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High-performance engineering plastic/polyester type TPU (thermoplastic polyurethane) alloy material and preparation method thereof

A technology of engineering plastics and alloy materials, applied in the field of material science, can solve problems such as small melt index, restriction, and poor fluidity, and achieve the effects of improving fluidity, convenient operation, and simple process

Inactive Publication Date: 2014-05-28
GUIZHOU MATERIAL IND TECH INSTITUE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the use of long fiber reinforced technology can not only reduce the cost of materials, but also greatly improve the mechanical properties of materials and the phenomenon of "floating fibers"; but ordinary TPU has high viscosity, low melt index, poor fluidity and low hardness. , so that the preparation of long glass fiber reinforced TPU is limited

Method used

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  • High-performance engineering plastic/polyester type TPU (thermoplastic polyurethane) alloy material and preparation method thereof
  • High-performance engineering plastic/polyester type TPU (thermoplastic polyurethane) alloy material and preparation method thereof
  • High-performance engineering plastic/polyester type TPU (thermoplastic polyurethane) alloy material and preparation method thereof

Examples

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Embodiment 1

[0015] Embodiment 1 of the present invention: High-strength and high-toughness TPU and styrene-based composite material, calculated in parts by mass, including 25 parts of polyester TPU, 30 parts of long glass fiber, 45 parts of engineering plastics, and styrene-maleic anhydride copolymer 3 parts, 0.6 parts of fluidity aid, 1.2 parts of chain extender and 0.6 parts of antioxidant.

[0016] The grade of TPU is 2103-80AE, the melt flow rate is 25-55g / 10min (200℃ / 2.16Kg), and the Shore hardness (A) of TPU is 65-85;

[0017] The grade of glass fiber is 4501, with a diameter of 17 microns, Chongqing Compound International Company; the grade of styrene-maleic anhydride copolymer is SMA218; the grade of fluidity aid is ADP-1200; the grade of chain extender is ADR4300S; The grade of the oxygen agent is PUB350.

[0018] The preparation method of high-strength and high-toughness TPU and styrene-based composite material is to get each component according to the above-mentioned mass part...

Embodiment 2

[0021] Embodiment 2 of the present invention: High-strength and high-toughness TPU and styrene-based composite material, calculated in parts by mass, including 20 parts of polyester TPU, 40 parts of long glass fiber, 40 parts of styrene-based resin, styrene-maleic anhydride 4 parts of copolymer, 0.6 part of flow aid, 0.9 part of chain extender and 0.5 part of antioxidant.

[0022] The preparation method is the same as in Example 1.

Embodiment 3

[0023] Example 3 of the present invention: High-strength and high-toughness TPU and styrene-based composite material, calculated in parts by mass, including 18 parts of polyester TPU, 50 parts of long glass fiber, 32 parts of engineering plastics, and styrene-maleic anhydride copolymer 5 parts, 0.5 part of flow aid, 0.8 part of chain extender and 0.5 part of antioxidant.

[0024] The preparation method is the same as in Example 1.

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Abstract

The invention discloses a high-performance engineering plastic / polyester type TPU (thermoplastic polyurethane) alloy material comprising the following components in parts by mass: 15 to 25 parts of polyester type TPU, 30 to 60 parts of long glass fibers, 20 to 45 parts of engineering plastics, 3 to 6 parts of compatilizer, 0.4 to 0.6 part of fluidity aid, 0.8 to 1.2 parts of chain extender and 0.4 to 0.6 part of antioxidant. According to the alloy material disclosed by the invention, the fluidity of the engineering plastics (AS (acrylonitrile styrene), PS (polystyrene), ABS (acrylonitrile butadiene styrene), PC (polycarbonate), PBT (polybutylene terephthalate) or PMMA (polymethyl methacrylate)) is improved, and the problem that resin has low probability of infiltrating glass fibers is solved by adopting the high-fluidity polyester type TPU; the 'floating fiber' phenomenon of the glass fibers can be eliminated and the interfacial strength of the glass fibers and the resin can be improved by adding the fluidity modifier and the compatilizer; the defect of reduction of the molecular weight of the TPU in the processing process is overcome by adding the hydroxy-containing chain extender.

Description

technical field [0001] The invention relates to the field of material science, in particular to a polymer material and a preparation method thereof. Background technique [0002] The engineering plastics selected by the present invention are AS, PS, ABS, PC, PBT, PMMA, all of which have good rigidity. It is difficult for these materials to obtain high-strength and high-toughness composite materials. They are all modified by adding glass fiber reinforced grafts containing elastomers, but their toughness is not greatly improved. For example: AS or PC is added The notched impact strength of the glass fiber is not as good as that of the raw material. At present, the use of long fiber reinforced technology can not only reduce the cost of materials, but also greatly improve the mechanical properties of materials and the phenomenon of "floating fibers"; but ordinary TPU has high viscosity, low melt index, poor fluidity and low hardness. , so that the preparation of long glass fib...

Claims

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Application Information

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IPC IPC(8): C08L25/12C08L25/06C08L55/02C08L69/00C08L67/02C08L33/12C08L75/06C08L35/06C08L51/00C08K13/04C08K7/14C08K5/10C08K5/06
Inventor 张道海郭建兵瞿进吴斌秦舒浩
Owner GUIZHOU MATERIAL IND TECH INSTITUE
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