Machine printing silica gel for pigment printing as well as preparation method and application thereof

A paint printing and silicone technology, applied in dyeing, textile and papermaking, etc., can solve problems such as unfavorable product promotion, slurry failure, screen blockage, etc. Good cover effect

Active Publication Date: 2015-04-01
GUANGZHOU HUMAN CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, at home and abroad, due to problems such as blockage of the screen plate and serious slurry failure in the process of using silicone gel, most of them are produced by manual treadmills, resulting in low production efficiency and poor stability of product batches. For today's rising labor costs and increasingly widespread mechanization, it will undoubtedly greatly hinder the use and promotion of silicone gel.
[0004] There are also relevant reports about the preparation of silica gel for printing at present. Chinese patent application CN101798391A reports a preparation method for preparing silica gel for textiles, but its base glue preparation process is cumbersome. Under 5 atmospheres, it takes 4 to 6 hours to process, which consumes time and energy; the treatment of white carbon black in Chinese patent application CN101550659A is the same as CN101798391A, which consumes time and energy; Chinese patent application CN103031748 prepares a condensation type silicone gel, and its curing process Generate a certain amount of waste and generate VOC
[0005] The printed silicone gel mentioned in the above-mentioned patent documents is not suitable for factory mechanization, and is not conducive to the promotion of industries with high production efficiency requirements. The plate is clogged, and the rubber material is quickly and easily (about 1 hour) dead, which leads to the failure of continuous production of the machine; 2. The product cannot meet the requirements of good screen performance and good ink return performance at the same time, making the screen printing process complicated and cumbersome. Time-consuming and labor-intensive, not conducive to product promotion

Method used

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  • Machine printing silica gel for pigment printing as well as preparation method and application thereof
  • Machine printing silica gel for pigment printing as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] Embodiment 1: Preparation of machine-printed silica gel for pigment printing

[0056] Preparation of Component A

[0057] Add 60 parts by mass of vinyl polysiloxane (Zhonghao Chenguang Chemical Research Institute Co., Ltd.) with a vinyl content of 0.8% and 5 parts by mass of white carbon black in the mixer MQ configuration (molecular weight 5000g / mol, vinyl content 5%) vinyl resin (Zhonghao Chenguang Chemical Research Institute Co., Ltd.) 10 parts by mass, hydrogen content is 0.8% hydrogen-containing siloxane (Zhejiang Xinan Chemical Industry Group Co., Ltd. Company) 1.5 parts by mass, cyclohexynol 5ppm, water 2 parts by mass, stirred and dispersed for 2 hours, vacuumed to 0.095mPa and kept for 1 hour, discharged and ground to obtain component A.

[0058] Preparation of Component B

[0059] In the blender, add 60 parts by mass of vinylpolysiloxane with a vinyl content of 0.8%, 5 parts by mass of white carbon black MQ configuration (molecular weight 4000g / mol, hydro...

Embodiment 2

[0061] Embodiment 2: Preparation of machine-printed silica gel for pigment printing

[0062] Preparation of Component A

[0063] Adding 60 parts by mass of vinyl polysiloxane with a vinyl content of 0.4%, and 10 parts by mass of white carbon black in the mixer MTQ configuration (vinyl content 3%, molecular weight 6000g / mol) vinyl MQ resin 10 parts by mass (Zhonghao Chenguang Chemical Research Institute Co., Ltd.), 10 parts by mass 2 parts by mass of hexamethyldisilazane, 1 part by mass of 0.8% hydrogen-containing siloxane, 20 ppm of cyclohexynol, and 1 part by mass of water were stirred and dispersed for 3 hours, and component A was obtained by discharging.

[0064] Preparation of Component B

[0065] Adding 60 parts by mass of vinyl polysiloxane with a vinyl content of 0.4%, and 10 parts by mass of white carbon black in the mixer MTQ configuration (hydrogen content 0.2%, molecular weight 3000g / mol) hydrogen-containing silicone resin 10 parts by mass (Zhonghao Chenguang ...

Embodiment 3

[0067] Embodiment 3: Preparation of machine-printed silica gel for pigment printing

[0068] Preparation of Component A

[0069] Adding 30 parts by mass of vinyl polysiloxane with a vinyl content of 0.2%, and 10 parts by mass of white carbon black in the mixer MTQ configuration (vinyl content 3%, molecular weight 6000g / mol) 5 parts by mass of vinyl MQ resin, 2.5 parts by mass of hexamethyldisilazane, 0.5 parts by mass of 0.8% hydrogen-containing siloxane, cyclohexynol After 10 ppm and 0.5 parts by mass of water, stir and disperse for 3 hours, and discharge to obtain Component A.

[0070] Preparation of Component B

[0071] 60 parts by mass of vinyl polysiloxane and 15 parts by mass of white carbon black with a vinyl content of 0.2% were added into the mixer After 10 ppm of Speier's catalyst, 2 parts by mass of ethyl orthosilicate, and 2 parts by mass of water, stir and disperse for 2 hours, and discharge to obtain component B.

[0072] Mix component A and component B to ...

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PUM

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Abstract

The invention belongs to the technical field of organic silicon, and discloses a machine printing silica gel, which can be used for performing continuous machine printing and is excellent in performance, for pigment printing, a preparation method of the machine printing silica gel and an application of the machine printing silica gel in the field of textile printing. The machine printing silica gel for pigment printing comprises unsaturated silicon oxide, a crosslinking agent containing silicon hydrogen bonds, silicon hydrogen addition catalyst and a reinforcing agent, wherein the reinforcing agent comprises an inorganic substance reinforcing agent and an organic substance reinforcing agent. A composite enhancing system is creatively used, so that the product silicone gel is surely good in network passing property and good in ink returning property; siloxane with a certain structure, MQ resin and hydrogen-containing organic substances are designed and used to ensure that the reaction temperature and operation time of the product have relatively wide ranges, glue dying mesh clogging is avoided after 4 hours of continuous machine printing, and the production efficiency is improved; and the preparation method disclosed by the invention is simple, environmentally friendly and energy-saving, and the obtained silica gel is stable in storage and excellent in performance, has advantages of less bubbles, easy leveling, good fastness, good slip resistance and the like, and can be widely applied to the field of textile printing.

Description

technical field [0001] The invention belongs to the technical field of organosilicon, and in particular relates to a machine-printed silica gel for pigment printing capable of continuous machine-printing and excellent performance, a preparation method thereof, and an application in the field of textile printing. Background technique [0002] Silicone gel is a kind of organic silicon product, which belongs to semi-inorganic material, and has excellent cold and heat resistance, corrosion resistance, weather resistance and so on. Addition-type liquid silicone rubber has a wide range of viscosity, fluidity of low-viscosity fluid and viscosity of high-viscosity fluid, and controllable vulcanization conditions, so it can effectively control the operation and construction conditions according to needs. Injection-in-situ molding and other fields have been widely used. [0003] At present, in the textile printing industry at home and abroad, printing coatings are generally thermoset...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P1/52D06P1/673D06P1/651D06P1/00
Inventor 张琴苏结平吴敏黎永铭王乐丰
Owner GUANGZHOU HUMAN CHEM
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