Novel diazonaphthoquinone sulfonate derivative
A technology of diazonaphthoquinone sulfonate and derivatives of pimaric acid imide, which is applied in the field of new diazonaphthoquinone sulfonate derivatives, and can solve problems such as poor contrast and development tolerance, and limit practical applications
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[0019] In the present invention, the parent compound N-hydroxymaleopimaric acid imide used can be prepared by the method described in our previous patent application (N-hydroxymaleopimaric acid imide sulfonate photoacid generator And its synthesis method, ZL: 200410039318.7), firstly obtained by reacting rosin with maleic anhydride and then reacting with hydroxylamine. Its structural formula is as follows:
[0020]
[0021] In the method of the present invention, the diazonaphthoquinone sulfonyl chloride used includes 2,1,4-diazonaphthoquinone sulfonyl chloride, 2,1,5-diazonaphthoquinone sulfonyl chloride or 2,1,6-diazonaphthalene sulfonyl chloride Quinone sulfonyl chloride. In terms of low price and easy availability, 2,1,4-diazonaphthoquinone sulfonyl chloride and 2,1,5-diazonaphthoquinone sulfonyl chloride are preferred, both of which are industrial products. Since 2,1,4-diazonaphthoquinone sulfonate has certain characteristics of generating acid after light exposure, which i...
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