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Resin composition, pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, pressure-sensitive adhesive sheet, and surface protective film

A technology of resin composition and pressure-sensitive adhesive, applied in the fields of pressure-sensitive adhesive sheet and surface protection film, pressure-sensitive adhesive layer, and pressure-sensitive adhesive composition, can solve the problem of producing adhesive residue, thickness variation, and pressure-sensitive adhesive properties. adverse effects, etc.

Active Publication Date: 2014-02-12
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, a pressure-sensitive adhesive sheet or surface protective film using an acrylic resin in the pressure-sensitive adhesive layer has poor wettability, so when the pressure-sensitive adhesive sheet or surface protective film is adhered by hand, there is a problem between the adherend and the sheet. or trap air bubbles between membranes
In addition, when an acrylic resin is used in a pressure-sensitive adhesive layer, there is a problem that adhesive residue is easily generated at the time of peeling, so that when a pressure-sensitive adhesive sheet or a surface protective film is used to protect a member in which the introduction of foreign matter is not particularly desired Problems such as the surface of optical components or electronic components
Therefore, in the formation of the pressure-sensitive adhesive layer, the surface of the pressure-sensitive adhesive layer becomes rough or its thickness varies, and in addition, the pressure-sensitive adhesive properties of the formed pressure-sensitive adhesive layer are also adversely affected

Method used

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  • Resin composition, pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, pressure-sensitive adhesive sheet, and surface protective film
  • Resin composition, pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, pressure-sensitive adhesive sheet, and surface protective film
  • Resin composition, pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, pressure-sensitive adhesive sheet, and surface protective film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0112] To the polyol (A) 70 parts by weight of a polyol having two OH groups and a number average molecular weight Mn of 5500 (manufactured by ASAHI GLASS CO., LTD., PREMINOL S4006), 18 parts by weight of a polyol having three A polyhydric alcohol having four OH groups and a number average molecular weight Mn of 1500 (manufactured by Sanyo Chemical Industries, Ltd., SANNIX GP-1500) and 12 parts by weight of a polyhydric alcohol having four OH groups and a number average molecular weight Mn of 1100 To alcohol (manufactured by ADEKA CORPORATION, EDP-1100), 40 parts by weight of trimethylolpropane / toluene diisocyanate trimer adduct (manufactured by Japan Nippon Polyurethane Industry Co., Ltd. (manufactured by Nippon Polyurethane Industry Co., Ltd., trade name: CORONATE L), 0.04 parts by weight of tris(acetylacetonate)iron as a catalyst (C) (provided by Nippon Chemical Industry Co., Ltd. (NIHON KAGAKU SANGYO CO., LTD.), trade name: Nacem Ferric Iron) and 0.0061 parts by weight of ...

Embodiment 2

[0116] Resin composition (2) was obtained in the same manner as in Example 1 except that the amount of acetylacetone (AcAc) used was changed to 0.0029 parts by weight.

[0117] The obtained resin composition (2) was defined as the pressure-sensitive adhesive composition (2) and various evaluations were performed on the resin composition (2) or the pressure-sensitive adhesive composition (2).

[0118] Tables 1 and 2 show the results.

Embodiment 3

[0120] Resin composition (3) was obtained in the same manner as in Example 1 except that the amount of acetylacetone (AcAc) used was changed to 0.0012 parts by weight.

[0121] The obtained resin composition (3) was defined as a pressure-sensitive adhesive composition (3) and various evaluations were performed on the resin composition (3) or the pressure-sensitive adhesive composition (3).

[0122] Tables 1 and 2 show the results.

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Abstract

Provided is a resin composition that can serve as a pressure-sensitive adhesive composition that is a material for forming a pressure-sensitive adhesive layer containing a polyurethane-based resin, the resin composition having a sufficiently long pot life in a stage where the resin composition is stored as it is, while allowing a cross-linking reaction between a polyol and a polyfunctional isocyanate compound to rapidly progress upon formation of a pressure-sensitive adhesive layer through the use of a pressure-sensitive adhesive composition containing the resin composition. Also provided is a pressure-sensitive adhesive composition formed of such resin composition. Also provided is a pressure-sensitive adhesive layer formed through the use of such pressure-sensitive adhesive composition. Also provided are a pressure-sensitive adhesive sheet and a surface protective film each including such pressure-sensitive adhesive layer. The resin composition includes: a polyol (A) having at least two OH groups; a polyfunctional isocyanate compound (B); a catalyst (C); and a compound (D) that undergoes keto-enol tautomerization, in which: a content ratio of the polyfunctional isocyanate compound (B) with respect to 100 parts by weight of the polyol (A) is 1 part by weight to 100 parts by weight; and the catalyst (C) includes an iron-based compound containing iron as an active center thereof.

Description

technical field [0001] The present invention relates to a resin composition having excellent pot life. The present invention also relates to pressure-sensitive adhesive compositions containing such resin compositions. The present invention also relates to a pressure-sensitive adhesive layer formed by using such a pressure-sensitive adhesive composition. The present invention also relates to a pressure-sensitive adhesive sheet and a surface protective film each comprising such a pressure-sensitive adhesive layer. Background technique [0002] Optical members and electronic members such as LCDs, organic EL displays, touch panels using such displays, lens portions of cameras, and electronic devices may each have a pressure-sensitive adhesive sheet or a surface protective film usually adhered to its exposed surface side , to prevent, for example, flaws on its surface during processing, assembly, inspection, transportation, etc. Such a pressure-sensitive adhesive sheet or surf...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/76C08G18/75C08G18/73C08G18/48C08G18/42C08G18/44C08G18/36C08G18/22C09J175/08C09J175/06C09J175/04C09J7/02C09J7/38
CPCC09J7/0207C08G18/4825C09J175/08C08G18/222C08G18/794C08K5/07C08G18/8029C08G18/792C08G18/4816C08G18/4829C09J2475/00C09J7/38C08G2170/40C08K5/0091Y10T428/2896C09J7/22C08L75/04C09J175/04C09J2203/00
Inventor 伊关亮佐佐木翔悟徐创矢安藤雅彦
Owner NITTO DENKO CORP
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