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A high light and low volatility polybutylene terephthalate composition and its preparation method and application

A polybutylene terephthalate and low-volatility technology, which is applied in the field of high-gloss and low-volatility polybutylene terephthalate composition and its preparation, can solve the problem of gas gas easily generated by PBT materials and the gloss of injection molded parts Brightness is not enough, affecting the mechanical properties of materials and other issues, to achieve excellent mechanical and processing properties, less volatile matter, and improve the effect of gloss

Active Publication Date: 2016-04-27
KINGFA SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, PBT still has shortcomings in some aspects, such as the glossiness of PBT injection molded parts is not bright enough, and it is easy to produce air marks, especially when preparing high-gloss products, the rejection rate is high
[0003] For a long time, without affecting the mechanical and processing properties of PBT materials, improving the glossiness of PBT materials and the output rate of high-gloss products has always been a difficult problem in the industry. Researchers have done a lot of work on high-gloss and low-volatility PBT materials and have achieved Some achievements have been achieved, such as patent CN102660109A adding a mesoporous material to absorb the gas generated during the processing of the material, which has achieved certain results in the preparation of high-gloss spray-free materials, but due to the high content of the mesoporous material, it will affect the mechanical properties of the material
Patent CN101580632A adds PMMA resin and special heat-resistant agent to PBT resin to improve the gloss and thermal stability of the material. The PBT material prepared by this method is easy to generate gas and is not suitable for preparing products with high gloss requirements.

Method used

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  • A high light and low volatility polybutylene terephthalate composition and its preparation method and application

Examples

Experimental program
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Effect test

Embodiment 1~16 and comparative example 1~6

[0053] According to the proportions in Table 1~2, mix the dried PBT resin, PET resin, gloss additives, black seeds and additives in a high-speed mixer for 1-2 minutes to obtain a premix, and add the premix to the twin-screw extruder The extruder (screw diameter: 35mm, length-to-diameter ratio L / D=36) is melt-extruded, glass fiber is side-fed, and the finished product is made by two-stage vacuum granulation. Among them, the temperature of each screw barrel of the twin-screw extruder (from the feed port to the machine head) is: 140°C, 220°C, 230°C, 240°C, 240°C, 220°C, the screw speed is 300 rpm, and the feeding amount 50kg / h. The product obtained above was dried in an oven at 120°C for 3-4 hours and then injected into a standard sample strip at a temperature of 250°C. The injection-molded standard strips were placed at 25°C and 50% relative humidity for 24 hours before testing performance. The performance test results are shown in Table 1-2.

[0054] Table 1 High-gloss and l...

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Abstract

The invention discloses a high-gloss and low-volatility polybutylene terephthalate composition and its preparation method and application, including components: 100 parts of PBT resin; 2-20 parts of PET resin; 0-20 parts of glass fiber; high-gloss 0.5~2 parts of auxiliary agent; 0.5~2 parts of black seed; 0.1~2 parts of auxiliary agent. Its preparation method is to mix PBT resin, PET resin, high-gloss additives, black seeds and additives in a high-speed mixer for 1-2 minutes to obtain a premix, and the premix is ​​melted and extruded by a twin-screw extruder, and the glass fiber Side feeding, using two-stage vacuum granulation to make finished products. The invention introduces a high-gloss additive into the polybutylene terephthalate composition, which can effectively improve the glossiness of the material and the output rate of high-gloss products without affecting the mechanical and processing properties of the composition. The obtained polybutylene terephthalate composition not only has high gloss, good fluidity and less volatile matter, but also has excellent mechanical and processing properties, and is suitable for high-gloss requirements products such as electronic appliances and car lamp decorative rings.

Description

technical field [0001] The invention relates to a polybutylene terephthalate composition, in particular to a high-light and low-volatility polybutylene terephthalate composition and a preparation method thereof. Background technique [0002] Polybutylene terephthalate (PBT) is a semi-crystalline engineering plastic with good mechanical properties, electrical properties, heat resistance and chemical resistance, etc. It is widely used in automobiles, electronics, electrical appliances and other industries. However, PBT still has shortcomings in some aspects, such as the glossiness of PBT injection molded parts is not bright enough, and it is easy to produce air marks, especially when preparing high-gloss products, the rejection rate is high. [0003] For a long time, without affecting the mechanical and processing properties of PBT materials, improving the glossiness of PBT materials and the output rate of high-gloss products has always been a difficult problem in the industry...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08K13/04C08K7/14C08K5/5419C08J3/22B29B9/06
Inventor 刘晓亮杨波丁正亚丁超罗忠富袁绍彦周英辉
Owner KINGFA SCI & TECH CO LTD
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