Novel CO isothermal conversion method

A new type of isothermal transformation technology, applied in the field of temperature transformation, can solve the problems of safe operation of equipment affecting the service life of catalyst, high hot spot temperature of catalyst bed, easy occurrence of methanation reaction, etc. Side reactions, effect of constant operating temperature

Inactive Publication Date: 2013-03-20
EAST CHINA ENG SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The high steam-gas ratio conversion process has a high water vapor content, a large reaction driving force, a high hot spot temperature of the catalyst bed, and the reactor is prone to overheating, which affects the service life of the catalyst and the safe operation of the equipment. At the same time, due to the large amount of steam , higher operating costs
The low steam-to-gas ratio conversion process reduces the H in the feed gas 2 The content of O is prone to methanation reaction; the load of a single reactor is low, and the utilization rate of the equipment is poor; 2 O, unable to convert H in the feed gas 2 The content of O is reduced, and the reactor is easy to overheat

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0036] The raw material gas is calcium carbide furnace gas. After dedusting and compression, the temperature is 140°C and the pressure is 3.0MPaG. The raw material gas is filled with steam and then enters the transformation process. The raw gas is heated by the raw gas preheater to 230°C, and enters the raw gas filter to filter dust and remove poisons. The filtered raw gas enters the first shift furnace (axial flow steam reactor) for shift reaction. The coal gas goes through the tube side of the first converter, and the shell side tube passes through the boiler feed water to by-produce steam to take off the reaction heat. After leaving the first shift furnace, the gas enters the raw gas preheater to preheat the inlet raw gas, then enters the waste heat boiler by-product steam to cool down, and then enters the second shift furnace (air-cooled reactor) for shift reaction. The heat of reaction generated in the second shift furnace is removed by preheating the inlet gas of the se...

Embodiment 2

[0040] The raw material gas is water gas produced by GSP gasification technology (dry pulverized coal fluidized bed gasification technology). After liquid and dust removal, the temperature is 209°C and the pressure is 3.8MPaG to enter the transformation process. The raw gas is heated by the raw gas preheater to 230°C, and enters the raw gas filter to filter dust and remove poisons. The filtered raw gas enters the first shift furnace (axial flow steam reactor) for shift reaction. The coal gas goes through the tube side of the first converter, and the shell side tube passes through the boiler feed water to by-produce steam to take off the reaction heat. After the gas leaves the first shift furnace, it enters the raw gas preheater to preheat the inlet raw gas, and then enters the waste heat boiler by-product steam to cool down, and then enters the second shift furnace (air-cooled reactor) for shift reaction. The heat of reaction generated in the second shift furnace is removed b...

Embodiment 3

[0044] The raw material gas is water gas produced by coal-water slurry gasification technology. After liquid and dust removal, the temperature is 221°C and the pressure is 40.6MPaG to enter the conversion process. The raw gas is heated by the raw gas preheater to 270°C, and enters the raw gas filter to filter dust and remove poisons. The filtered raw gas enters the first shift furnace (axial steam reactor) for shift reaction. The coal gas goes through the tube side of the first converter, and the shell side tube passes through the boiler feed water to by-produce steam to take off the reaction heat. After the gas leaves the first shift furnace, it enters the raw gas preheater to preheat the inlet raw gas, and then enters the waste heat boiler by-product steam to cool down, and then enters the second shift furnace (air-cooled reactor) for shift reaction. The heat of reaction generated in the second shift furnace is removed by preheating the inlet gas of the second shift furnace...

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Abstract

The present invention discloses a novel CO isothermal conversion method, which comprises the following steps that: raw material gas is subjected to heating temperature increasing, dust filtration and poison removing; the filtered raw material gas enters a first conversion furnace to carry out a conversion reaction; the by-produced medium pressure steam is adopted to remove reaction heat produced in the first conversion furnace; the gas leaves the first conversion furnace, enters a raw material gas pre-heater to preheat the inlet raw material gas, then enters a waste heat boiler to by-produce steam so as to cool, and enters a second conversion furnace to carry out a conversion reaction; the second conversion furnace inlet gas is preheated to remove reaction heat produced in the second conversion furnace; and the gas leaves the second conversion furnace, and then enters the downstream process. The novel CO isothermal conversion method is applicable for characteristics of a wide steam-gas ratio and a wide CO dry base content. With the novel CO isothermal conversion method, a reactor hot spot temperature can be controlled so as to improve a catalyst service life and improve equipment operation conditions; methanation side reaction generation can be effectively inhibited; reaction heat can be efficiently recovered; conversion rate of the single reactor can be increased; the conversion process can be simplified; and equipment cost can be reduced.

Description

Technical field: [0001] The invention relates to a novel conversion method for performing a conversion reaction at a constant temperature, in particular to a novel CO isothermal conversion method. Background technique: [0002] transformation response ( ) is an exothermic reaction. In traditional industrial production, adiabatic reactors are used in converter furnaces. In the process setting, multi-stage reactions are often used, and the way of heat exchange and cooling between stages is used. The traditional conversion method has the characteristics of relatively complicated process, high heat loss and high equipment cost. At the same time, when the dry basis content of CO in the feed gas is high, the hot spot temperature of the shift reactor is high, and the outlet of the shift reactor is prone to overheating, which affects the service life of the shift catalyst. adjustment means to avoid overheating. At present, there are two conversion processes for feed gas with hig...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B3/16
CPCY02P20/129Y02P20/52
Inventor 刘洪涛胡文生
Owner EAST CHINA ENG SCI & TECH
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