Metal ceramic seal ring material and preparation method thereof
A technology of cermets and sealing rings, which is applied in the field of powder metallurgy and cermets, can solve the problems of adverse effects on corrosion resistance, expensive additives, high brittleness, etc., to improve mechanical properties, avoid the formation of brittle phases, and achieve low density. Effect
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example 1
[0012] Example 1: Prepare molybdenum-free cermets by weighing raw materials by weight percentage, (W, Cr) C with a particle size of 1.3 μm accounts for 5%, (W, Ti) C with a particle size of 2.5 μm accounts for 10%, and (W, Ti) C with a particle size of 1.5 μm Ni accounts for 10%, Co with a particle size of 1.2μm accounts for 6%, and the rest is Ti(C,N) with a particle size of 1.8μm. The C:N atomic ratio in Ti(C,N) powder is 7:3, (W ,Cr) The weight ratio of W:Cr in C powder is 98:2, and the weight ratio of WC:TiC in (W,Ti)C powder is 7:3. During the ball milling process, the (W,Cr)C and (W,Ti)C powders are first added to the ball mill, and oleic acid and PEG6000 molding agent are added at the same time, and ball milled for 24 hours; then Ni, Co, Ti(C,N) powders are added Then ball mill for 36 hours, the ball milling medium is absolute ethanol, the addition amount is 280ml, the addition amount of PEG6000 forming agent is 2wt%, the addition amount of oleic acid is 1wt%, the ball ...
example 2
[0013]Example 2: Prepare molybdenum-free cermets by weighing raw materials by weight percentage, (W, Cr) C with a particle size of 0.8 μm accounts for 6%, (W, Ti) C with a particle size of 2.0 μm accounts for 15%, and (W, Ti) C with a particle size of 1.6 μm Ni accounts for 8%, Co with a particle size of 1.2 μm accounts for 15%, and the rest is Ti (C, N) with a particle size of 1.9 μm. The atomic ratio of C:N in Ti (C, N) powder is 7:3, (W ,Cr) The weight ratio of W:Cr in C powder is 99:1, and the weight ratio of WC:TiC in (W,Ti)C powder is 7:3. During the ball milling process, the (W,Cr)C and (W,Ti)C powders were first added to the ball mill, and oleic acid and PEG6000 forming agent were added at the same time, and ball milled for 16 hours; then Ni, Co, Ti(C,N) powders were added Then ball mill for 48 hours, the ball milling medium is absolute ethanol, the addition amount is 450ml, the addition amount of PEG6000 molding agent is 5wt%, the addition amount of oleic acid is 0.5w...
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