Method and apparatus for rapidly stabilizing catalyst activity by heavy fuel oil

A technology of heavy fuel oil and catalyst, applied in the direction of catalyst protection, chemical instruments and methods, physical/chemical process catalysts, etc.

Active Publication Date: 2014-07-02
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the uneven injection of fuel oil, the distribution of catalyst in the regenerator is also uneven, resulting in uneven reduction of catalyst activity. Some catalysts are seriously deactivated in the ultra-high temperature environment where the combustion oil is injected, and some catalysts are still highly active.

Method used

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  • Method and apparatus for rapidly stabilizing catalyst activity by heavy fuel oil
  • Method and apparatus for rapidly stabilizing catalyst activity by heavy fuel oil
  • Method and apparatus for rapidly stabilizing catalyst activity by heavy fuel oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] Example 1 illustrates the catalyst aging effect of the method provided by the present invention.

[0059] The process flow of the catalyst aging device structure is attached figure 1 As shown, the catalyst aging device includes a fluidized bed reactor 5 and a dilute-phase combustion pipe 4. The catalyst in the fluidized bed reactor enters the bottom of the dilute-phase combustion pipe 4 through a pipeline 9 and a control valve 10, and is connected with the air from the pipeline 1. After mixing, change the flow direction of the catalyst, go upward along the dilute-phase combustion tube, and then mix with a part of oil slurry from pipeline 2 for combustion reaction. Then inject air through the pipeline 21 to make it burn; then spray the remaining oil slurry into the riser reactor through the pipeline 22 to make it contact with the catalyst, make it evenly dispersed on the catalyst, and then inject air through the pipeline 23 to make it burn; The gas and catalyst after t...

Embodiment 2

[0062] Example 2 illustrates the effect of the aging catalyst provided by the method used in the catalytic cracking reaction.

[0063] The medium-sized device and raw oil in Comparative Example 2 were adopted, and the operating steps and reaction conditions were the same as those in Comparative Example 2, except that the catalyst was the catalyst with reduced activity obtained by aging in Example 1. The properties of the raw oil are shown in Table 4, and the reaction conditions and results are shown in Table 5.

Embodiment 3

[0065] Example 3 illustrates the catalyst aging effect of the method provided by the present invention.

[0066] The aging device and aging method adopted are the same as in embodiment 1, except that the fuel injected in the dilute phase combustion tube is diesel oil.

[0067] The properties of the fresh catalyst CTZ-1 are shown in Table 1, the fuel is diesel, its properties are shown in Table 2, the operating conditions are shown in Table 3, and the properties of the aged catalyst are shown in Table 1.

[0068] Example 2

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Abstract

A method and equipment for rapidly stabilizing catalyst activity using heavy fuel oil, comprising: (1) The catalyst enters the bottom of a dilute-phase combustion tube from a fluidized bed reactor, and the dilute-phase combustion tube is provided with two or more feed ports from bottom to top , spraying oxygen-containing gas and heavy fuel oil in sequence, the catalyst first mixes with oxygen-containing gas and flows upwards, then mixes with heavy fuel oil, and then replenishes oxygen-containing gas; (2) the high-temperature gas and catalyst after combustion reaction The outlet of the dilute phase combustion tube enters the fluidized bed reactor; (3) the high temperature catalyst in the fluidized bed reactor reacts with water vapor to reduce the activity, and the catalyst separated from the top of the catalyst aging device returns to the fluidized bed reactor; (4) the catalyst is aged After completion, shut down and unload the catalyst. and a device for implementing the method. By adopting the aging method and equipment provided by the invention, the activity of the catalyst can be quickly reduced to a stable level, the activity of the aged catalyst is evenly distributed, and the distribution of products used for catalytic cracking reaction of hydrocarbon oil is obviously improved.

Description

technical field [0001] The invention relates to a method and equipment for stabilizing the activity of catalytic cracking catalysts, more specifically, to a method and equipment for using heavy fuel oil as fuel to rapidly stabilize the activity of catalysts. Background technique [0002] Catalytic cracking technology is the main secondary processing technology of oil refining enterprises. The technology converts heavy hydrocarbon oil feedstocks into products such as gasoline, diesel, propylene and liquefied gas. During the operation of the catalytic cracking unit, the activity of the catalyst in the unit needs to be kept at a stable level. If the catalyst activity is too high, the yield of dry gas and coke will be too high, and the product selectivity will be poor; if the catalyst activity is too low, if it is lower than 55, it will cause the conversion rate to decrease and the yield of light oil products to decrease. The activity of the catalyst can be measured by the mic...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J33/00B01J27/055C10G11/02
Inventor 张执刚许友好谢朝钢毛安国陈昀朱根权刘银亮刘炜
Owner CHINA PETROLEUM & CHEM CORP
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