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Method for improving appearance and color and enhancing various technical indicators of high-ammonia whole latex rubber

A technical index, high-ammonia full-emulsion technology, which is applied in the field of improving the appearance color of high-ammonia full-emulsion rubber and improving various technical indicators, and can solve the problem of high-ammonia natural rubber appearance color and consistency not being improved, plastic initial plasticity Problems such as low retention rate, easy pinching and stickiness, etc., achieve good consistency, increase plastic retention rate, and increase value

Active Publication Date: 2015-07-08
AGRI PRODS PROCESSING RES INST CHINESE ACAD OF TROPICAL AGRI SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Compared with the full latex (SCR WF) in the national standard GB / T8081-2008 / ISO 2000:2003 "Natural Raw Rubber Technology Graded Rubber (TSR) Specification Guidelines", this high ammonia rubber has an initial plasticity value (P 0 ), lower plastic retention rate (PRI), darker appearance, poor consistency, easy to get stuck and sticky, therefore, leading to a decline in grade
[0004] In view of this, for a long time there have been studies aimed at improving various indicators and properties of high-ammonia rubber. Fu Boqun and others increased the P of rubber by adding whey. 0 , PRI, but the appearance color and consistency of high ammonia natural rubber have not been improved [Tropical Agricultural Engineering 2004 (1): 31-34,]

Method used

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  • Method for improving appearance and color and enhancing various technical indicators of high-ammonia whole latex rubber
  • Method for improving appearance and color and enhancing various technical indicators of high-ammonia whole latex rubber
  • Method for improving appearance and color and enhancing various technical indicators of high-ammonia whole latex rubber

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] (1), 0.2g diammonium hydrogen phosphate is dissolved in deionized water, is made into the solution that concentration is 5%, then joins in 1000g high-ammonia latex and stirs evenly, leaves standstill for half an hour, makes the high-ammonia latex processed ;

[0040] (2), 1.5g sodium pyrosulfite is dissolved in deionized water, is made into the solution that concentration is 0.5%, joins in (1) made in the high ammonia latex that has been processed, stirs evenly, makes the high ammonia that has been processed again latex;

[0041] (3), use 3% formic acid solution or 5% acetic acid solution to coagulate the high ammonia latex processed again by (2), make high ammonia rubber clot;

[0042] (4) Dissolve 1.5g sodium pyrosulfite in deionized water, make a solution with a concentration of 0.5%, spray it on the high ammonia latex clot, ripening, tableting, and granulation obtained in (3), to obtain high ammonia rubber Wet gel particles;

[0043] (5), soak the high ammonia ru...

Embodiment 2

[0048] (1) Dissolve 0.4g of diammonium hydrogen phosphate in deionized water to make a solution with a concentration of 5%, then add it to 1000g of high ammonia latex, stir evenly, and leave it to stand for half an hour to obtain treated high ammonia latex;

[0049] (2), 0.5g sodium pyrosulfite is dissolved in deionized water, is made into the solution that concentration is 0.5%, joins in (1) made in the processed high ammonia latex, stirs evenly, makes the processed high ammonia latex again latex;

[0050] (3), use 3% formic acid solution or 5% acetic acid solution to coagulate the high ammonia latex processed again by (2), make high ammonia rubber clot;

[0051] (4) Dissolve 0.5g sodium pyrosulfite in deionized water, make a solution with a concentration of 0.5%, and spray it on (3) to obtain high ammonia latex curd, ripening, tableting, and granulation to obtain high ammonia rubber wet Gel particles;

[0052] (5), soak the high ammonia rubber wet gel particles obtained i...

Embodiment 3

[0056] (1) Dissolve 0.8g of diammonium hydrogen phosphate in deionized water to make a solution with a concentration of 5%, then add it to 1000g of high ammonia latex, stir evenly, and leave it to stand for half an hour to obtain treated high ammonia latex;

[0057] (2), 0.7g sodium pyrosulfite is dissolved in deionized water, is made into the solution that concentration is 0.5%, joins in (1) made in the high ammonia latex that has been processed, stirs evenly, makes the high ammonia that has processed again latex;

[0058] (3), use 3% formic acid solution or 5% acetic acid solution to coagulate the high ammonia latex processed again by (2), make high ammonia rubber clot;

[0059] (4) 0.7g sodium pyrosulfite is dissolved in deionized water, made into a solution with a concentration of 0.5%, sprayed on the high-ammonia latex clot, ripening, tableting, and granulating obtained in (3) to obtain high-ammonia rubber Wet gel particles;

[0060] (5), soak the high ammonia rubber w...

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Abstract

The invention discloses a method for improving appearance and color and enhancing various technical indicators of a high-ammonia (ammonia content is about 0.10%) whole latex rubber. The method comprises the following steps: firstly, using an additive (diammonium hydrogen phosphate) to process the high-ammonia whole latex rubber, standing, adding an antioxidant (sodium pyrosulfite) for antioxidation, solidifying, forming bubbles on the surface in pressing manner, spraying sodium pyrosulfite, and curing, performing tabletting, and prilling then, putting wet colloidal particles into a calcium carbonate solution for soaking, and finally drying and acquiring a standard whole latex rubber (SCRWF) with shallow color, excellent consistency and a capacity that various technical indicators meet the standard. The method effectively improves the phenomena that the high-ammonia whole latex rubber is dark in color, bad in consistency and low in various technical indicators, comprehensively increases the value of high-ammonia whole latex rubber, is simple and convenient for operation and low in cost, and fully possesses the prospect of industrialized popularization and application.

Description

[Field of invention] [0001] The invention relates to the technical field of primary processing of natural rubber, in particular to a method for improving the appearance color of high-ammonia full-emulsion rubber and improving various technical indicators. [Background technique] [0002] Natural fresh latex is the latex secreted by Hevea brasiliensis. This emulsion contains not only rubber hydrocarbons and water, but also a small amount of non-gum substances such as proteins, esters, organic acids and sugars. Under normal circumstances, the rubber particles in the latex are protected by an electric double layer formed by hydrophilic substances such as proteins and lipids, and the latex can maintain a stable colloidal state. If the fresh latex is polluted by microorganisms, or acid, inorganic salts , the protective layer of the latex is weakened or eliminated, making the latex lose its stability, thereby gelling or solidifying, and the solidified rubber block is then made into...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08C1/02C08C1/15
Inventor 黄红海王永周黄茂芳桂红星李普旺高天明张福全
Owner AGRI PRODS PROCESSING RES INST CHINESE ACAD OF TROPICAL AGRI SCI