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Hollow microspheres based on methacryloxy cage silsesquioxane and its preparation method and application

A technology of methacryloyloxy cage and silsesquioxane, which is applied in the field of microspheres with hollow structure and its preparation, can solve the problems of narrow range of monomers of hollow structure microspheres, achieve mild experimental conditions, reduce The effect of simple use and operation process

Active Publication Date: 2016-08-24
GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Even so, the range of monomers used to prepare hollow structure microspheres is still relatively narrow, and no one has reported the use of cage silsesquioxanes in the preparation of hollow structure materials.

Method used

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  • Hollow microspheres based on methacryloxy cage silsesquioxane and its preparation method and application
  • Hollow microspheres based on methacryloxy cage silsesquioxane and its preparation method and application
  • Hollow microspheres based on methacryloxy cage silsesquioxane and its preparation method and application

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Embodiment 1: Preparation of hollow structural material based on MA-POSS

[0039] (1) prepare T 8 -MA-POSS content accounted for T 8 -10% T of the total content of MA-POSS and St 8 -MA-POSS Emulsion with Pickering effect.

[0040] (2) Preparation of hollow structural materials

[0041]The emulsion prepared in the above steps was dried in a freeze dryer at a freezing temperature of -55°C and a freezing time of 24 hours. A solid powder was obtained after freeze-drying. Configure a mixed solution with a volume ratio of acetone and cyclohexane of 3:7, and soak the obtained solid powder therein. After 12 hours, it was filtered, and the filtered product was naturally dried to obtain hollow microspheres based on methacryloxycage silsesquioxane in the form of solid powder.

[0042] (3) Dissolve 0.0004g of methylene blue in 20ml of water to obtain a blue liquid, prepare 2 samples, add 0.02g of the above-mentioned hollow microspheres based on methacryloxy cage silsesquioxan...

Embodiment 2

[0044] Embodiment 2: Preparation of hollow structure material based on MA-POSS

[0045] (1) prepare T 8 -MA-POSS content accounted for T 8 -10% T of the total content of MA-POSS and St 8 -MA-POSS Emulsion with Pickering effect.

[0046] (2) Preparation of hollow structural materials

[0047] The emulsion prepared in the above steps was dried in a freeze dryer at a freezing temperature of -55°C and a freezing time of 24 hours. A solid powder was obtained after freeze-drying. Prepare a mixed solution with a volume ratio of acetone and cyclohexane of 5:5, and soak the obtained solid powder therein. After 18 hours, it was filtered, and the filtered product was naturally dried to obtain hollow microspheres based on methacryloxycage silsesquioxane in the form of solid powder.

[0048] (3) Dissolve 0.0004g of methylene blue in 20ml of water to obtain a blue liquid, prepare 2 samples, add 0.02g of the above-mentioned hollow microspheres based on methacryloxy cage silsesquioxane ...

Embodiment 3

[0049] Embodiment 3: preparation of hollow structure material based on MA-POSS

[0050] (1) prepare T 8 -MA-POSS content accounted for T 8 -10% T of the total content of MA-POSS and St 8 -MA-POSS Emulsion with Pickering effect.

[0051] (2) Preparation of hollow structural materials

[0052] The emulsion prepared in the above steps was dried in a freeze dryer at a freezing temperature of -65°C and a freezing time of 24 hours. A solid powder was obtained after freeze-drying. Prepare a mixed solution with a volume ratio of acetone and cyclohexane of 7:3, and soak the obtained solid powder in it. After 24 hours, it was filtered, and the filtered product was naturally dried to obtain hollow microspheres based on methacryloxycage silsesquioxane in the form of solid powder.

[0053] (3) Dissolve 0.0004g of methylene blue in 20ml of water to obtain a blue liquid, prepare 2 samples, add 0.02g of the above-mentioned hollow microspheres based on methacryloxy cage silsesquioxane to...

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Abstract

The invention belongs to the technical field of organic-inorganic nano-hybrid materials, and discloses a hollow microsphere based on methacryloxy cage silsesquioxane, a preparation method and application thereof. The method comprises the following steps: preparing an emulsion with a Pickering effect stabilized by methacryloxy cage silsesquioxane, and drying; using a mixed solution of acetone and cyclohexane as an etchant, and performing the above-mentioned emulsion after drying Soaking is performed to remove the polystyrene core to obtain the product. The product has good adsorption performance and can be used in the field of sewage treatment. The operation process of the invention is relatively simple, the experimental conditions are mild, the selected raw materials and reagents are relatively easy to obtain, and the reaction yield is high.

Description

technical field [0001] The invention belongs to the technical field of organic-inorganic nano-hybrid materials, in particular to a microsphere with a hollow structure based on methacryloxy cage silsesquioxane (MA-POSS) and its preparation method and application. Background technique [0002] Cage silsesquioxane (POSS), also known as polyhedral cage silsesquioxane, is a general term for a class of silsesquioxanes with a lantern-like structure. According to the number of silicon atoms in POSS, they are also referred to as T for short. 8 -POSS([RSiO 1.5 ] 8 ), T 10 -POSS([RSiO 1.5 ] 10 ) and T 12 -POSS([RSiO 1.5 ] 12 ). The existing technology has synthesized high-yield, high-purity T 8 -MA-POSS and T 10 -MA-POSS, that is, methacryloxy cage silsesquioxane, and related articles are reported, such as articles by J.Peng et al. (J.Peng, K.Xu, H.L.Cai and J.C.Wu, RSC. Advances., 2014, 4, 7124-7131) and patent CN103214509A-cubic octamethacryloxypropyl silsesquioxane cryst...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/26B01J20/28B01J20/30C02F1/28C08F212/08C08F220/18C08F2/24
Inventor 许凯邢玉秀彭军林伟鸿陈鸣才
Owner GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI
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