Preparation method of high-plasticity TiNi51 alloy wire material

An alloy wire and high plasticity technology is applied in the field of preparation of high plasticity titanium-nickel shape memory alloy Ti-Ni51at% wire, which can solve the problems of poor alloy fluidity, inability to convert production costs into stable processes, and reduce material processing performance. The effect of improving plastic workability

Active Publication Date: 2013-08-14
西安赛特金属材料开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, due to the limitations of the smelting equipment itself and the smelting process, small ingots below 20Kg are generally prepared, and the fluidity of the alloy is poor, as well as the limitations of pouring conditions, which inevitably produce defects such as pores and cold shuts, which reduces the processing of materials. performance
TiNi alloy smeltin

Method used

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  • Preparation method of high-plasticity TiNi51 alloy wire material
  • Preparation method of high-plasticity TiNi51 alloy wire material

Examples

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Example Embodiment

[0029] Example 1

[0030] The processing method of TiNi51 (Ti-Ni51at%) alloy Φ6.5mm wire: First, the raw material grade 0 sponge titanium and Ni9999 electrolytic nickel are mixed according to the ratio of Ti-Ni51at% (Ti-Ni56.06wt%), and then smelted at 25Kg intermediate frequency vacuum induction Φ100-15Kg primary titanium nickel alloy ingot. After cutting off the riser of one ingot and peeling the skin, 4 sets of welding electrodes are selected as consumable electrodes, and the weight is 45Kg. Φ160mm copper crucible is selected for smelting in vacuum consumable furnace to obtain Φ160-45Kg ingot. Then the ingot is homogenized at high temperature, the temperature is 950-1150℃, and the holding time is 4-6h. After forging and rolling, it is processed into a wire blank; finally, it is drawn and straightened to produce a finished wire.

Example Embodiment

[0031] Example 2

[0032] The processing method of TiNi51 (Ti-Ni51at%) alloy Φ3.5mm wire: firstly mix the raw materials of grade 0 sponge titanium and Ni9999 electrolytic nickel according to the ratio of Ti-Ni51at% (Ti-Ni56.06wt%), and smelt at 25Kg intermediate frequency vacuum induction Φ100-15Kg primary titanium nickel alloy ingot. Cut off the riser of the primary ingot, and after peeling, select 10 for group welding as consumable electrodes, the weight is 110Kg. Φ160mm copper crucible is selected for smelting in vacuum consumable furnace to obtain Φ160-110Kg ingot. Then, the ingot is homogenized at high temperature, the temperature is 950-1150℃, and the holding time is 6-8h. After forging and rolling, it is processed into a wire blank; finally, it is drawn and straightened to produce a finished wire. The straightening process is temperature 800~950℃, speed 5~14mm / s, water cooling. The wire can realize an automatic line to Φ1.1mm once, and the cold deformation can reach mo...

Example Embodiment

[0033] Example 3

[0034] The processing method of TiNi51 (Ti-Ni51at%) alloy Φ1mm wire: First, the raw material 0 grade sponge titanium and Ni9999 electrolytic nickel are mixed according to the ratio of Ti-Ni51at% (Ti-Ni56.06wt%), and the vacuum induction melting Φ100- at 25Kg intermediate frequency 15Kg primary titanium nickel alloy ingot. After cutting off the riser of the primary ingot and peeling the skin, select 14 consumable electrodes for group welding, with a weight of 150Kg. Φ160mm copper crucible is selected for smelting in vacuum consumable furnace to obtain Φ160-150Kg ingot. Then, the ingot is homogenized at high temperature, the temperature is 950-1150℃, and the holding time is 6-8h. After forging and rolling, it is processed into a wire blank; finally, it is drawn and straightened to produce a finished wire. Temperature 800~860℃, speed 10~20mm / s, water cooling.

[0035] Metallographic analysis of TiNi51at%-Φ2.0mm alloy wire prepared by the invention figure 1 , Be...

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Abstract

The invention discloses a preparation method of a high-plasticity TiNi51 alloy wire material. The method comprises steps of: carrying out medium frequency induction smelting and vacuum self-consuming smelting so that the casting defects of primary ingots are eliminated to obtain pure and uniform cast ingots and moreover titanium and nickel alloy large-scale ingot casting are obtained and the production efficiency and material batch stability are improved further; then, homogenizing the cast ingot at a high temperature so as to reduce the brittle phase of the materials; forging and rolling to form wire blanks; and finally, drawing and correcting to produce the finished wire materials. Compared with the prior art, the method has the following advantages that the technology combining medium frequency induction smelting with vacuum self-consuming smelting is adopted so as to obtain the uniform, pure and large-scale titanium-nickel cast ingots; the brittle phase of the materials is reduced through high-temperature homogenizing treatment; and reasonable heating and finished product correcting technologies are adopted so as to improve the plastic processing performance of the materials. The TiNi51 alloy wire materials with large ingot shape, uniformity, stability and high plasticity are prepared.

Description

technical field [0001] The invention relates to a method for preparing a titanium-nickel wire, in particular to a method for preparing a high-plasticity titanium-nickel shape memory alloy Ti-Ni51at% wire. Background technique [0002] Titanium-nickel-based shape memory alloy is a new type of metal functional material that emerged in the 1960s with three characteristics: shape memory, superelasticity and high damping. It also has excellent biocompatibility. It has been used in electronics, machinery , aerospace, energy, medical care and daily necessities and other fields. [0003] The main application characteristics of equiatomic ratio Ti-Ni alloy materials are superelasticity and shape memory effect, including parameters such as alloy phase transition point, recovery stress and recovery rate, and chemical composition is the most sensitive factor affecting alloy performance. When the Ni content is less than 50.5at%, the superelasticity of Ti-Ni alloy is poor; the higher the...

Claims

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Application Information

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IPC IPC(8): C22C19/03C22C1/02C22F1/10
Inventor 毛江虹曹继敏杨华斌牛中杰雷亚军薛飒
Owner 西安赛特金属材料开发有限公司
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