Positive photosensitive resin composition, photosensitive resin layer and display device using same
A resin composition, positive photosensitive technology, applied in photosensitive materials for opto-mechanical equipment, nonlinear optics, optics, etc., can solve the problem of difficult to achieve high aperture ratio, low heat resistance and insulation performance, insulation resistance performance deterioration, etc.
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Embodiment 1
[0299] Synthesis Example 1: Synthesis of Polybenzoxazole Precursor (PBO-A)
[0300]In a four-necked flask equipped with a stirrer, a temperature control device, a nitrogen injector, and a condenser, 41.1 g of 2,6-bis[[[5-[1-(amino-4-hydroxyphenyl)-2 , 2,2-trifluoro-1-(trifluoromethyl)ethyl]-2-hydroxyphenyl]amino]methyl]-4-cresol dissolved in 280g of N-methyl-2-pyrrolidone (NMP ), while passing nitrogen gas. When the solid was completely dissolved, 9.9 g of pyridine was added to the solution. The mixture was kept at a temperature range of 0 to 5°C, and slowly added thereto in 30 minutes in a dropwise manner by dissolving 13.3 g of 4,4'-oxydibenzoyl chloride in 142 g of N-methyl The solution prepared in base-2-pyrrolidone (NMP). The resulting mixture was reacted at 0°C to 5°C to room temperature for 1 hour and then its temperature was raised to room temperature, followed by stirring for 1 hour to complete the reaction.
[0301] Here, 1.6 g of 5-norbornene-2,3-dicarboxylic ...
Embodiment 2
[0316] The positive photosensitive resin composition was prepared according to the same procedure as in Example 1, except that 8 parts by weight of the red dye CFR007 represented by Chemical Formula 29 and 2 parts by weight of the azo-based orange color represented by Chemical Formula 30 were added. Dye CFO011.
Embodiment 3
[0318] The positive photosensitive resin composition was prepared according to the same procedure as in Example 1, except that 16 parts by weight of the red dye CFR007 represented by Chemical Formula 29 and 4 parts by weight of the azo-based orange represented by Chemical Formula 30 were added. Dye CFO011.
PUM
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