Substrate for solar cell and oxide semiconductor electrode for dye-sensitized solar cell
An oxide semiconductor, solar cell technology, applied in electrolytic capacitors, circuits, capacitors, etc., can solve the problems of conductive film wear, time and cost
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[0134] Hereinafter, the present invention will be described based on examples, but the present invention is not limited to these examples.
[0135] First, a first aspect of the present invention will be described based on an embodiment.
[0136] First, a glass substrate (100 mm×100 mm) having the composition, thickness, thermal expansion coefficient, and strain point described in Table 1 was prepared. In addition, the thermal expansion coefficient is a value measured using a dilatometer. In addition, the strain point is a value measured by DTA.
[0137] Then, an FTO film (film thickness: 1 μm) was formed as a conductive film on each glass substrate by thermal CVD at a film formation temperature of 510° C. using dimethyltin dichloride and trifluoroacetic acid.
[0138] After slowly cooling the obtained glass substrate with the conductive film, it was placed on a table, and the presence or absence of deformation was checked with a gap gauge. The state of the glass substrate h...
Embodiment 5~8 and comparative example 3、4)
[0147] On each of the glass substrates (120 mm×120 mm) described in Table 2, an FTO film as a conductive film was formed by thermal CVD. Specifically, using (CH 3 ) 2 SnCl 2 、CF 3 COOH was used as a raw material, and after they were vaporized once, they were sprayed onto a glass substrate heated to the film-forming temperature described in Table 2 to form a film to obtain a glass substrate having a conductive film. Film formation was performed after holding each glass substrate at the film formation temperature for 10 minutes. In addition, the film-forming time was adjusted in the range of 2 to 5 minutes so that the thickness of the FTO film was about 1 μm.
[0148] Each of the obtained glass substrates having a conductive film was slowly cooled, and the slow-cooled glass substrates with a conductive film were placed on a stage, and the presence or absence of deformation was checked with a gap gauge. The state of the glass substrate having the conductive film was evaluate...
Embodiment 9~13)
[0153] The glass substrates with the conductive film of Examples 5 and 6 were cut into a size of 15 mm×15 mm, and the titanium oxide paste was screen-printed on the conductive film using a 200-mesh screen. The Ti-Nanoxide T / SP (hereinafter referred to as T / SP, with an average particle size of 13nm) from Solaronix, which is translucent after firing and Ti-Nanoxide D / SP from the same company ( Hereinafter, it is called D / SP, and its average particle diameter is 13 nm (including some particles with an average particle diameter of 400 nm). Only to D / SP in embodiment 9 and 11, only to T / SP in embodiment 10 and 12, and in embodiment 13, carry out screen printing according to the order of T / SP, D / SP, use electric furnace in Baking at 500°C for 30 minutes.
[0154] Next, the transparent repair tape 810 was attached to the baked titanium oxide layer, and immediately peeled off after applying pressure with a rubber roller, thereby confirming the adhesiveness between the glass substrate...
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Abstract
Description
Claims
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