A kind of machine printing silica gel for pigment printing and its preparation method and application

A paint printing, silica gel technology, applied in dyeing, textile and papermaking, etc., can solve problems such as unfavorable product promotion, slurry failure, screen blockage, etc., to broaden application fields and use processes, extend product shelf life, and extend shelf life Effect

Active Publication Date: 2017-01-11
GUANGZHOU HUMAN CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, at home and abroad, due to problems such as blockage of the screen plate and serious slurry failure in the process of using silicone gel, most of them are produced by manual treadmills, resulting in low production efficiency and poor stability of product batches. For today's rising labor costs and increasingly widespread mechanization, it will undoubtedly greatly hinder the use and promotion of silicone gel.
[0004] There are also relevant reports about the preparation of silica gel for printing at present. Chinese patent application CN101798391A reports a preparation method for preparing silica gel for textiles, but its base glue preparation process is cumbersome. Under 5 atmospheres, it takes 4 to 6 hours to process, which consumes time and energy; the treatment of white carbon black in Chinese patent application CN101550659A is the same as CN101798391A, which consumes time and energy; Chinese patent application CN103031748 prepares a condensation type silicone gel, and its curing process Generate a certain amount of waste and generate VOC
[0005] The printed silicone gel mentioned in the above-mentioned patent documents is not suitable for factory mechanization, and is not conducive to the promotion of industries with high production efficiency requirements. The plate is clogged, and the rubber material is quickly and easily (about 1 hour) dead, which leads to the failure of continuous production of the machine; 2. The product cannot meet the requirements of good screen performance and good ink return performance at the same time, making the screen printing process complicated and cumbersome. Time-consuming and labor-intensive, not conducive to product promotion

Method used

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  • A kind of machine printing silica gel for pigment printing and its preparation method and application
  • A kind of machine printing silica gel for pigment printing and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] Example 1: Preparation of machine-printed silica gel for pigment printing

[0056] Preparation of component A

[0057] Add 60 parts by mass of vinyl polysiloxane (Zhonghao Chenguang Chemical Research Institute Co., Ltd.) with a vinyl content of 0.8% and 5 parts by mass of silica in the mixer. MQ configuration (molecular weight 5000g / mol, vinyl content 5%) vinyl resin (Zhonghao Chenguang Chemical Research Institute Co., Ltd.) 10 parts by mass, hydrogen-containing siloxane with a hydrogen content of 0.8% (Zhejiang Xin'an Chemical Group Co., Ltd. Company) 1.5 parts by mass, 5 ppm of cyclohexynol, 2 parts by mass of water, stirring and dispersing for 2 hours, vacuuming to 0.095 mPa and keeping it for 1 hour, discharging and grinding to obtain component A.

[0058] Preparation of component B

[0059] Add 60 parts by mass of vinyl polysiloxane with a vinyl content of 0.8% and 5 parts by mass of silica in the mixer. MQ configuration (molecular weight 4000g / mol, hydrogen content 0.8%...

Embodiment 2

[0061] Example 2: Preparation of machine-printed silica gel for pigment printing

[0062] Preparation of component A

[0063] Add 60 parts by mass of vinyl polysiloxane with a vinyl content of 0.4% and 10 parts by mass of silica into the mixer. MTQ configuration (vinyl content 3%, molecular weight 6000g / mol) vinyl MQ resin 10 parts by mass (Zhonghao Chenguang Chemical Research Institute Co., Ltd.), 10 parts by mass 2 parts by mass of hexamethyldisilazane, 1 part by mass of 0.8% hydrogen-containing siloxane, 20 ppm of cyclohexynol, 1 part by mass of water, stirred and dispersed for 3 hours, and discharged to obtain component A.

[0064] Preparation of component B

[0065] Add 60 parts by mass of vinyl polysiloxane with a vinyl content of 0.4% and 10 parts by mass of silica into the mixer. MTQ configuration (hydrogen content 0.2%, molecular weight 3000g / mol) hydrogen-containing silicone resin 10 mass parts (Zhonghao Chenguang Chemical Research Institute Co., Ltd.), Speier's catalyst 1...

Embodiment 3

[0067] Example 3: Preparation of machine-printed silica gel for pigment printing

[0068] Preparation of component A

[0069] Add 30 parts by mass of vinyl polysiloxane with a vinyl content of 0.2% and 10 parts by mass of silica in the mixer. MTQ configuration (vinyl content 3%, molecular weight 6000g / mol) 5 parts by mass of vinyl MQ resin, 2.5 parts by mass of hexamethyldisilazane, 0.5 parts by mass of 0.8% hydrogen-containing siloxane, cyclohexynol After 10 ppm, 0.5 parts by mass of water, stir and disperse for 3 hours, and discharge to obtain component A.

[0070] Preparation of component B

[0071] Add 60 parts by mass of vinyl polysiloxane with a vinyl content of 0.2% and 15 parts by mass of silica in the mixer. After 10 ppm of Speier's catalyst, 2 parts by mass of ethyl orthosilicate, and 2 parts by mass of water, the mixture was stirred and dispersed for 2 hours and discharged to obtain component B.

[0072] Mix component A and component B to obtain a machine-printed silica ge...

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Abstract

The invention belongs to the technical field of organosilicon, and discloses a continuous machine-printable, excellent-performance machine-printed silica gel for pigment printing, a preparation method thereof, and an application in the field of textile printing. The machine-printed silica gel for pigment printing includes unsaturated silicon oxide, a cross-linking agent containing silicon-hydrogen bonds, a catalyst for hydrosilylation and a reinforcing agent; the reinforcing agent includes an inorganic reinforcing agent and an organic reinforcing agent. agent. The invention creatively uses a composite reinforcement system, which not only ensures good net-passing property and good ink return performance of the product silica gel, but also designs and uses siloxane, MQ resin and hydrogen-containing organic matter with a certain configuration, so that the reaction temperature and operation time of the product have a certain With a wide range, it can achieve continuous machine printing for more than 4 hours without dead glue blocking the screen, which improves production efficiency; the preparation method of the present invention is simple, environmentally friendly and energy-saving, and the obtained silica gel is stable in storage and has excellent performance, with less air bubbles, easy leveling, fastness Good, anti-skid and other advantages, can be widely used in the field of textile printing.

Description

Technical field [0001] The invention belongs to the technical field of organic silicon, and in particular relates to a machine-printed silica gel for pigment printing with continuous machine printing and excellent performance, a preparation method thereof, and application in the textile printing field. Background technique [0002] Silicone gel is a kind of organic silicon product, which is a semi-inorganic material with excellent heat and cold resistance, corrosion resistance, weather resistance, etc. Because of the wide viscosity range, the fluidity of low-viscosity fluid, the viscosity of high-viscosity fluid, and the controllable characteristics of vulcanization conditions, the addition-molded liquid silicone rubber can effectively control the operation and construction conditions according to needs. Injection molding in-situ and other fields have been widely used. [0003] At present, in the textile printing industry at home and abroad, printing coatings are generally thermos...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P1/52D06P1/673D06P1/651D06P1/00
Inventor 张琴苏结平吴敏黎永铭王乐丰
Owner GUANGZHOU HUMAN CHEM
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