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A kind of oil and gas well solid corrosion inhibitor and preparation method thereof

A corrosion inhibitor and technology for oil and gas wells, applied in chemical instruments and methods, earthwork drilling and production, wellbore/well components, etc., can solve the problems of high cost of dosing, negative impact on the environment, and large consumption of chemicals, and achieve significant Economic effect, increase crude oil gas volume, and reduce production cost

Active Publication Date: 2016-09-07
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the corrosion inhibitors currently used are organic corrosion inhibitors, and most of the organic corrosion inhibitors are liquid corrosion inhibitors. Liquid corrosion inhibitors have a series of advantages such as convenient use, easy preparation and compounding, etc., but in the process of use in oil and gas fields Some disadvantages are also exposed in the process: (1) filling requires equipment such as dosing pumps, which is inconvenient to use; (2) it is easy to adhere to the oil pipe wall, and the consumption of chemicals is large, causing unnecessary losses; (3) intermittent Injection dosing is uneven, and the effective protection time is short; (4) The effect of dosing is not good, and the cost of dosing is high; (4) Negative impact on the environment
Due to the lack of anti-corrosion effect of the above-mentioned dosing of liquid corrosion inhibitors and the complexity of its operation, it is necessary to research and develop solid corrosion inhibitors

Method used

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  • A kind of oil and gas well solid corrosion inhibitor and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0017] The long-acting solid corrosion inhibitor of the present invention is synthesized from the following raw materials in mass ratio: 47% of modified rosin, 15% of polyol, 32% of main agent, 3% of toughening agent and 3% of barium sulfate.

[0018] The main agent of the invention is polyoxyethylene naphthenic acid imidazoline, the modifying agent is polyvinyl alcohol, the polyhydric alcohol is glycerol, and the toughening agent is polyvinyl acetate.

[0019] The concrete preparation method of solid corrosion inhibitor of the present invention comprises the steps:

[0020] A. Synthesis of modified rosin: Put rosin in a stirring bottle, turn on the heater, and stir while heating. When the temperature reaches 250°C, add polyvinyl alcohol and keep stirring, keep the temperature for 2 hours, and turn off the heating after the reaction is completed. device, cooled to room temperature, that is, the modified rosin.

[0021] B. Preparation of long-acting solid corrosion inhibitor: ...

Embodiment 2

[0023] The long-acting solid corrosion inhibitor of the present invention is synthesized from the following raw materials in mass ratio: 48% of modified rosin, 16.5% of polyol, 33% of main agent, 1% of toughening agent and 1.5% of barium sulfate.

[0024] The main agent of the invention is polyoxyethylene naphthenic acid imidazoline, the modifying agent is polyvinyl alcohol, the polyhydric alcohol is pentaerythritol, and the toughening agent is polyvinyl acetate.

[0025] The concrete preparation method of long-acting solid corrosion inhibitor of the present invention comprises the following steps:

[0026] A. Synthesis of modified rosin: put rosin in a stirring bottle, turn on the heater, and stir while heating. When the temperature reaches 260°C, add polyvinyl alcohol and keep stirring, keep the temperature for 3 hours, and turn off the heating after the reaction is completed. device, cooled to room temperature, that is, the modified rosin.

[0027] B. Preparation of long-a...

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PUM

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Abstract

The invention relates to a solid corrosion inhibitor for an oil and gas well and a preparation method thereof. The solid corrosion inhibitor comprises, by mass, 47-50% of modified rosin, 15-16.5% of polyol, 31-35% of a main agent, 1-3% of a flexibilizer and 1.5-3% of barium sulfate. The preparation method comprises the following steps of modified rosin synthesis: adding rosin into a stirring bottle and adding a modifier into the rosin to obtain modified rosin; and solid corrosion inhibitor preparation: adding barium sulfate into the modified rosin, adding polyol into the mixture, adding the liquid main agent and the flexibilizer into the mixture, pouring the mixture into a mold, and carrying out cooling molding to obtain a cylindrical solid finished product. The solid corrosion inhibitor can be prepared by simple processes, is convenient for construction, resists a high temperature, has a high comprehensive corrosion inhibition rate and a long corrosion inhibition period, greatly prolongs a service life of the production device, reduces a production cost and improves work efficiency.

Description

technical field [0001] The invention relates to a solid corrosion inhibitor for oil and gas well anticorrosion and a preparation method thereof, in particular to a long-acting solid corrosion inhibitor for oil and gas well downhole equipment high temperature anticorrosion and a preparation method thereof. Background technique [0002] Most of the structures and pipeline equipment in various links of the petroleum industry are made of carbon steel and low-alloy steel. They are often corroded by air, seawater, soil and various components in petroleum. For this reason, it can be effectively and economically To achieve the purpose of corrosion control. Most of the corrosion inhibitors currently used are organic corrosion inhibitors, and most of the organic corrosion inhibitors are liquid corrosion inhibitors. Liquid corrosion inhibitors have a series of advantages such as convenient use, easy preparation and compounding, etc., but in the process of use in oil and gas fields Som...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/54C23F11/173
CPCC09K8/54C09K2208/32
Inventor 李强刘帮华王磊黄雪萍唐树全陈力群李晓芸韩东兴王轩高亮王霞王蕾王雅萍赵扬帆
Owner PETROCHINA CO LTD
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