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Disperse yellow dye mixture resistant to light and acid-base and improved in sublimation fastness

A technology of dye mixture and sublimation fastness, which is applied in organic dyes, dyeing methods, textiles and papermaking, etc. It can solve the problems of decreased quality of dyed finished products, inconsistent sublimation fastness, and affecting the quality of finished products, so as to improve light fastness, good Effects of light fastness and stable color development

Inactive Publication Date: 2012-04-11
WUJIANG LVZHOU DYESTUFF CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In the long-term practice of fabric printing and dyeing, the inventor has noticed that the ternary color dyes used in the dyeing of polyester fibers and fabrics in the past have the defects of poor light fastness, poor acid and alkali resistance and inconsistent sublimation fastness.
For example, a ternary color dye with disperse blue 2BLN (C.I. disperse blue 56), disperse yellow E-RG (a mixture of C.I. disperse yellow 54 + C.I. disperse orange 25), and disperse red 3B (C.I. disperse red 60), The light fastness is tested according to the European standard. After 48 hours of exposure, both Disperse Blue 2BLN and Disperse Red 3B can reach level 4, while Disperse Yellow E-RG can only reach level 2.5-3; the pH value of Disperse Blue 2BLN is suitable for 3-8, the pH range of Disperse Yellow E-RG value is 3-8, and the pH range of Disperse Red 3B is 3-8; the sublimation fastness is tested according to national standards (180 degrees, 2kg pressure, hot pressing for 30 seconds), Disperse blue 2BLN is grade 3.5, disperse yellow E-RG is grade 2, and disperse red 3B is grade 3. This will lead to serious color changes due to differences in dye sublimation fastness during heat setting after dyeing of medium and light colors, resulting in dyeing The quality of the finished product decreases, affecting the quality of the finished product

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Example 1: A kind of disperse yellow dye mixture with improved sublimation fastness to light and acid and alkali

[0034] (1) Dye mixture formula:

[0035] The dye part consists of 85 parts (parts by mass) of C.I. Disperse Yellow 33 and 15 parts (parts by mass) of C.I. Disperse Yellow 163. Then, the dyestuff and the auxiliary agent are mixed in a ratio of 1:1, wherein the auxiliary agent is usually a dispersant and a diffusing agent, and the dispersing agent and the diffusing agent are generally necessary. The dispersant usually chooses domestic sodium lignosulfonate type B or / and imported sodium lignosulfonate 85A. The diffusing agent usually chooses domestic MF or / and NNO. The ratio between the dispersant and the diffusing agent can be determined according to the quality standard of the finished disperse dye mixture. Each manufacturer can optimize the combination in specific applications, which is relatively flexible.

[0036] (2) Preparation of dye mixture

[003...

Embodiment 2

[0038] Embodiment 2: a kind of sublimation fastness-improving disperse yellow dye mixture with light resistance and acid and alkali resistance

[0039] (1) Dye mixture formula:

[0040] The dye part consists of 80 parts (parts by mass) of C.I. Disperse Yellow 33 and 20 parts (parts by mass) of C.I. Disperse Yellow 163. Then, it is mixed according to the ratio of dye and auxiliary agent 1:1, wherein, the content of auxiliary agent is the same as that in Example 1, and will not be repeated here.

[0041] (2) The preparation method is the same as that of Example 1.

Embodiment 3

[0042] Embodiment 3: a kind of sublimation fastness improvement type disperse yellow dye mixture with light resistance, acid and alkali resistance

[0043] (1) Dye mixture formula:

[0044] The dye part consists of 75 parts (parts by mass) of C.I. Disperse Yellow 33 and 25 parts (parts by mass) of C.I. Disperse Yellow 163. Then, it is mixed according to the ratio of dye and auxiliary agent 1:1, wherein, the content of auxiliary agent is the same as that in Example 1, and will not be repeated here.

[0045] (2) The preparation method is the same as that of Example 1.

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PUM

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Abstract

A disperse yellow dye mixture resistant to light and acid-base and improved in sublimation fastness is formed by mixing a dye part and an auxiliary part, wherein the dye part is composed of two dyes in the following mass percentage contents: (1) 50-85% dye in accordance with a chemical general formula (I), wherein R in the formula (I) represents hydrogen or an alkyl having less than or equal to 4 carbon atoms; and (2) 15-50% dye in accordance with a chemical structural formula (II).

Description

technical field [0001] The invention relates to a disperse dye suitable for dyeing polyester fibers or fabrics. In particular, it relates to a disperse yellow dye mixture whose sublimation fastness to light and acid and alkali is improved to grade 3.5. This disperse yellow dye can be used as one of the basic three primary colors. It forms a group of three primary color dyes with other disperse red and disperse blue with the same light resistance, acid and alkali resistance and sublimation fastness for color matching. When dyeing fibers and fabrics, it solves the problem of color change of polyester fibers or fabric clothing under sunlight due to the performance defects of the dye itself, and also solves the problem of color deviation during dyeing and processing, and also solves the problem of sublimation fastness due to dye formulations. Inconsistencies leading to severe shade changes during heat setting finishing. In addition, this disperse yellow dye mixture can be used d...

Claims

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Application Information

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IPC IPC(8): C09B67/22C09B67/38D06P1/19D06P1/18D06P3/54
Inventor 蒋金根
Owner WUJIANG LVZHOU DYESTUFF CHEM
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