Ceramic Copper Circuit Board And Semiconductor Device Employing Same
A technology for circuit substrates and ceramic substrates, which is applied in semiconductor devices, semiconductor/solid-state device components, and improvement of metal adhesion on insulating substrates.
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Embodiment 1~11、 comparative example 1~9
[0045] As the ceramic substrate, a silicon nitride substrate with a thickness of 0.635mm (thermal conductivity: 90W / m·K, three-point bending strength: 730MPa) and an aluminum nitride substrate with a thickness of 0.635mm (thermal conductivity: 180W / m·K, three-point bending strength: 400MPa), an alumina substrate with a thickness of 0.635mm (thermal conductivity: 15W / m·K, three-point bending strength: 500MPa). The shape of the ceramic substrate is uniformly 50 mm long x 30 mm wide.
[0046] Next, the active metal solder material having the composition shown in Table 1 was prepared and pasted, and then coated on the ceramic substrate. The coating thickness of the active metal solder paste is shown in Table 1. Next, a copper plate (oxygen-free copper plate) having a thickness of 0.3 mm was prepared. The shape of the copper plates is uniformly 45 mm in length x 25 mm in width. In Examples 1 to 9, a copper plate having a thickness of 0.3 mm was used, and in Examples 10 to 11, a cop...
Embodiment 12~13
[0059] The ceramic copper circuit board of Example 9 was referred to as Example 12, and the ceramic copper circuit board obtained by changing the thickness of the copper plate of the ceramic copper circuit board of Example 9 to 0.5 mm was referred to as Example 13. For the ceramic copper circuit board of Example 12 and Example 13, under condition 2 (1 cycle: -40°C×30 minutes→room temperature (25°C)×10 minutes→175°C×30 minutes→room temperature (25°C)× 10 minutes) TCT was performed, and the number of cycles in which cracks occurred in the ceramic substrate was investigated. The results are shown in Table 4.
[0060] [Table 4]
[0061]
[0062] It can be seen from Table 4 that the ceramic copper circuit board of the example also has a durability of 6000 cycles or more for TCT with a maximum temperature exceeding 170°C.
Embodiment 14~18
[0064] The following substrate was prepared as a ceramic substrate. The ceramic substrate 1 is a silicon nitride substrate with a thickness of 0.320 mm (thermal conductivity: 93 W / m·K, three-point bending strength: 700 MPa). The ceramic substrate 2 is a silicon nitride substrate with a thickness of 0.320 mm (thermal conductivity: 100 W / m·K, three-point bending strength: 600 MPa). The ceramic substrate 3 is an aluminum nitride substrate having a thickness of 0.635 mm (thermal conductivity: 200 W / m·K, three-point bending strength: 320 MPa). The ceramic substrate 4 is an alumina substrate (thermal conductivity: 12 W / m·K, three-point bending strength: 400 MPa) with a plate thickness of 0.635 mm. In addition, the shape of the ceramic substrate is uniformly 50 mm in length × 30 mm in width.
[0065] Next, the active metal solder material of the composition shown in Table 5 was prepared and paste, and printed on the ceramic substrate and applied. A copper plate with a length of 45 mm...
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