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Gold extraction method employing gold cyanided tailing roasting-ultrasonic intensification thiourea gold leaching-activated carbon enrichment

A gold cyanide and activated carbon technology, applied in the field of hydrometallurgy, can solve the problems of cumbersome pretreatment process, unfavorable manual operation, and polluting the production environment, and achieve the effects of shortening the gold leaching time, improving the gold leaching efficiency, and increasing the leaching rate

Inactive Publication Date: 2012-09-19
INNER MONGOLIA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the patent CN88102653.0 "New industrial production process for gold extraction by thiourea iron leaching method", the particle size of the leached material needs to be -320 mesh, and the leaching time needs to be 32 to 40 hours. The crushing time is long, the cost is high, and the leaching cycle is too long; patent CN92105962. 0 "The method of extracting gold and silver with thiourea" has the advantages of high leaching rate and short production cycle, but it needs to add SO 2 The industrial flue gas pollutes the production environment and is not conducive to manual operation. At the same time, if this method is used to extract low-grade gold in the tailings, it may not necessarily have the same gold and silver grades as the original ore in the actual operation. High leaching rate: Patent CN200310110091.6 "Biological Oxidation of Refractory Gold Concentrate - Thiourea Resin Slurry Gold Extraction Process" has the advantages of high leaching rate and low cost, but its pretreatment process is cumbersome and time-consuming; patent N200810136957.3 "A gold extraction process with thiourea carbon slurry" has the advantages of high recovery rate and environmental protection, but its disadvantages are cumbersome operation and long process cycle

Method used

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  • Gold extraction method employing gold cyanided tailing roasting-ultrasonic intensification thiourea gold leaching-activated carbon enrichment
  • Gold extraction method employing gold cyanided tailing roasting-ultrasonic intensification thiourea gold leaching-activated carbon enrichment

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] The gold cyanide tailings were reground to -100 mesh, 100g was roasted in a muffle furnace at 650°C for 3 hours, cooled, and taken out. Add mass concentration and be 10g / L thiourea solution 200ml (liquid-solid ratio is 2: 1 during leaching), add Fe 2 (SO 4 ) 3 0.6g, make Fe 2 (SO 4 ) 3 The mass concentration is 3g / L, adjust pH=1.5 with sulfuric acid, 90W ultrasonic treatment 30min, stirring and leaching for 0.5 hour, stirring speed is 100rpm, temperature is 293K, after leaching, use suction filter to filter, add 5g activated carbon (tail The mass ratio of ore powder to activated carbon is 20:1), stir evenly, pH=5, stir once every 10 minutes, absorb for 2 hours, the temperature is 293K, use suction filter after enrichment, and the activated carbon is used for analysis and extraction of gold. The extraction rate of gold is 80.5%.

Embodiment 2

[0018] The gold cyanide tailings were reground to -200 mesh, 100g was roasted in a muffle furnace at 1000°C for 2h, cooled, and taken out. Add 300ml of 15g / L thiourea solution (the ratio of liquid to solid during leaching is 3:1), add Fe 2 (SO 4 ) 3 1.2g, make Fe 2 (SO 4 ) 3 The mass concentration is 4g / L, adjusted to pH=3 with sulfuric acid, 100W ultrasonic treatment for 40min, stirring and leaching for 0.6 hour, stirring speed is 120rpm, temperature is 298K, after leaching, use suction filter to filter, add 5g of activated carbon (tail The mass ratio of mineral powder to activated carbon is 20:1), stir evenly, pH=4, stir once every 10 minutes, absorb for 1.5 hours, the temperature is 298K, use suction filter after enrichment, and activated carbon is used for analysis and extraction of gold, The extraction rate of gold is 90.2%.

Embodiment 3

[0020] The gold cyanide tailings were reground to -200 mesh, 100g was roasted in a muffle furnace at 800°C for 2h, cooled, and taken out. Add mass concentration and be 12g / L thiourea solution 300ml (liquid-solid ratio is 3: 1 during leaching), add Fe 2 (SO 4 ) 3 1.2g, make Fe 2 (SO 4 ) 3 The mass concentration is 4g / L, adjusted to pH=2 with sulfuric acid, 110W ultrasonic treatment for 30min, stirring and leaching for 0.5 hour, the stirring speed is 130rpm, and the temperature is 298K. The mass ratio of ore powder to activated carbon is 12.5:1), stir evenly, pH=3, stir once every 10 minutes, absorb for 1.5 hours, the temperature is 298K, use suction filter after enrichment, and the activated carbon is used for analysis and extraction of gold. The extraction rate of gold is 92.4%.

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Abstract

The invention relates to a gold extraction method employing gold cyanided tailing roasting, ultrasonic intensification thiourea gold leaching and activated carbon enrichment, and belongs to the field of wet method metallurgy. According to the gold extraction method, gold-containing cyanided tailing is subjected to roasting treatment, then thiourea is used for leaching gold, meanwhile the ultrasonic intensification treatment is carried out, solid-liquid separation is performed after the gold leaching, gold contained in the liquid phase is gathered by the activated carbon through enrichment, solid-liquid separation is performed after the enrichment, the activated carbon is used for extracting and resolving gold, after resolving, the activated carbon is activated to be recycled repeatedly, a large quantity of thiourea exits in the tail liquid, and the thiourea can be circularly used for the leaching process after being simply treated. The gold extraction method is used for extracting gold in the cyanided tailing through leaching, the leaching speed is high, the extraction rate can be more than 90%, the cycle is short, and the activated carbon and the tail liquid can be recycled, so the production cost is greatly reduced, the economical benefit on the utilization of gold cyanided tailing is improved, and meanwhile, the environmental protection is facilitated.

Description

technical field [0001] The invention relates to a gold extraction method of roasting gold cyanide tailings-ultrasonic enhanced thiourea gold leaching-activated carbon enrichment, and belongs to the field of hydrometallurgy. Background technique [0002] At present, the method of extracting gold is mainly by cyanide extraction. As a classic method, cyanide gold leaching is simple in operation, high in gold recovery rate and low in production cost. It has been widely used in the gold industry and occupies a dominant position. However, because cyanide is highly toxic, it is more harmful to environmental pollution, has defects such as long production cycle, and has poor leaching effect on low-grade ores such as gold tailings. [0003] With the increasing amount of gold tailings and the scarcity of gold resources, gold in tailings has become a resource that cannot be underestimated. Therefore, it is particularly important to seek a method suitable for extracting gold from gold c...

Claims

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Application Information

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IPC IPC(8): C22B11/00C22B1/02C22B3/04C22B3/24
CPCY02P10/20
Inventor 王建英张雪峰许世伟郑春丽郑升
Owner INNER MONGOLIA UNIV OF SCI & TECH
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