Method for producing alpha olefins by oligomerization of ethylene
An ethylene oligomerization and olefin technology, applied in chemical instruments and methods, chemical recovery, hydrocarbons, etc., to achieve the effect of smooth polymer blockage and easy pressure control
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Embodiment 1
[0037] Such as figure 1 As shown, the technical process according to the present invention is as follows, taking ethylene trimerization to produce 1-hexene as an example, the material ethylene flow rate (200kg / h, polymerization grade, commercially available) in the reaction, solvent (380kg / h, heptane , commercially available) and a chromium-based catalyst (calculated as chromium, with a concentration of 0.5mol / L·Cr, commercially available), and the volume of the external container 9 is 0.5 cubic meters. After purging the closed reaction system with inert gas, replace it with ethylene for 2-3 times and dry it at 120°C for 3 hours, then feed ethylene to keep the pressure of the external container at 5.3MPa, and the flow of ethylene into the external container is 80kg / h (accounting for 40% of the total ethylene feed), and the solvent flow into the external container is 320kg / h (accounting for 84% of the total solvent consumption). Here, the external container adopts a cylindrical...
Embodiment 2
[0042] Same as Example 1, the difference is that the ethylene flow entering the external container is 20Kg / h (accounting for 10% of the total amount of ethylene feed, and the solvent flow is 190kg / h (accounting for 50% of the total solvent consumption), and the external The shape of the liquid distributor in the container is cylindrical, and its opening ratio is 85%.
[0043] According to this example, the catalyst activity is 350kg oligomerization product / (g·Cr·h), and the loop reactor has been operated continuously for 80 days without any abnormal fluctuations, maintaining stable production.
Embodiment 3
[0045] Same as embodiment 1, the difference is that the ethylene flow entering the external container is 100Kg / h (accounting for 50% of the total feed amount of ethylene), and the solvent flow is 342kg / h (accounting for 90% of the total solvent consumption), The shape of the liquid distributor in the external container is serpentine, and its opening ratio is 15%. The reaction temperature in the reactor was maintained at 110° C., and the reaction pressure was 5.0 MPa.
[0046] According to this example, the activity of the catalyst is 345kg oligomerization product / (g·Cr·h), the reaction system has been continuously and stably operated for 100 days, and there is no polymer blocking, abnormal pressure fluctuation, etc. in the loop reactor, and it remains stable Production.
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