5-hydroxy indole derivative contain heterocyclic ring and applications thereof
A hydroxyl and indole technology, applied in the field of 5-hydroxyindole derivatives, can solve the problems of inability to prevent and treat viral diseases, lack of drugs and the like
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[0189] The examples are intended to illustrate, not limit, the scope of the invention. The H NMR spectra of the compounds were determined by Bruker ARX-300, and the mass spectra were determined by Agilent 1100 LC / MSD; the reagents used were analytical or chemically pure.
[0190] Preparation of thiol or thiophenol intermediates
[0191] Some mercaptans or thiophenols are commercially available; other mercaptans or thiophenols are prepared as follows:
[0192] method 1: preparation of
[0193] Add 100 mL (1.6 mole) of carbon disulfide into the three-neck flask, cool down to -5°C, add dropwise 300 mL of 15% ammonia-ethanol solution, and continue stirring at -5°C for 4 h. Suction filtration, washing with ether, and drying gave 152 g of ammonium dithiocarbamate as yellow crystals, with a yield of 86%.
[0194] Add 100 mL (0.85 mol) of acetophenone into 150 mL ethanol, keep the temperature not higher than -5°C, and add 320 g (0.85 mol) of phenyl trimethylammonium tribromide (P...
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