Preparation method of in-situ synthesized aluminum-based composite bar

An aluminum matrix composite material, an in-situ self-generating technology, applied in the field of metal matrix composite materials, can solve the problems of shrinkage cavities, slow solidification of composite materials, shrinkage porosity, etc., and achieve the effect of overcoming poor quality, uniform distribution and dense organization

Active Publication Date: 2014-11-12
西安超晶科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

ZL200310122739.1 and ZL200510028209.X introduced the preparation of in situ self-generated aluminum matrix composites by mixed salt method, however, these methods only solved the problem of uniform distribution of reinforcement phase in the molten state of composite materials
Because the composite material in the molten state repells the reinforcement phase to the grain boundary during the crystallization process, the reinforcement phase is enriched and segregated, resulting in the inhomogeneity of the composite material, which greatly deteriorates the material properties.
Especially when large bars above Φ150mm are to be produced, due to the use of conventional casting molds such as sand sleeves, the solidification of the composite material in the molten state is very slow, and the uneven reinforcement phase in the composite material is very serious. Due to simultaneous solidification, defects such as shrinkage porosity and shrinkage cavities are easily formed in the center of the material, and the slag inclusions in the material are difficult to float out of the surface, and the quality of the ingot is difficult to control

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] ZL101 / TiB 2 Preparation of aluminum matrix composite bars

[0022] Step 1. Use mixed salt method to prepare TiB 2 Reinforced aluminum matrix composite ingot, the specific process is: according to ZL101 / TiB 2 Nominal chemical composition of aluminum matrix composites Al-7Si-0.3Mg-15TiB 2 Calculate the alloying element mass ratio of the aluminum matrix composite material, and calculate the KBF according to the calculated mass ratio. 4 and K 2 TiF 6 After mixing evenly, it is added to pure aluminum liquid, and the reaction generates TiB. 2 Reinforcing phase, and then add master alloy AlSi12A and pure Mg to pure aluminum liquid to obtain ZL101 / TiB 2 The liquid aluminum matrix composite material required by the composition. Pouring the liquid aluminum-based composite material into the sand sleeve to form a cuboid-shaped aluminum-based composite material ingot with a cross-section of 30mm×30mm;

[0023] In step 2, the aluminum-based composite material ingot is assembl...

Embodiment 2

[0027] ZL105 / TiB 2 Preparation of aluminum matrix composite bars

[0028] Step 1. Use mixed salt method to prepare TiB 2 Reinforced aluminum matrix composite ingot, the specific process is: according to ZL105 / TiB 2 Nominal chemical composition of aluminum matrix composites Al-5Si-1.25Cu-0.5Mg-10TiB 2 Calculate the alloying element mass ratio of the aluminum matrix composite material, according to the calculated mass ratio, the KBF will be 4 and K 2 TiF 6 After mixing evenly, it is added to pure aluminum liquid, and the reaction generates TiB. 2 Reinforcing phase, and then adding AlSi12A, AlCu50A master alloy and pure Mg to the pure aluminum liquid to obtain a liquid aluminum matrix composite material that meets the composition requirements. Pouring the liquid aluminum-based composite material into a metal mold to form a cuboid-shaped aluminum-based composite material ingot with a cross-section of 50mm×50mm;

[0029] In step 2, the aluminum-based composite material ingot...

Embodiment 3

[0033] ZL201 / TiB 2 Preparation of aluminum matrix composite bars

[0034] Step 1. Use mixed salt method to prepare TiB 2 Reinforced aluminum matrix composite ingot, the specific process is: according to ZL201 / TiB2 Nominal chemical composition of aluminum matrix composites Al-5Cu-0.8Mn-0.25Ti-10TiB 2 Calculate the alloying element mass ratio of the aluminum matrix composite material, and KBF will be used according to the calculated mass ratio 4 and K 2 TiF 6 After mixing evenly, it is added to pure aluminum liquid, and the reaction generates TiB. 2 Reinforcing phase, and then adding AlCu50A, AlMn10A, AlTi4BA master alloy to pure aluminum liquid to obtain a liquid aluminum matrix composite material that meets the composition requirements. Pouring the liquid aluminum-based composite material into the sand sleeve to form a cuboid-shaped aluminum-based composite material ingot with a cross-section of 100mm×100mm;

[0035] In step 2, the aluminum-based composite material ingot...

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Abstract

The invention discloses a preparation method of an in-situ synthesized aluminum-based composite bar. The preparation method comprises the steps of preparing TiB2 reinforced aluminum-based composite billet by adopting a mixed salts method; installing and welding the aluminum-based composite billet to form a consumable electrode with the cross section of Phi 150-500mm; then, smelting to obtain a vacuum consumable ingot of Phi 200-600mm; feeding the vacuum consumable ingot into a resistance furnace, heating, preserving the heat, and forging the vacuum consumable ingot to obtain the aluminum-based composite bar with the cross section of Phi 150-500mm. Through microscopic and macroscopic metallographic inspection, the aluminum-based composite bar prepared by using the preparation method is very uniform in TiB2 reinforced phase distribution and very compact in tissue; and through ultrasonic inspection, the bar has no inclusion defect and has the tensile strength of 415MPa and the rupture elongation of 2.5%.

Description

technical field [0001] The invention belongs to the technical field of metal matrix composite materials, and relates to a preparation method of a metal composite material, in particular to a preparation method of an in-situ self-generated aluminum matrix composite material bar. Background technique [0002] Materials used for key components in aerospace vehicles, space devices, space exploration and other systems are required to have comprehensive properties such as high specific strength, high specific modulus, high thermal conductivity, low thermal expansion, and high thermal deformation resistance. It is difficult for traditional single metal, polymer and ceramic materials to meet such high comprehensive performance requirements. The discontinuous reinforced aluminum matrix composite material composed of high-performance reinforcements (particles, whiskers, short fibers) and aluminum alloys, both It has the excellent properties of aluminum alloys, and can obtain the requi...

Claims

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Application Information

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IPC IPC(8): B21C37/04C22C1/02C22C21/00C22B9/20B22D7/06
Inventor 周中波林琳刘娣张利军薛祥义
Owner 西安超晶科技股份有限公司
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