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Cationization composite modification method of pure cotton fabric

A pure cotton fabric, cationization technology, applied in the direction of dyeing, plant fiber, textiles and paper making, can solve the problem of reactive dye dyeing rate (low K/S value, etc.), to achieve the improvement and protection of the environment, Reduced need for salt, high usability effect

Inactive Publication Date: 2012-06-20
SHAOXING UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Such as adopting quaternary ammonium salt compounds containing chlorohydrin groups or quaternary ammonium salt compounds containing s-triazine groups to carry out cationic modification treatment on cotton fibers, however, although the above-mentioned prior art has realized the salt-free or low Salt dyeing, but low reactive dye uptake (K / S value)

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Example 1: Cotton fabric is modified by using a quaternary ammonium salt modifier.

[0022] The bath ratio of cationic treatment solution is 1:40, the concentration of quaternary ammonium salt modifier is 10.00% (o.w.f), the concentration of ethanol is 7.00% (o.w.f), the dosage of NaOH is 10.00% (o.w.f), and the cotton fabric is treated for 40 minutes under constant temperature conditions of 65°C , the obtained cotton fabric was dyed with 1% (o.w.f) reactive red 3BR at a liquor ratio of 1:40, dyed at a constant temperature of 85°C*30min, and fixed at 85°C*30min. K / S Value, which is obtained by dyeing the non-cationized modified cotton fabric under the same dyeing conditions with 22g / L sodium anhydride and other same dyeing conditions K / S The value has increased by 30.18%.

Embodiment 2

[0023] Example 2: Cotton fabric is modified by chitosan modifier.

[0024] Cationic treatment liquid bath ratio 1:30, chitosan concentration 2.50% (o.w.f), 90°C constant temperature treatment for 40 minutes, the obtained cotton fabrics were treated with 1% (o.w.f) reactive red 3BR with bath ratio 1:40, 85°C*30min constant temperature Dyeing, dyeing with salt-free reactive dyes under 85℃*30min color fixing process conditions, test its K / S value, which is the same as that of non-cationized modified cotton fabric dyed under 22g / L yuan sodium powder and other same dyeing conditions K / S The value has increased by 33.23%.

Embodiment 3

[0025] Example 3: Cotton fabric was modified by using quaternary ammonium salt+chitosan modifier.

[0026] Cotton fabric is pretreated with quaternary ammonium salt first, the treatment process conditions are quaternary ammonium salt concentration of 9.00% (o.w.f), NaOH 10.00% (o.w.f), ethanol 7.00% (o.w.f), bath ratio 1:40, constant temperature at 70°C Wash and dry after 50 minutes of treatment.

[0027] Thereafter, the cotton fabric was treated with chitosan. The treatment process conditions were bath ratio 1:30, chitosan concentration 3.00% (o.w.f), and constant temperature treatment at 95°C for 50 minutes. The resulting cotton fabric was bathed with 1% (o.w.f) reactive red 3BR. Ratio 1:40, 85°C*30min constant temperature dyeing, 85°C*30min color fixing process conditions for salt-free reactive dye dyeing, test its K / S value, which is the same as that of non-cationized modified cotton fabric dyed under 22g / L yuan sodium powder and other same dyeing conditions K / S The valu...

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PUM

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Abstract

The invention discloses a cationization composite modification method of a pure cotton fabric and belongs to the field of textile printing and dyeing preprocessing. The cationization composite modification method of the pure cotton fabric is characterized in that first chitosan modification processing is performed to the pure cotton fabric, and then quaternary ammonium salt modification processing is performed to the pure cotton fabric; or first the quaternary ammonium salt modification processing is performed to the pure cotton fabric, and then the chitosan modification processing is performed to the pure cotton fabric. By adopting composite cationization modifier processing to the cotton fabric, the cotton fabric can achieve dyeing effects better than a traditional dyeing process without using dyeing accelerating salt or under conditions of salt dyeing acceleration with low concentration, salt content of dyeing waste water is reduced, and the cationization composite modification method is a cotton fabric processing process which is good for the environment.

Description

Technical field: [0001] The invention relates to a cationic composite modification method for pure cotton fabric, which belongs to the field of pretreatment of textile printing and dyeing. Background technique: [0002] During the dyeing process of pure cotton fabric with reactive dyes, the dyes mainly rely on the affinity of the fibers to adsorb to the surface of the fibers, and then diffuse to the inside of the fibers until most of the dyes in the dye bath are transferred to the fibers. However, due to the existence of anionic groups in the molecular structure of reactive dyes, they are electronegative after being dissolved in water, and have a repulsive effect with cotton fibers that are also electronegative in water, so that the exhaustion rate and color fixation rate of reactive dyes are generally biased. Low. [0003] At present, the main way to solve the above problems is to add salt (or sodium salt) in the dyeing bath to solve it. Since the extra sodium ions are a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): D06M15/03D06M13/46D06M11/38D06P1/38D06M101/06
Inventor 刘越项丽华
Owner SHAOXING UNIVERSITY
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