Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A kind of polymer-based conductive elastomer and preparation method thereof

A technology of polymers and elastomers, applied in the field of designing conductive polymer composite materials, to achieve the effects of improved tensile strength, good elasticity and resilience, and improved elasticity and resilience.

Active Publication Date: 2017-07-11
SICHUAN UNIV
View PDF1 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The construction of such isolated structures with excellent interfacial interactions has not been reported so far

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of polymer-based conductive elastomer and preparation method thereof
  • A kind of polymer-based conductive elastomer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The vulcanizing agent uses 3 phr dicumyl peroxide (DCP), blended with ethylene octene copolymer (POE) for 1 min, statically vulcanized at 170°C and 10 MPa for 15 min, and cooled for 1 min. After being pulverized by a high-speed pulverizer with a rotating speed of 25000 rpm for 3 minutes, cross-linked particles with a particle size of 40-60 mesh (about 250-420 microns) are sieved with a sample sieve.

[0033] Under the condition of 150℃ and 50rpm, the POE and mass fraction are respectively 0, 2.5, 5, 7.5, 10, 12.5, 15, 17.5 in a torque rheometer (XSS-300, produced by Shanghai Light Machinery Mould Factory) The multi-walled carbon nanotubes (MWCNT) were blended for 5 minutes to obtain a masterbatch; then the crosslinked particles with a content of 75 wt.% were added, and the blending was continued for 5 minutes. After blending, hot press at 150° C. and 10 MPa for 5 minutes, and after cooling to prepare cross-linked particles / POE / MWCNT-A conductive elastomer.

Embodiment 2

[0035] The vulcanizing agent uses 3 phr dicumyl peroxide (DCP), blended with ethylene octene copolymer (POE) for 1 min, statically vulcanized at 170°C and 10 MPa for 15 min, and cooled for 1 min. After being pulverized by a high-speed pulverizer with a rotating speed of 25000 rpm for 3 minutes, cross-linked particles with a particle size of 40-60 mesh (about 250-420 microns) are sieved with a sample sieve.

[0036] Under the condition of 150℃ and 50rpm, the POE and mass fraction are respectively 0, 2.5, 5, 7.5, 10, 12.5, 15, 17.5 in a torque rheometer (XSS-300, produced by Shanghai Light Machinery Mould Factory) The multi-walled carbon nanotubes (MWCNT) were blended for 5 minutes to obtain a masterbatch; after that, the cross-linked particles with a content of 25 wt.% were added, and the blending was continued for 5 minutes. After blending, hot press at 150° C., 10 MPa for 5 minutes, and cool to obtain cross-linked particles / POE / MWCNT-B conductive elastomer.

Embodiment 3

[0038] The vulcanizing agent uses 3 phr dicumyl peroxide (DCP), blended with ethylene octene copolymer (POE) for 1 min, statically vulcanized at 170°C and 10 MPa for 15 min, and cooled for 1 min. After being pulverized by a high-speed pulverizer with a rotation speed of 25000 rpm for 3 minutes, cross-linked particles with a particle size of 20-40 mesh (about 420-850 microns) are sieved with a sample sieve.

[0039] Under the condition of 150℃ and 50rpm, the POE and mass fraction are respectively 0, 2.5, 5, 7.5, 10, 12.5, 15, 17.5 in a torque rheometer (XSS-300, produced by Shanghai Light Machinery Mould Factory) The multi-walled carbon nanotubes (MWCNT) are blended for 5 minutes to obtain a masterbatch; then the crosslinked particles with a content of 75 wt.% are added, and the blending is continued for 5 minutes. After blending, hot press at 150° C., 10 MPa for 5 min, and after cooling to prepare cross-linked particles / POE / MWCNT-C conductive elastomer.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
tensile strengthaaaaaaaaaa
Login to View More

Abstract

The invention discloses a polymer-based conductive elastomer and its preparation method. According to the preparation method, a certain percentage of a cross-linking agent is used to crosslink a polymer matrix and the cross-linked polymer matrix is crushed to obtain cross-linked particles; and the cross-linked particles are added in proportion into the matrix to prepare a cross-linked particles / elastic matrix / conductive carbon material composite elastomer. By the above method, conductive percolation threshold of the polymer-based conductive elastomer can effectively be reduced; stretching strength of the polymer-based conductive elastomer under the stretching action can be enhanced; and elasticity of the polymer-based conductive elastomer can effectively be raised, and strain recovery rate of the polymer-based conductive elastomer under strain retraction action can be raised. The polymer-based conductive elastomer prepared by the above method has advantages of good electrical property, enhanced stretching strength and good and stable elasticity and rebound resilience. The method provided by the invention has advantages of simple preparation technology, low cost, short production period and the like during the construction process.

Description

Technical field [0001] The invention relates to a new field of designing conductive polymer composite materials, in particular to a new method for introducing cross-linked particles into a polymer-based conductive elastomer to construct an isolation structure with excellent interface interaction. Background technique [0002] The conductive polymer composite material with isolation structure is composed of a polymer matrix, a well-dispersed isolation structure, and conductive fillers. Introducing an isolation structure into conductive polymer composites can greatly reduce the percolation value of conductive polymer composites. Therefore, in recent decades, conductive polymer composites with isolation structures have attracted more and more attention. Generally, polymers with higher viscosity are used to construct this isolation structure, such as ultra-high molecular weight polyethylene (UHMWPE), natural rubber (NR), and the like. Many scholars have studied the performance of co...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/08C08L23/16C08L61/06C08L9/02C08K5/14C08K7/24C08K3/04C08J3/22
CPCC08J3/226C08J2307/00C08J2323/08C08J2323/16C08J2407/00C08J2423/08C08J2423/16C08L7/00C08L23/0815C08L23/16C08L2203/20C08L2205/03C08K5/14C08K7/24C08L61/06C08K3/04
Inventor 杨伟李亭马丽凤亓国强包睿莹谢邦互杨鸣波
Owner SICHUAN UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products