Unlock instant, AI-driven research and patent intelligence for your innovation.

Preparation method of poly-aluminum calcium chloride

A technology of polyaluminum calcium chloride and calcium chloride, which is applied in the fields of water treatment, printing and dyeing, and papermaking. It can solve the problems of harsh preparation conditions and poor adaptability of PAC, and achieve the effects of improving product application effects, reducing costs, and broadening the scope of raw materials.

Active Publication Date: 2012-11-07
EAST CHINA UNIV OF SCI & TECH
View PDF3 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the above-mentioned technical problems, the present invention provides a preparation method of polyaluminum calcium chloride to overcome the problems of harsh preparation conditions and poor adaptability of existing PAC.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The preparation method of polyaluminum calcium chloride comprises the steps:

[0019] (1) Prepare a mixed solution of aluminum chloride and calcium chloride so that the molar ratio of aluminum chloride and calcium chloride in the solution is 2:1;

[0020] (2) heating the mixed solution treated in step (1) to keep the temperature of the mixed solution at 80°C;

[0021] (3) Slowly add alkali solution to the mixed solution treated in step (2), and calculate the alkali consumption according to the alkalization degree of 80%;

[0022] (4) reacting the mixed solution treated in step (3) for 30 minutes, so that the pH of the mixed solution is 6;

[0023] In order to make the technical effect of the product better, the curing process can also be carried out. The curing time is 15 hours, and the curing temperature is controlled at 80°C. Adding an appropriate amount of the prepared solution product can make the residual turbidity of the simulated sewage as low as 4 NTU.

Embodiment 2

[0025] The steps are the same as in Example 1, except that the parameters involved are different, and the implementation is as follows:

[0026] Prepare a mixed solution of aluminum chloride and calcium chloride, adjust the molar ratio of aluminum chloride to calcium chloride in the solution to 5, the reaction temperature is 60°C, the degree of alkalinity is 70%, the reaction is 45 minutes, the pH is controlled at 5.8, and the aging temperature is 60°C , matured for 24 hours, adding an appropriate amount of the prepared solution product, the residual turbidity of the simulated sewage will be as low as 3 NTU.

Embodiment 3

[0028] The steps are the same as in Example 1, except that the parameters involved are different, and the implementation is as follows:

[0029] Prepare a mixed solution of aluminum chloride and calcium chloride, adjust the molar ratio of aluminum chloride and calcium chloride in the solution to 3, the reaction temperature is 80°C, the degree of alkalinity is 40%, the reaction is 90 minutes, the pH is controlled at 3.5, and the aging temperature is 80°C , matured for 48 hours, adding an appropriate amount of the prepared solution product, the residual turbidity of the simulated sewage will be as low as 1NTU.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The present invention relates to the fields of water treatment, paper making, and printing and dyeing, and provides a preparation method of poly-aluminum calcium chloride. A mixed solution of aluminum calcium chloride is adjusted to a certain proportion, and then treated with an alkalization reaction and curing, so as to prepare a mixed solution suitable for sewage treatment. According to the invention, calcium is utilized to partially substitute aluminum, thereby synthesizing the poly-aluminum calcium chloride. The method provided by the invention can replace an existing novel inorganic flocculant method for preparation of poly-aluminum chloride (PAC), and overcome problems of harsh conditions and bad adaptability of the existing PAC preparation, and has double effects in environmental protection and economic utilization.

Description

technical field [0001] The invention relates to the technical fields of water treatment, papermaking, and printing and dyeing. Specifically, it is a method for preparing inorganic polymer materials containing chlorine, aluminum and calcium. Background technique [0002] The problem of water safety treatment has become a serious constraint factor for the sustainable development of my country's economy and society. In the process of purifying urban sewage, sewage-containing rivers, and industrial wastewater, there is an urgent need for a composite flocculant with the characteristics of low price, high efficiency, and multiple functions. [0003] The flocculants used in water treatment can basically be divided into biological flocculants, organic flocculants, natural polymer flocculants and inorganic flocculants. Among them, inorganic polymer flocculant is a special chemical agent that is widely used and widely used in the field of water treatment technology. In the sales vol...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C02F1/52C01F7/56
Inventor 乔秀臣于建国金鑫
Owner EAST CHINA UNIV OF SCI & TECH