Graphene-containing marine anticorrosion antifouling coating and preparation method thereof

A marine anti-corrosion and graphene technology, applied in anti-corrosion coatings, anti-fouling/underwater coatings, epoxy resin coatings, etc., can solve problems such as poor comprehensive performance and high environmental risks, and achieve low cost, simple process equipment, high The effect of anti-corrosion properties

Inactive Publication Date: 2014-02-19
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these two types of coatings have the disadvantages o

Method used

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  • Graphene-containing marine anticorrosion antifouling coating and preparation method thereof
  • Graphene-containing marine anticorrosion antifouling coating and preparation method thereof
  • Graphene-containing marine anticorrosion antifouling coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach 1

[0041] Step 1: Hydroxylation of graphene surface

[0042] Utilize 98wt% concentrated sulfuric acid and 65wt% concentrated nitric acid, press Prepare aqua regia according to the ratio; then press m:V 王水 =1g:600mL scale (measure) to take graphene and aqua regia. The weighed graphene was dispersed in aqua regia and ultrasonically treated in a water bath for 30 minutes. Then the system was heated and stirred in a water bath at 60°C for 6 hours, and the graphene was washed with distilled water until neutral, dried in an oven at 60°C, and ground.

[0043] Step 2: Coupling of Graphene

[0044] The graphene obtained in step 1 and KH602 (N-β-(aminoethyl)-γ-aminopropylmethyldimethoxysilane), according to m 石墨烯 :m KH-602 The mass ratio of =1mg:3mg is dissolved in a small amount of deionized water, stirred evenly, and ultrasonically dispersed for 30min. Thereafter, it was heated and stirred with a magnetic stirrer at 60°C for 8 hours, and the modified graphene was separated by cent...

experiment approach 2

[0052] Step 1: Hydroxylation of graphene surface

[0053] Using 98% concentrated sulfuric acid and 65% concentrated nitric acid, press Prepare aqua regia according to the ratio; then press m:V 王水 =1g:610mL scale (measure) to take graphene and aqua regia. The weighed graphene was dispersed in aqua regia and ultrasonically treated in a water bath for 30 minutes. Then the system was heated and stirred in a water bath at 60°C for 6 hours, and the graphene was washed with distilled water until neutral, dried in an oven at 60°C, and ground.

[0054] Step 2: Coupling of Graphene

[0055] The graphene obtained in step 1 and KH602 (N-β-(aminoethyl)-γ-aminopropylmethyldimethoxysilane), according to m 石墨烯 :m KH-602The mass ratio of =1mg:4mg is dissolved in a small amount of deionized water, stirred evenly, and ultrasonically dispersed for 30min. Thereafter, it was heated and stirred with a magnetic stirrer at 60°C for 9 hours, and the modified graphene was separated by centrifugat...

experiment approach 3

[0063] Step 1: Hydroxylation of graphene surface

[0064] Using 98% concentrated sulfuric acid and 65% concentrated nitric acid, press Prepare aqua regia according to the ratio; then press m:V 王水 =1g:620mL scale (measure) to take graphene and aqua regia. The weighed graphene was dispersed in aqua regia and ultrasonically treated in a water bath for 30 minutes. Then the system was heated and stirred in a water bath at 60°C for 6 hours, and the graphene was washed with distilled water until neutral, dried in an oven at 60°C, and ground.

[0065] Step 2: Coupling of Graphene

[0066] The graphene obtained in step 1 and KH602 (N-β-(aminoethyl)-γ-aminopropylmethyldimethoxysilane), according to m 石墨烯 :m KH-602 The mass ratio of =1mg:4mg is dissolved in a small amount of deionized water, stirred evenly, and ultrasonically dispersed for 30min. Thereafter, it was heated and stirred with a magnetic stirrer at 60°C for 10 hours, and the modified graphene was separated by centrifug...

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Abstract

The invention discloses a graphene-containing marine anticorrosion antifouling coating and a preparation method thereof. Graphene having an antibacterial function is used as a filling material and is added into epoxy resin by surface modification, and the nano composite antifouling coating having antibacterial and anticorrosion properties is prepared. The graphene is added into the epoxy resin to form the marine antifouling coating; the excellent characteristics of the two materials are fully combined, so the coating has both the antifouling characteristic and the anticorrosion characteristic, that is to say, graphene and the epoxy resin are composited, so the antibacterial property of graphene and the anticorrosion property of the epoxy resin are organically combined jointly, and thus the novel antifouling coating having both the anticorrosion property and the antifouling property is developed.

Description

technical field [0001] The invention relates to an antifouling paint for marine metal components and a preparation method thereof, more specifically, to a graphene-containing marine antifouling paint and a preparation method thereof. Background technique [0002] Biofouling is a major problem that has plagued the development of the marine shipbuilding industry for a long time; the research results show that marine fouling caused by marine organisms on the surface of the ship will increase the roughness of the hull surface, reduce the speed of the ship, increase fuel consumption, and will contribute to the future development of the hull. Pollution and cleaning cause a lot of capital and manpower consumption. According to statistics, biofouling will increase the fuel consumption of ships by 40%; in addition, the annual economic loss caused by corrosion in my country is at least 90 billion yuan, and marine corrosion accounts for more than 30%. It accounts for about 30% of the t...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D7/12C09D5/08C09D5/16
CPCC08K3/04C08K9/02C08K9/06C09D5/08C09D5/16C09D7/62C09D163/00
Inventor 岳鑫王慧慧王吉会
Owner TIANJIN UNIV
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