Biaxially-oriented polypropylene anti-mist film with five-layer coextrusion and manufacturing method thereof

A biaxially stretched and copolymerized polypropylene technology, applied in chemical instruments and methods, layered products, synthetic resin layered products, etc. The effect of high printability, excellent anti-fog function, and excellent anti-fog effect

Inactive Publication Date: 2015-01-07
HAINAN SHINER IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing biaxially oriented polypropylene film with anti-fog function has a three-layer structure, which has the following disadvantages: (1) The anti-fog agent is blended with PP homopolymer or heat-sealing material and then extruded, and the anti-fog agent is completely separated out. It takes a certain amount of time, and it will take half a month to have a good effect. Therefore, it usually needs to be placed for half a month before it can be used to achieve a good anti-fog effect; (2) in the existing anti-fog film process formula , the effective content of the anti-fog agent is controlled within a small range, resulting in the persistence of the anti-fog effect is not long enough, often placed for 1 year, its anti-fog function will decline

Method used

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  • Biaxially-oriented polypropylene anti-mist film with five-layer coextrusion and manufacturing method thereof
  • Biaxially-oriented polypropylene anti-mist film with five-layer coextrusion and manufacturing method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0037] Ingredients: Produce a film with a thickness of 17 μm. The thickness of the upper layer is 0.8 μm, in which the content of copolymerized polypropylene is 97.5%, polyglycerol fatty acid ester is 1.5%, and synthetic silica is 1%; the thickness of the upper layer is 0.5 μm, and polyglycerin fatty acid ester is 100%; Polypropylene 99.5%, polyglycerin fatty acid ester 0.5%; the thickness of the next layer is 0.5μm, polyglycerol fatty acid ester 100%; the thickness of the lower layer is 0.8μm, wherein the content of copolymerized polypropylene is 97.5%, polyglycerol fatty acid ester 1.5% , Synthetic silica 1%.

[0038] Film making: The biaxially oriented polypropylene anti-fog film of the present invention is produced by co-extrusion biaxially stretching process, wherein the temperature of the upper layer extruder: 190°C, the temperature of the upper layer extruder: 220°C, and the temperature of the middle layer extruder : 230°C, next layer extruder temperature: 220°C, lower...

Embodiment 2

[0041] Ingredients: Produce a film with a thickness of 20 μm. The thickness of the upper layer is 0.8 μm, in which the content of copolymerized polypropylene is 96%, polyglycerin fatty acid ester is 3%, and synthetic silica is 1%; the thickness of the upper layer is 1 μm, and polyglycerin fatty acid ester is 100%; 97% propylene, 3% polyglycerol fatty acid ester; the thickness of the next layer is 1 μm, 100% polyglycerol fatty acid ester; the thickness of the lower layer is 1.2 μm, and the content of copolymerized polypropylene is 96%, 2% polyglycerol fatty acid ester, synthetic silica 2%.

[0042]Film making: The biaxially oriented polypropylene of the present invention is produced by co-extrusion biaxial stretching process, wherein the temperature of the upper layer extruder: 185°C, the temperature of the upper layer extruder: 210°C, and the temperature of the middle layer extruder: 230°C , the temperature of the next extruder: 210°C, the temperature of the lower extruder: 1...

Embodiment 3

[0045] Ingredients: Produce a film with a thickness of 22 μm. The thickness of the upper layer is 1.5 μm, and the content of copolymerized polypropylene is 97%, polyglycerol fatty acid ester is 2.0%, and synthetic silica is 1%. The thickness of the last layer is 1.5 μm, and polyglycerin fatty acid ester is 100%. Polypropylene 98%, polyglycerol fatty acid ester 2%; the next layer thickness 1.5μm, polyglycerol fatty acid ester 100%; lower layer thickness 1.5μm, in which the content of copolymerized polypropylene is 95%, polyglycerol fatty acid ester 3% , Synthetic silica 2%.

[0046] Film making: The biaxially oriented polypropylene anti-fog film of the present invention is produced by co-extrusion biaxially stretching process, wherein the temperature of the upper layer extruder: 200°C, the temperature of the upper layer extruder: 220°C, and the temperature of the middle layer extruder : 235°C, next layer extruder temperature: 220°C, lower layer extruder temperature: 200°C; cas...

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Abstract

The invention relates to a biaxially-oriented polypropylene anti-mist film with five-layer coextrusion and a manufacturing method thereof. The anti-mist film comprises an upper layer, an upper sublayer, a middle layer, a lower sublayer and a lower layer and is in a five-layer structure, wherein the upper layer is prepared from the following materials in percent by weight: 93-99% of co-polypropylene, 0.5-5% of anti-mist agent and 0.5-2% of anti-blocking agent; the upper sublayer is prepared from the following material in percent by weight: 100% of anti-mist agent; the middle layer is prepared from the following materials in percent by weight: 95-99.5% of homo-polypropylene and 0.5-5% of anti-mist agent; the lower sublayer is prepared from the following material in percent by weight: 100% of anti-mist agent; and the lower layer is prepared from the following materials in percent by weight: 92.5-98.5% of co-polypropylene, 0.5-5% of anti-mist agent and 1.0-2.5% of anti-blocking agent. The biaxially-oriented polypropylene anti-mist film not only has good transparency, heat-sealing strength and printing effect, but also has excellent and durable anti-mist property, so that the service life is effectively prolonged.

Description

technical field [0001] The invention relates to a five-layer co-extruded biaxially stretched polypropylene anti-fog film and a manufacturing method thereof, belonging to the field of polymer materials. Background technique [0002] Vegetables, fruits, meat and frozen food, because of their high water content or large temperature difference, usually tend to form a layer of opaque water mist in the packaging bag. This layer of opaque water mist will prevent consumers from seeing the product clearly. It is impossible to visually judge the quality status of the product. In order to solve this problem, the packaging is usually packaged with an anti-fog film that prevents water vapor from forming fog on the surface of the film. However, the existing biaxially oriented polypropylene film with anti-fog function has a three-layer structure, which has the following disadvantages: (1) The anti-fog agent is blended with PP homopolymer or heat-sealing material and then extruded, and the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/20B32B27/36B32B27/08B32B33/00
CPCB32B27/08B32B27/32B32B27/36B32B33/00B32B2250/05B32B2307/412B32B2307/54B32B2307/558B32B2439/70
Inventor 黎坛王俊峰
Owner HAINAN SHINER IND
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