A kind of non-mercury catalyst for preparing vinyl chloride and its preparation method and application
A non-mercury catalyst, vinyl chloride technology, applied in chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., can solve environmental pollution, mercury resource exhaustion, poor wear resistance And other issues
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0026] Weigh 1.7279g of SnCl 2 2H 2 O and 0.3960 g of TiCl 4 Dissolve in 40mL of absolute ethanol, make a solution, reflux and stir at 78°C for 3h in a reflux stirring device, and then stand and age in a 30°C constant temperature water bath for 8h to obtain a composite metal oxide sol, which is divided into two times to obtain The composite metal oxide sol sprayed onto 20g of coconut shell activated carbon, and then after drying at 80°C for 12h and roasting at 300°C for 4h, the activated carbon carrier modified by composite metal oxide was obtained;
[0027] Take 1.2 mL of 16.7 mg / mL HAuCl 4 4H 2 O aqueous solution was added to 40 mL of deionized water, sprayed onto the composite metal oxide-modified activated carbon support twice, dried at 80 °C for 12 h, and calcined at 200 °C for 4 h to obtain a non-mercury catalyst.
Embodiment 2
[0029] Weigh 1.5359g of SnCl 2 2H 2 O and 0.7920 g of TiCl 4 Dissolve in 40mL of absolute ethanol, make a solution, reflux and stir at 78°C for 3h in a reflux stirring device, and then stand and age in a 30°C constant temperature water bath for 8h to obtain a composite metal oxide sol, which is divided into two times to obtain The composite metal oxide sol sprayed onto 20g of coconut shell activated carbon, and then after drying at 80°C for 12h and roasting at 300°C for 4h, the activated carbon carrier modified by composite metal oxide was obtained;
[0030] Take 1.2 mL of 16.7 mg / mL HAuCl 4 4H 2 O aqueous solution was added to 40 mL of deionized water, sprayed onto the composite metal oxide-modified activated carbon support twice, dried at 80 °C for 12 h, and calcined at 200 °C for 4 h to obtain a non-mercury catalyst.
Embodiment 3
[0032] Weigh 1.3439g of SnCl 2 2H 2 O and 1.1880 g of TiCl 4 Dissolve in 40mL of absolute ethanol, make a solution, reflux and stir at 78°C for 3h in a reflux stirring device, and then stand and age in a 30°C constant temperature water bath for 8h to obtain a composite metal oxide sol, which is divided into two times to obtain The composite metal oxide sol sprayed onto 20g of coconut shell activated carbon, and then after drying at 80°C for 12h and roasting at 300°C for 4h, the activated carbon carrier modified by composite metal oxide was obtained;
[0033] Take 1.2 mL of 16.7 mg / mL HAuCl 4 4H 2 O aqueous solution was added to 40 mL of deionized water, sprayed onto the composite metal oxide-modified activated carbon support twice, dried at 80 °C for 12 h, and calcined at 200 °C for 4 h to obtain a non-mercury catalyst.
PUM
| Property | Measurement | Unit |
|---|---|---|
| specific surface area | aaaaa | aaaaa |
| specific surface area | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More