Method utilizing melt salt activation to prepare active carbon

A technology for preparing activated carbon and molten salt, applied in the field of activated carbon preparation, can solve the problems of waste, prolonged activated carbon cycle, aggravated pollution, etc., and achieve the effects of improving production efficiency, reducing production cost, and reducing salt waste.

Active Publication Date: 2014-11-26
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to improve the quality of activated carbon, it is common to increase the amount of chemical reagents in the process of preparing activated carbon. The above methods will inevitably lead to increased costs and aggravated pollution.
In the actual preparation process of activated carbon, a large part of the chemical reagents is wasted due to high-temperature volatilization, and cannot actually participate in the activation process, resulting in low utilization of the activation reagents; another core problem: after the chemical reagents are mixed with raw materials and coke, it takes a certain amount of time. The time for the chemical reagents to fully immerse in the raw materials and coke, this process will lead to the extension of the cycle of activated carbon preparation, and increase the cost and efficiency of the preparation in a disguised form

Method used

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  • Method utilizing melt salt activation to prepare active carbon

Examples

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Effect test

Embodiment 1

[0021] Use industrial waste furfural slag as raw material: select 100g of furfural slag and crush it to 1mmg, dry it at 120°C until the quality is constant, put it in a heating furnace and pyrolyze it at a constant temperature of 400°C for 25min, put the coke produced by pyrolysis into the In molten salt at 400°C, take it out after constant temperature reaction for 2 minutes, and heat to 800°C under inert atmosphere for constant temperature activation at 600°C. Cool to room temperature, soak the obtained substance with 0.1mol / L hydrochloric acid solution, wash with water until neutral, and dry the obtained substance to be activated carbon.

Embodiment 2

[0023] Use agricultural waste corncobs as raw materials: choose 100g of corncobs and crush them to 1mm, dry them at 120°C until the quality is constant, put them in a heating furnace and pyrolyze them at a constant temperature of 350°C for 25min, put the coke produced by pyrolysis into the In molten salt at 400°C, take it out after constant temperature reaction for 2 minutes, and heat to 700°C under an inert atmosphere for constant temperature activation for 60 minutes. Cool to room temperature, soak the obtained substance with 0.1mol / L hydrochloric acid solution, wash with water until neutral, and dry the obtained substance to be activated carbon.

Embodiment 3

[0025] Coal as raw material: choose coal 100g crushed to 2mm, dry at 120°C until the quality is constant, put it in a heating furnace and pyrolyze it at a constant temperature of 500°C for 25 minutes, put the coke produced by pyrolysis into molten salt at 400°C , take out after constant temperature reaction for 2min, and heat to 900°C under inert atmosphere for constant temperature activation for 60min. Cool to room temperature, soak the obtained substance with 0.1mol / L hydrochloric acid solution, wash with water until neutral, and dry the obtained substance to be activated carbon.

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Abstract

The invention discloses a method utilizing melt salt activation to prepare active carbon. The method comprises the following steps: grinding and drying raw materials, placing the grinded and dried raw materials in a heating furnace, carrying out constant temperature pyrolysis under a certain temperature condition, adding the coke generated during the pyrolysis process into melt salts to carry out constant temperature reactions for a while, heating the coke in an inert gas atmosphere to a certain temperature, carrying out constant temperature activation at the temperature for a while, cooling the coke to the room temperature, soaking the coke in a hydrochloric acid solution with a certain concentration, washing the coke with water until the coke becomes neutral, and finally drying so as to obtain the active carbon. The preparation method can obtain high quality active carbon, utilizes the good permeability of melt salts at a high temperature to reduce the salt waste and volatilization in the preparation process and the pyrolysis process, shortens the preparation time, greatly reduces the production cost of active carbon, and promotes the technology innovation of active carbon production.

Description

technical field [0001] The invention belongs to the field of active carbon preparation, and relates to a method for preparing active carbon by activating molten salt. Background of the invention [0002] Activated carbon is a carbonaceous material with a large specific surface area and well-developed pores, and has excellent adsorption capacity. Adsorption, separation, purification and energy storage of phase and gas phase substances. [0003] There are many ways to prepare activated carbon, which are mainly divided into physical activation method, chemical activation method and physical chemical activation method according to the nature of the activator. The advantage of the physical activation method is that the process is simple, the preparation cost is low, the pollution to the environment is small, and no washing is required in the later stage. The disadvantage is that the activation temperature is high, the quality of the activated carbon is relatively low, and the ec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/12
Inventor 李爱民尹玉磊高宁博张雷
Owner DALIAN UNIV OF TECH
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