High-scratch-resistance optical resin monomer and preparation method thereof
A technology of optical resin and performance, applied in the field of resin monomer preparation, can solve the problems of poor chemical resistance, large lens color difference, low pass rate, etc., and achieve excellent scratch resistance, high scratch resistance, and stability Good results
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Embodiment 1
[0046] A kind of high anti-scratch performance optical resin monomer, the parts by weight of its components are:
[0047] Dimethyl terephthalate 21
[0048] Propylene Glycol 3
[0049] Acryl alcohol 4
[0050] Oligomers 37
[0051] CR-39 16
[0052] Dibutyl maleate 7
[0053] Pentaerythritol tetramercaptoacetate 4
[0054] Bismaleimide 3
[0055] Diphenylmethane diisocyanate 5.
[0056] The preparation method of the high-scratch-resistant performance optical resin monomer of the present embodiment is carried out according to the following steps:
[0057] (1) Dimethyl terephthalate, allyl alcohol, calcium hydroxide and salt of wormwood, by the following weight percentages:
[0058] Dimethyl terephthalate 66%
[0059] Allyl Alcohol 32.5%
[0060] Calcium Hydroxide 0.9%
[0061] Potassium carbonate 0.6%
[0062] Put it into the reaction kettle, heat it to 120°C, stir the raw materials after dissolving to make the raw materials react, and recover the allyl alcohol and ...
Embodiment 2
[0079] A kind of high anti-scratch performance optical resin monomer, the parts by weight of its components are:
[0080] Dimethyl terephthalate 21
[0081] Propylene Glycol 5
[0082] Acryl alcohol 2
[0083] Oligomers 37
[0084] CR-39 16
[0085] Dibutyl maleate 9
[0086] Pentaerythritol tetramercaptoacetate 2
[0087] Bismaleimide 5
[0088] Diphenylmethane diisocyanate 3.
[0089] The preparation method of the high-scratch-resistant performance optical resin monomer of the present embodiment is carried out according to the following steps:
[0090] (1) Dimethyl terephthalate, allyl alcohol, calcium hydroxide and salt of wormwood, by the following weight percentages:
[0091] Dimethyl terephthalate 66%
[0092] Allyl Alcohol 32.5%
[0093] Calcium hydroxide 0.6%
[0094] Potassium carbonate 0.9%
[0095] Put it into the reaction kettle, heat it to 130°C, stir the raw materials after dissolving to make the raw materials react, and recover the allyl alcohol and ...
Embodiment 3
[0112] A kind of high anti-scratch performance optical resin monomer, the parts by weight of its components are:
[0113] Dimethyl terephthalate 22
[0114] Propylene Glycol 4
[0115] Acryl alcohol 3
[0116] Oligomer 39
[0117] CR-39 17
[0118] Dibutyl maleate 7
[0119] Pentaerythritol tetramercaptoacetate 2
[0120] Bismaleimide 3
[0121] Diphenylmethane diisocyanate 3.
[0122] The preparation method of the high-scratch-resistant performance optical resin monomer of the present embodiment is carried out according to the following steps:
[0123] (1) Dimethyl terephthalate, allyl alcohol, calcium hydroxide and salt of wormwood, by the following weight percentages:
[0124] Dimethyl terephthalate 69%
[0125] Allyl Alcohol 29.5%
[0126] Calcium Hydroxide 0.9%
[0127] Potassium carbonate 0.6%
[0128] Put it into the reaction kettle, heat it to 135°C, stir the raw materials after dissolving to make the raw materials react, and recover the allyl alcohol and t...
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