The invention provides an iron and steel normal temperature rapid blackening solution. The blackening solution comprises the following components in the following contents: 3-12 g/L of copper sulfate pentahydrate, 1.5-3.5 g/L of chromium oxide, 5-15 g/L of ammonium chloride, 3-10 g/L of citric acid, 1-10 g/L of octaphenyl polyoxyethyiene, 0.2-0.5 g/L of ammonium citrate, 5-10 g/L of sodium thiosulfate, 0.73-0.76 g/L of sulfuric acid, 0.6-0.8 g/L of boric acid and the balance of water. The iron and steel normal temperature rapid blackening solution has the advantages of stable solution, short blackening time, proper color, convenient and simple used process, sufficient raw material, low cost and the like, and particularly, the adhesion and the corrosion resistance capacity of a blackening film layer are obviously improved. The blackening solution has the characteristics of no pollution, energy saving, no steel type selectivity and the like.