-ion battery, in particular to a thin-film solid-state lithium-ion secondary battery, wherein all layers formed on a substrate and constituting the battery can be formed by a dry process, and to a manufacturing method thereof. Background technique [0002] Lithium-ion secondary batteries have higher energy density and better charge-discharge cycle characteristics than other secondary batteries, so lithium-ion secondary batteries are widely used as power sources for mobile electronic devices. In a lithium ion secondary battery using an electrolytic solution as an electrolyte, reduction in size and thickness thereof is limited. Accordingly, polymer batteries using gel electrolytes and thin-film solid-state batteries using solid electrolytes have been developed. [0003] In polymer batteries using gel electrolytes, size and thickness reductions are easier to achieve than in batteries using electrolyte solutions. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0585H01M2/02H01M4/13H01M4/485H01M4/66H01M10/052H01M10/0562H01M50/548H01M50/557
CPCH01M10/0585H01M4/1397H01M10/0525H01M4/667H01M4/1391H01M4/382H01M2/0212H01M4/131Y02E60/122H01M4/134H01M4/136H01M6/40H01M10/0562H01M2004/027Y02E60/10H01M50/557Y02P70/50H01M50/548H01M4/66H01M10/052
Inventor 猿飞裕一日隈弘一郎高原克典守冈宏之古谷龙也
Owner MURATA MFG CO LTD