Chloridized 1-vinyl-3-amino-formyl methyl-imidazole bifunctional ionic liquid and synthetic method thereof

A technology of carbamoylmethylimidazole and vinylimidazole is applied in the field of functional materials and preparation thereof, and achieves the effects of simple steps and low cost

Inactive Publication Date: 2013-08-14
NORTHWESTERN POLYTECHNICAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with the development of polymerizable ionic liquids, a single ionic liquid containing double bonds can no longer meet the needs of appli

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Add 3.00g (32.10mmol) of 2-chloroacetamide to 45.00g of acetone and stir thoroughly at 50°C for 20min to obtain a clear acetone solution containing 2-chloroacetamide. Add 0.03g of polymerization inhibitor phenol to the solution, after stirring, add 3.02g (32.10mmol) of 1-vinylimidazole, react at 45°C for 24h, the reaction will give a white precipitate, wash the white precipitate with acetone 3 times, each Hypoacetone was used in an amount of 30 mL, filtered, and vacuum-dried in a vacuum oven at 50° C. for 3 h to obtain 1.93 g of white powder of 1-vinyl-3-carbamoylmethylimidazole chloride, with a yield of 32%.

Embodiment 2

[0019] Add 4.50g (48.15mmol) of 2-chloroacetamide to 90.00g of acetone, and stir thoroughly at 50°C for 20min to obtain a clear acetone solution containing 2-chloroacetamide. Add 0.03g of polymerization inhibitor phenol to the solution, after stirring, add 3.02g (32.1mmol) of 1-vinylimidazole, and react at 48°C for 24h, the reaction will give a white precipitate, wash the white precipitate with acetone 3 times, every Hypoacetone was used in an amount of 30 mL, filtered, and vacuum-dried in a vacuum oven at 50°C for 3 hours to obtain 2.23 g of white powder of 1-vinyl-3-carbamoylmethylimidazole chloride, with a yield of 37%.

Embodiment 3

[0021] Add 6.00g (64.20mmol) of 2-chloroacetamide to 150.00g of acetone, and stir thoroughly at 50°C for 20min to obtain a clear acetone solution containing 2-chloroacetamide. Add 0.03g of polymerization inhibitor phenol to the solution, after stirring, add 3.02g (32.1mmol) of 1-vinylimidazole, react at 50°C for 18h, and get a white precipitate, wash the white precipitate with acetone 3 times, every Hypoacetone was used in an amount of 30 mL, filtered, and vacuum-dried in a vacuum oven at 50° C. for 3 h to obtain 2.05 g of white powder of 1-vinyl-3-carbamoylmethylimidazole chloride, with a yield of 34%.

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Abstract

The invention provides chloridized 1-vinyl-3-amino-formyl methyl-imidazole bifunctional ionic liquid and a synthetic method thereof. The chloridized 1-vinyl-3-amino-formyl methyl-imidazole bifunctional ionic liquid is obtained by taking 1-vinylimidazole and 2-chloroacetamide as raw materials, acetone as a solvent and phenol as a polymerization inhibitor, and reacting at 45-55 DEG C. The synthesized ionic liquid enriches the variety of polymerizable ionic liquid, and provides more selections for the application of the ionic liquid in the fields of functional materials, catalysis, separation and the like. Besides, the synthetic method is simple in step, does not need special equipment and is lower in cost.

Description

technical field [0001] The invention relates to a bifunctional ionic liquid chlorinated 1-vinyl-3-carbamoylmethylimidazole with double bonds and amide groups and a synthesis method thereof, belonging to the technical field of functional materials and their preparation. Background technique [0002] Ionic liquids are composed of organic cations and inorganic anions or inorganic cations and organic anions, and are liquid molten salts at 100°C. Ionic liquids have almost no vapor pressure, are nonflammable, have high ion density and ion conductivity, and have good solubility for both inorganic and organic substances. Due to the adjustability of anions and cations, ionic liquids with desired properties can be obtained by changing the structures of anions and cations in ionic liquids. Therefore, ionic liquids have been widely used in separation chemistry, electrochemistry, organic chemistry, and even polymer chemistry in recent years. [0003] As an important branch of ionic liq...

Claims

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Application Information

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IPC IPC(8): C07D233/56
Inventor 胡小玲钱立伟管萍
Owner NORTHWESTERN POLYTECHNICAL UNIV
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