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A kind of C5 hydrogenated petroleum resin raw material and its preparation method and application

A technology for hydrogenating petroleum resins and raw materials, applied in chemical instruments and methods, hydrocarbons, organic chemistry, etc., can solve problems such as difficulty in obtaining further optimization of physical and chemical properties, and achieve high industrial application value, structural optimization, and easy control. Effect

Active Publication Date: 2016-04-06
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] At present, the raw material of C5 hydrogenated petroleum resin is the material after ethylene cracking C5 to remove C4. Due to the fluctuation of the production and processing raw materials of the upstream ethylene plant, the fluctuation of the C5 composition of ethylene cracking makes it impossible for the C5 hydrogenated petroleum resin plant to realize that the components include three The adjustment and control of the proportion of diolefins and the proportion of active monodienes makes it difficult to further optimize the production process and the physicochemical properties of the products

Method used

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  • A kind of C5 hydrogenated petroleum resin raw material and its preparation method and application
  • A kind of C5 hydrogenated petroleum resin raw material and its preparation method and application
  • A kind of C5 hydrogenated petroleum resin raw material and its preparation method and application

Examples

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Effect test

Embodiment 1

[0048] according to figure 1 Shown flow process prepares C5 hydrogenated petroleum resin raw material, concrete steps are as follows:

[0049] (1) Lanzhou Petrochemical ethylene cracking C5 (see Table 1 for material composition) (flow rate: 400kg / hr) is sent to the de-C4 tower T101 to remove light hydrocarbon fractions below C4, and light hydrocarbon fractions below C4 are obtained at the top of the tower T101- OUT (see Table 1 for the composition of the material), the material R1-IN (see Table 1 for the composition of the material) obtained from the tower reactor to remove the light hydrocarbon fraction below C4, wherein the operating parameters in the tower are shown in Table 2;

[0050] (2) Send the material R1-IN obtained in step (1) to remove light hydrocarbon fractions below C4 into the dimerization reactor R1, and the material T102-IN after dimerization (see Table 1 for the material composition), wherein, the column Internal dimerization conditions are shown in Table 2...

Embodiment 2~3

[0057] The C5 hydrogenated petroleum resin raw material was prepared according to the method of Example 1, the difference is that the mixing ratio of the 5 stocks in step (7) has a certain change, as shown in Table 2, and the rest of the conditions are the same.

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Abstract

The invention relates to a C5 hydrogenated petroleum resin raw material, and a preparation method thereof. The method comprises the following steps: removing below C4 light hydrocarbon fractions in an ethylene cracking C5 product; dimerizing a below C4 light hydrocarbon fraction removed material; carrying out weight removal of a dimerized material to obtain an above C6 hydrocarbon fraction and a weight removed material; sending the weight removed material to a first rectifying tower for separation in order to obtain concentrated isoprene at the top of the tower and concentrated m-pentadiene at the bottom of the tower; sending the concentrated isoprene to a second rectifying tower for separation in order to obtain crude isoprene at the top of the tower and obtain a second rectification residue at the bottom of the tower; carrying out extracting separation of the most crude isoprene to obtain an extraction residue C5; and mixing the less crude isoprene, the concentrated m-pentadiene, the second rectification residue, the above C6 fraction and the extraction residue C5 mixture to obtain the C5 hydrogenated petroleum resin raw material. An apparatus realizes the optimization of the raw material based on the prior art, and the operation is stationary and controllable, so the product quality stability and controllability are guaranteed.

Description

technical field [0001] The present invention relates to a method for preparing C5 hydrogenated petroleum resin raw material and a C5 hydrogenated petroleum resin raw material prepared by the method of the present invention for preparing C5 hydrogenated petroleum resin raw material and its application in synthesizing C5 hydrogenated petroleum resin . Background technique [0002] Ethylene cracking C5 (usually referred to as C5 fraction) is a by-product of steam cracking ethylene production, generally about 10-20% by weight of ethylene production, usually containing alkanes, olefins, dienes, alkynes, etc. with 4-6 carbon atoms Dozens of components. Among them, isoprene, cyclopentadiene and piperylene are mostly contained, and their contents are respectively about 15-25% by weight, 12-15% by weight, and 14-20% by weight. 40 to 60% by weight of C5. Due to their special molecular structure and active chemical properties, these diolefins can be used to synthesize many important...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F240/00C08F8/04C07C11/18C07C7/177C07C7/08
Inventor 王琪曲云王春磊李勇刘鹏举徐海燕郭金彪
Owner PETROCHINA CO LTD