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The preparation method that is rich in papi polyurethane high resilience foam material

A foam material and high-resilience technology, which is applied in the field of preparation of PAPI-rich polyurethane high-resilience foam materials, can solve the problems of environmental and occupational health and safety impacts, poor tear strength, difficulty in reducing density, etc., and achieve soft and hard Reasonable segment distribution, high foaming ratio, good high resilience effect

Active Publication Date: 2017-11-03
ZHOUSHAN YINDAI AUTO PARTS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Traditional polyurethane high-resilience foam is mostly based on TDI, and its products have good mechanical properties, but the cost is high, and it has a certain impact on the environment and occupational health and safety.
Although MDI-based (PAPI)-based polyurethane high-resilience foam has cost advantages and contributes to the environment and occupational health and safety, it has a low expansion ratio, poor rebound, elongation, and tear strength, and it is difficult to reduce it. density, so its production method needs to be improved

Method used

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  • The preparation method that is rich in papi polyurethane high resilience foam material

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Embodiment Construction

[0011] Below in conjunction with embodiment the present invention is described in further detail.

[0012] The preparation method of the PAPI-rich polyurethane high-resilience foam material of the present embodiment comprises the following steps: stirring the A component and the B component respectively in a reaction kettle of a high-pressure foaming agent for at least 1 hour, and heating the foam mold to 50~70℃, and evenly spray the mold release agent on the inner wall of the foam mold, then mix and feed the components A and B into the mold by high pressure of the foaming machine according to the weight ratio of 100:50~70, and the mold is closed and matured for 3~ 8 minutes, then demoulding and trimming in turn to form the finished product; the proportion of component A is: polyether 330N: 33-60%, polymer polyol: 33-60%, silicone oil: 0.5-1.5%, Catalyst A33: 0.2-0.8%, Catalyst A-1: ​​0.2-0.8%, Diethanolamine as a cross-linking agent: 0.5-3.0%, Polyol additive DJ002: 3-10%, Wa...

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Abstract

The invention relates to a preparation method of a polyurethane high-resilience foam material rich in PAPI (polymethylene polyphenylisocyanate). The preparation method comprises the following steps: stirring a component A and a component B in a reaction kettle of a high-pressure foaming agent for at least one hour respectively, heating a foam mold to 50-70 DEG C, uniformly spraying a demolding agent on the inner wall of the foam mold, performing high-pressure mixing on the component A and the component B by the foaming machine according to the ratio in parts by weight of 100: (50-70), then pouring the obtained mixture into a mold, performing mold closing, curing for 3-8min, and then sequentially demolding and trimming to obtain a finished product. The preparation method provided by the invention has the advantages that a raw material containing multiple active hydrogens is taken as a starting agent, a polyol prepared by high-temperature polymerization reaction of propylene oxide (PO) and ethylene oxide (EO) is taken as a modifier, and the foaming reaction sequence of foam which is mainly based on an MDI (diphenylmethane diisocyanate) base (PAPI) is regulated, so that the foaming reaction is relatively balanced, the distribution of soft and hard sections is relatively reasonable, the prepared foam which is mainly based on the MDI base (PAPI) has great high resilience, high foaming rate, high extension rate and high tear strength; and more importantly, the foam material prepared by using the formula has good tactility.

Description

technical field [0001] The invention relates to the technical field of foam material production, in particular to a method for preparing a PAPI-rich polyurethane high-resilience foam material. Background technique [0002] Traditional polyurethane high-resilience foam is mainly based on TDI, and its products have good mechanical properties, but the cost is high, and it has a certain impact on the environment and occupational health and safety. Although MDI-based (PAPI)-based polyurethane high-resilience foam has cost advantages and contributes to the environment and occupational health and safety, it has a low expansion ratio, poor rebound, elongation, and tear strength, and it is difficult to reduce it. Densification, so its production method needs to be improved. Contents of the invention [0003] The technical problem to be solved by the present invention is to provide a method for preparing a PAPI-rich polyurethane high-resilience foam material with high expansion rat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/76C08G18/66C08G18/48C08G18/32C08J9/08C08G65/28C08G101/00
CPCC08G18/161C08G18/168C08G18/2063C08G18/3275C08G18/4072C08G18/4837C08G18/4883C08G18/5021C08G18/632C08G18/6688C08G18/7664C08G2110/0008C08G2110/0083
Inventor 夏瑞军陆备峰韩志峰朱军伟汤国均於汉辉
Owner ZHOUSHAN YINDAI AUTO PARTS
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