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Preparation method of lead-acid storage battery anode for electric bike

A technology of lead-acid batteries and electric bicycles, applied in the direction of lead-acid battery electrodes, etc., can solve the problems that are difficult to meet the long-life requirements of batteries, affect the deep charge and discharge performance of batteries, intergranular corrosion of anode corrosion layers, etc., and achieve excellent The effects of life cycle capability, good maintenance-free performance, and stable electrochemical performance

Inactive Publication Date: 2012-04-04
徐艳
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Lead-antimony alloys have good mechanical casting properties and deep charge and discharge capabilities, but Sb 3+ Ions are easy to migrate between the separators and deposit on the surface of the negative electrode, thereby reducing the hydrogen evolution overpotential on the negative electrode, making the battery very easy to gas and lose water when it is charged or overcharged, which will cause the battery to dry up prematurely and terminate its life; Although the lead-calcium alloy has the advantages of small gas loss and water loss, and the battery does not need to add water for maintenance, but during the charging process, a layer of high-resistance anode corrosion layer and severe intergranular corrosion are easily grown on the surface of the positive grid.
As a result, the deep charge and discharge performance of the battery is greatly affected, and the service life of the battery is shortened.
Although the above two alloys have their own advantages, they are difficult to meet the long-life requirements of the battery. It is urgent to develop a new type of alloy that can not only eliminate the antimony that is easy to break and lose water, but also avoid the defects that calcium is easy to produce a high-resistance corrosion layer. Antimony-free, calcium-free positive grid alloy

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A method for preparing a positive electrode of an electric bicycle lead-acid battery, the positive electrode is composed of the following components in weight percentage: Sn 1.2, Al 0.6, Bi 0.01, Ag 0.08, In 0.02, Cu 0.10, and the balance is Pb; The preparation method is:

[0016] (1) Put Sn, Ag, In and Cu into a crucible, heat to 1130°C to melt, stir evenly, pour into an ingot mold, and obtain an ingot for later use after cooling;

[0017] (2) Smelt Al and Bi in a lead pot, melt at 640°C and keep warm; put the above ingot into the lead pot, stir evenly after the ingot is melted, and let it stand for 20 minutes;

[0018] (3) Adjust the pouring temperature to 570°C, and pour into the grid mold to form a grid.

Embodiment 2

[0020] A method for preparing a positive electrode of an electric bicycle lead-acid battery, the positive electrode is composed of the following components in weight percentage: Sn 1.6, Al 0.2, Bi 0.02, Ag 0.02, In 0.05, Cu 0.05, and the balance is Pb; The preparation method is:

[0021] (1) Put Sn, Ag, In and Cu into a crucible, heat to 1150°C to melt, stir evenly, pour into an ingot mold, and obtain an ingot for later use after cooling;

[0022] (2) Smelt Al and Bi in a lead pot, melt at 660°C and keep warm; put the above ingot into the lead pot, stir evenly after the ingot is melted, and let it stand for 15 minutes;

[0023] (3) Adjust the pouring temperature to 580°C, and pour into the grid mold to form a grid.

Embodiment 3

[0025] A preparation method of a positive electrode of an electric bicycle lead-acid battery, the positive electrode is composed of the following components in weight percentage: Sn 1.3, Al 0.5, Bi 0.012, Ag 0.06, In 0.03, Cu 0.09, and the balance is Pb; The preparation method is:

[0026] (1) Put Sn, Ag, In and Cu into a crucible, heat to 1140°C to melt, stir evenly, pour into an ingot mold, and obtain an ingot for later use after cooling;

[0027] (2) Smelt Al and Bi in a lead pot, melt at 650°C and keep warm; put the above ingot into the lead pot, stir evenly after the ingot is melted, and let it stand for 118 minutes;

[0028] (3) Adjust the pouring temperature to 575°C, and pour into the grid mold to form a grid.

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PUM

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Abstract

The invention discloses a preparation method of a lead-acid storage battery anode for an electric bike. The lead-acid storage battery anode comprises the following components in percent by weight: 1.2-1.6 percent of Sn, 0.2-0.6 percent of Al, 0.01-0.02 percent of Bi, 0.02-0.08 percent of Ag, 0.02-0.05 percent of In, 0.05-0.10 percent of Cu and the balance of Pb. The preparation method comprises the steps of: 1, placing the Sn, the Ag, the In and the Cu into a crucible, heating to reach the temperature of 1130-1150 DEG C for melting, uniformly stirring, pouring into an ingot mould, cooling to obtain an ingot casting for later use; 2, smelting the Al and the Bi in a lead pan, melting at a temperature of 640-660 DEG C and preserving the temperature, placing the ingot casting into the lead pan, uniformly stirring after the ingot casting is molten, standing for 15-20min; and 3, regulating the pouring temperature to be 570-580 DEG C, and pouring into a board gate mould to form a board gate.

Description

technical field [0001] The invention relates to the field of electric bicycles, in particular to a method for preparing a positive electrode of a lead-acid storage battery for electric bicycles. Background technique [0002] With the shortage of energy, electric bicycles and hybrid vehicles are more and more popular in the market, but the charging and discharging performance and deep cycle performance of batteries are not very satisfactory at present. In this regard, countries all over the world are researching and developing high-performance batteries to solve problems such as reliability, maintainability, deep cycle, and corrosion resistance of lead-acid batteries. [0003] In theory, electric bicycles can choose fuel cells, lithium batteries, nickel-metal hydride batteries, lead-acid batteries, etc. as power sources. The advantages of lead-acid batteries are: (1) low cost, in line with popular requirements; (2) large-scale production, relatively mature technology; (3) no...

Claims

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Application Information

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IPC IPC(8): H01M4/16
CPCY02E60/126Y02E60/10
Inventor 徐艳
Owner 徐艳
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