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Potassium humate and preparation method thereof

A technology of potassium humate and tert-butyl peroxyneodecanoate, applied in the direction of organic chemistry, etc., can solve the problem of not being able to effectively utilize potassium resources of tert-butyl peroxyneodecanoate waste liquid, and achieve the effect of avoiding costs

Active Publication Date: 2016-01-20
乌鲁木齐市华泰隆化学助剂有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The present invention provides a kind of potassium humate and its preparation method, which overcomes the above-mentioned deficiencies in the prior art, and it can effectively solve the problem that new peroxide cannot be effectively utilized at present. The problem of potassium resources in tert-butyl decanoate waste liquid, its

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Embodiment 1: this potassium humate obtains by following preparation method: the first step, tert-butyl peroxyneodecanoate waste liquid is separated, obtains aqueous phase solution after separation; Second step, takes water by weight parts Phase solution 100 to 160 parts, weathered coal powder 80 to 120 parts, deionized water 110 to 200 parts, the required amount of aqueous phase solution, weathered coal powder and deionized water are mixed uniformly to obtain a mixed solution; The third step is to heat the mixed solution to 80°C to 100°C for reaction, test the pH value of the mixed solution during the reaction, and obtain a dark brown paste after the reaction, the fourth step is to dry the dark brown paste A dried substance of potassium humate is obtained, wherein: the reaction time is 40 minutes to 90 minutes, the pH value at the end of the reaction is 9 to 11, the drying temperature is 90° C. to 120° C., and the drying time is 2 hours to 4 hours.

Embodiment 2

[0017] Embodiment 2: the potassium humate is obtained by the following preparation method: the first step, the t-butyl peroxyneodecanoate waste liquid is separated, and the aqueous phase solution is obtained after the separation; the second step takes the water by weight parts Phase solution 100 or 160 parts, weathered coal powder 80 or 120 parts, deionized water 110 parts or 200 parts, the required amount of aqueous phase solution, weathered coal powder and deionized water are mixed uniformly to obtain a mixed solution; The third step is to heat the mixed solution to 80°C or 100°C for reaction, test the pH value of the mixed solution during the reaction, and obtain a dark brown paste after the reaction, the fourth step is to dry the dark brown paste The dried potassium humate is obtained, wherein: the reaction time is 40 minutes or 90 minutes, the pH value at the end of the reaction is 9 to 11, the drying temperature is 90° C. or 120° C., and the drying time is 2 hours or 4 ...

Embodiment 3

[0018] Embodiment 3: As the optimization of above-mentioned embodiment, contain the potassium hydroxide that massfraction is 10% to 15% and the tert-butyl peroxide that massfraction is 3% to 5% in peroxyneodecanoate waste liquid potassium.

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Abstract

The invention relates to the technical field of recovery and utilization of tert-butyl peroxyneodecanoate waste liquid, and relates to potassium humate and a preparation method thereof. The potassium humate is obtained by the following method: in the first step, the tert-butyl peroxyneodecanoate waste liquid is separated, and the aqueous phase solution is obtained after separation; in the second step, the aqueous phase solution, weathered coal Powder and deionized water are mixed evenly to obtain a mixed solution; the third step is to heat the mixed solution to react, and a dark brown paste is obtained after the reaction; the fourth step is to dry the dark brown paste to obtain humic acid Potassium acid dry matter. In the present invention, potassium hydroxide and potassium tert-butyl peroxide in tert-butyl peroxyneodecanoate waste liquid are utilized to prepare potassium humate from humic acid in weathered coal, and tert-butyl peroxyneodecanoate is effectively utilized Potassium hydroxide and potassium tert-butyl peroxide in the ester waste liquid not only avoid the cost of tert-butyl neodecanoate waste liquid treatment, but also obtain potassium humate with economic benefits.

Description

technical field [0001] The invention relates to the technical field of recovery and utilization of tert-butyl peroxyneodecanoate waste liquid, and relates to potassium humate and a preparation method thereof. Background technique [0002] In the process of synthesizing PVC polymerization initiator tert-butyl peroxyneodecanoate, after extracting the oil phase product, the remaining water phase contains excess unreacted potassium hydroxide, tert-butyl potassium peroxide and by-product chlorine Potassium chloride, the remaining aqueous phase is collected as tert-butyl peroxyneodecanoate waste liquid at present and then sent to the sewage treatment station for centralized treatment, which not only increases the treatment cost, but also wastes the potassium resources that are in short supply in the market. Contents of the invention [0003] The invention provides a kind of potassium humate and preparation method thereof, overcomes the above-mentioned deficiencies in the pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08H99/00C07G99/00
Inventor 张惠斌刘海滨朱毅
Owner 乌鲁木齐市华泰隆化学助剂有限公司