The invention discloses a preparation method of a low-pressure polymer decolorization nanofiltration membrane, which comprises the following steps: S1, taking a polymer, a copolymer, a porogen and a solvent, mixing it with a solvent to form a polymer solution, coating it on the surface of a nonwoven fabric, and forming a polymer solution. Washing to remove the solvent and porogen to obtain the blended polymer ultrafiltration membrane; S2, coating the surface of the blended polymer ultrafiltration membrane obtained in S1 with a polyamine solution for cross-linking reaction to form a nanofiltration separation layer; S3, applying S2 The obtained ultrafiltration membrane is obtained by heat treatment; the product and application thereof are also disclosed. The low-pressure polymer decolorization nanofiltration membrane of the present invention is resistant to oxidation, thin in thickness, does not fall off during use, and can efficiently separate multivalent ions and colored soluble organic substances. The membrane has good hydrophilicity, pollution resistance and permeation flux; In addition, the preparation method of the nanofiltration membrane has a simple process, can be produced in a large scale, and has good industrial application prospects.