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Inorganic fiber prepared by utilizing industrial tailings and preparation method thereof

A technology for industrial tailings and inorganic fibers, applied in glass manufacturing equipment, manufacturing tools, etc., can solve the problems of inability to realize the value of tailings, waste of resources, large tailings resources, etc., and achieve good application prospects, reduce pollution, and good quality. Effect

Inactive Publication Date: 2012-06-27
丁向群 +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The tailings resources are huge, with a large amount of accumulation, and the emissions have been increasing in recent years. If they are not utilized and turned into resources, it will cause huge environmental and safety problems, and waste precious resources.
The previous treatment methods such as landfilling and covering cannot fundamentally solve the environmental and social problems caused by tailings, and the use in road construction, building materials, ceramics and other fields cannot realize the ideal value of tailings. How to realize tailings The comprehensive utilization of mines and the realization of high added value of tailings products have attracted much attention

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] In this example, the raw materials of industrial tailings inorganic fibers are composed of 63.5% of iron tailings, 10% of limestone, 22% of coke, 2% of zinc alkoxide, 2% of zirconia, and 2% of alkyl modified 0.3% silicone oil, 0.1% sodium lauryl sulfate, 0.1% polyethylene glycol; mix iron tailings, limestone, coke, zinc alkylate, zirconia with water, water accounts for iron tailings, limestone, coke 15% of the weight sum of , zinc alkylate, and zirconia, granulated by a double-roller granulator, with a particle size of 3-5cm, fully melted in the cupola at 1520 ° C, and the molten melt flows to the four-roller Centrifuge, when the viscosity is 450 poises, form fibers, spray alkyl modified silicone oil, sodium lauryl sulfate and polyethylene glycol mixed aqueous solution (alkyl modified silicone oil, dodecane) quickly and evenly on the formed fibers The concentration of sodium sulfate and polyethylene glycol is 30wt%) to obtain iron tailings inorganic fibers.

[0039] In...

Embodiment 2

[0041] In the present embodiment, by weight percentage, the raw material of industrial tailings inorganic fiber is composed of: 59.5% of copper tailings, 5% of lime, 3% of fluorite, 28% of coke, 2% of sodium alkylate, and 2% of barium sulfate. %, polyether modified silicone oil 0.2%, sodium dodecylbenzene sulfonate 0.1%, polyvinyl alcohol 0.2%; mix copper tailings, lime, fluorite, coke, sodium alkylate, barium sulfate with water, Water accounts for 12% of the weight sum of copper tailings, lime, fluorite, coke, sodium alkanoate, and barium sulfate. It is granulated by a double-roller granulator with a particle size of 2-4 cm. Melt in a cupola at 1500 ° C. system, the melt after melting flows to a four-roller centrifuge, and when the viscosity is 350 poises, fibers are formed, and the mixed aqueous solution of polyether modified silicone oil, sodium dodecylbenzene sulfonate and polyvinyl alcohol is sprayed rapidly and evenly on the fibers ( The concentration of polyether modifi...

Embodiment 3

[0044] In this embodiment, the raw materials of industrial tailings inorganic fibers are composed of: 31% iron tailings, 31% copper tailings, 10% chalk, 26.5% coke, 0.5% magnesium alkanoate, oxygen-containing Silicone oil emulsion 0.2%, phosphoric acid 0.7%, citric acid 0.1%; mix iron tailings, copper tailings, chalk, coke, magnesium alkylate with water, water accounts for iron tailings, copper tailings, chalk, coke, alkane 14% of the weight sum of magnesium base acid is granulated by a double-roller granulator, and the particle size is 3-4cm. It is melted at 1550 ° C in the cupola, and the melt after melting flows to the four-roller centrifuge. At a viscosity of 400 During poling, fibers are formed, and the mixed aqueous solution of oxygen-containing silicone oil emulsion, phosphoric acid and citric acid is quickly and uniformly sprayed on the fibers (the concentration of oxygen-containing silicone oil emulsion, phosphoric acid and citric acid is 25wt%) to obtain tailings inor...

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PUM

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Abstract

The invention relates to the field of inorganic fiber materials, and in particular relates to an inorganic fiber prepared by melting industrial wastes at a high temperature, such as iron tailings or copper tailings, and a preparation method thereof. The inorganic fiber comprises the following raw material components by weight percent: 30-80% of industrial tailings, 0-20% of aided component, 20-40% of coke or coal and the balance of adjuvant and surface treatment agent, wherein the weight of the adjuvant accounts for 0.2-10% of that of the industrial tailings, and the weight of the surface treatment agent accounts for 0.1-5% of the industrial tailings. The preparation method comprises the following steps of: adding the necessary aided components and coke or coal in the industrial tailings and adding the necessary adjuvant, fully mixing and pelleting; carrying out high temperature melting in a cupola furnace or a tank furnace; and under the condition that viscosity of high temperature melt is controlled, forming fiber by utilizing centrifugal wire throwing equipment and spraying the surface treatment agent, and cooling to obtain the inorganic fiber. According to the invention, the fiber has good functionality and high value-added comprehensive utilization of the industrial tailings is achieved, thus the inorganic fiber disclosed by the invention can be widely applied to the fields of heat isolation, sound isolation, heat preservation and insulation materials, asphalt modification and the like, has a good application prospect and is especially suitable for the field of building heat preservation materials.

Description

technical field [0001] The invention relates to the field of inorganic fiber materials, in particular to an inorganic fiber prepared by melting industrial waste such as iron tailings or copper tailings at high temperature and a preparation method thereof. Background technique [0002] Inorganic fiber materials are widely used in many fields, such as: for heat insulation or sound insulation layer, as reinforcing fiber for building materials, as raw materials for papermaking, as friction materials such as vehicle brake pads. The raw materials used to prepare inorganic fibers have a wide range of sources, and their products include glass fiber, rock wool, mineral wool, glass wool and so on. [0003] The use of fly ash, red mud, basalt, steel slag, slag, etc. as raw materials to prepare inorganic fibers has been widely used, and there are patent reports, but there is no patent report on the preparation of inorganic fiber materials using iron tailings or copper tailings. [0004...

Claims

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Application Information

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IPC IPC(8): C03C13/06C03B37/00
Inventor 丁向群刘燚佳马煜喆李中石
Owner 丁向群
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