Adsorbent for absorbing heavy metal ions and preparation method thereof
A technology for adsorbing heavy metals and adsorbents, applied in the field of adsorbents and their preparation, can solve the problems of high processing cost and difficult regeneration, and achieve the effect of good adsorption performance
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Embodiment 1
[0014] Grind 15 parts of bentonite and 10 parts of retort clay into powder, and mix the obtained bentonite and retort clay powder with 15 parts of SBA-15 molecular sieve evenly, and then knead to prepare a composite. Roasting at ℃ for 3 hours; prepare calcium chloride and aluminum chloride solutions respectively, mix the two solutions at a ratio of 5:6 to obtain a mixed solution, add ammonia precipitant to the mixed solution, let it stand for 4 hours, and use the deposition method. Calcium and aluminum are supported on the composite, and the solid obtained after filtration is dried at 80°C for 18 hours, calcined at 850°C for 4 hours, ground and sieved to obtain an adsorbent for adsorbing heavy metal ions. When adsorbing chromium ions in wastewater, the adsorption rate can reach 97.3%.
Embodiment 2
[0016] Grind 25 parts of bentonite and 15 parts of retort clay into powder, and mix the obtained bentonite and retort clay powder with 18 parts of SBA-15 molecular sieve evenly to prepare a compound by kneading method. Roasting at ℃ for 4 hours; prepare calcium chloride and aluminum chloride solutions respectively, mix the two solutions at a ratio of 8:7 to obtain a mixed solution, add ammonia water precipitant to the mixed solution, let stand for 5 hours, and use the deposition method. Calcium and aluminum are supported on the composite, and the solid obtained after filtration is dried at 100°C for 20 hours, calcined at 950°C for 5 hours, ground and sieved to obtain an adsorbent for adsorbing heavy metal ions. When adsorbing chromium ions in wastewater, the adsorption rate can reach 97.6%.
Embodiment 3
[0018] Grind 35 parts of bentonite and 20 parts of retort clay into powder, and mix the obtained bentonite and rector clay powder with 20 parts of SBA-15 molecular sieve evenly, and then knead to prepare the composite. Roasting at ℃ for 5 hours; prepare calcium chloride and aluminum chloride solutions respectively, mix the two solutions at a ratio of 9:8 to obtain a mixed solution, add ammonia water precipitant to the mixed solution, let it stand for 6 hours, and use the deposition method. Calcium and aluminum are supported on the composite, and the solid obtained after filtration is dried at 120°C for 24 hours, calcined at 1000°C for 6 hours, ground and sieved to obtain an adsorbent for adsorbing heavy metal ions. When adsorbing chromium ions in wastewater, the adsorption rate can reach 97.4%.
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