Transparent, flame-retardant, thermal-insulation and anti-ultraviolet polymer composite film as well as preparation method and application thereof

A high-molecular polymer and anti-ultraviolet technology, which can be used in other household appliances, chemical instruments and methods, applications, etc., can solve the problems of low transmittance of visible light, high processing and production costs, and no absorption in the infrared region.

Active Publication Date: 2015-04-29
BEIJING UNIV OF CHEM TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are multiple ultraviolet shielding materials on the market at present, but the existing ultraviolet shielding materials still have shortcomin

Method used

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  • Transparent, flame-retardant, thermal-insulation and anti-ultraviolet polymer composite film as well as preparation method and application thereof
  • Transparent, flame-retardant, thermal-insulation and anti-ultraviolet polymer composite film as well as preparation method and application thereof
  • Transparent, flame-retardant, thermal-insulation and anti-ultraviolet polymer composite film as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0081] (1) Nano magnesium hydroxide (Mg(OH) 2 ) nanoparticles dispersed in toluene to form 2 transparent dispersion; the above containing Mg (OH) 2 Mix the transparent dispersion liquid with PDMS and additives or a solution of a certain concentration to obtain a film-forming stock solution. Mg(OH) in this step 2 The mass ratio with PDMS is about 30:70.

[0082] Disperse nano indium tin oxide (ITO) into an appropriate amount of ethanol to form a transparent dispersion containing ITO; fully stir the above transparent dispersion containing ITO with polyvinyl butyral (PVB) and additives to obtain heat insulation function layer of film-forming stock solution. The mass ratio of each main component in this step is ITO:PVB:auxiliary agent=5:75:20.

[0083] Disperse the ZnO nanoparticles into an appropriate amount of ethanol to form a transparent dispersion containing the ZnO nanoparticles. Fully mixing the transparent dispersion liquid containing ZnO nanoparticles and polyvinyl ...

Embodiment 2

[0088] (1) 30 parts of nano-aluminum hydroxide (Al(OH) 3 ) dispersed in toluene to form Al(OH) 3 transparent dispersion. The above containing Al(OH) 3 Mix the transparent dispersion liquid with PDMS and an appropriate amount of additives to obtain a film-forming stock solution. Al(OH) in this step 3 The mass ratio with PDMS is about 30:70.

[0089] LaB 6 Nanoparticles were dispersed into an appropriate amount of ethanol to form a LaB-containing 6 Transparent dispersion of nanoparticles. will contain LaB 6 The transparent dispersion liquid of nanoparticles, polyvinyl butyral (PVB) and additives are evenly mixed to obtain the film-forming stock solution of the heat-insulating functional layer. The mass ratio of each main component in this step is LaB 6 :PVB:auxiliary=5:75:20.

[0090] Disperse ZnO nanoparticles into a certain amount of ethanol to form a transparent dispersion containing ZnO nanoparticles. The transparent dispersion liquid containing ZnO nanoparticles ...

Embodiment 3

[0095] (1) Mg(OH) 2 Nanoparticles dispersed in toluene to form Mg(OH)-containing 2 transparent dispersion; will contain Mg(OH) 2 The transparent dispersion liquid, polytrimethylene terephthalate and additives are uniformly mixed to obtain the film-forming film-forming stock solution of the flame-retardant functional layer. Mg(OH) in this step 2 The mass ratio with PDMS is about 40:60.

[0096] A mixture of ITO and ATO (ITO:ATO=w1:w2=1:1) was dispersed into a certain amount of ethanol to form a transparent dispersion containing ITO and ATO nanoparticles. Mix the transparent dispersion containing ITO and ATO nanoparticles with PVB and an appropriate amount of additives to obtain the film-forming stock solution of the heat-insulating functional layer. The mass ratio of each main component in this step is (ITO and ATO):PVB:auxiliary agent=5:75:20.

[0097] Disperse ZnO nanoparticles into a certain amount of ethanol to form a transparent dispersion containing ZnO nanoparticles...

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Abstract

Disclosed is a transparent, flame-retardant thermally-insulating, UV-blocking polymer composite film, comprising sequentially from the top: a flame retardant layer, a base layer, a thermal insulation layer, and a UV-blocking layer, having a total film thickness of 1um to 500um, visible light transmittance greater than 80%, UV light transmittance less than 1%, and near-infrared transmittance less than 10%. Also disclosed is a preparation method for the present transparent, flame retardant thermally-insulating, UV-blocking polymer composite film, the technical processes whereof are simple and easy to execute, involve low production costs, and are suitable for industrial mass production. The present transparent, flame retardant thermally-insulating, UV-blocking polymer composite film can be used on such transparent materials and items as glass, windows, protective films, containers and electronic components, and has applications in such fields as construction, transportation, electronics, aerospace and medicine.

Description

technical field [0001] The invention relates to the field of polymer-inorganic nanoparticle synthetic composite films, in particular to a transparent flame-retardant, heat-insulating and anti-ultraviolet polymer composite film and a preparation method thereof. Background technique [0002] In recent years, the Party Central Committee and the State Council have successively issued clear texts stating that the country consumes 20% of energy, and energy conservation has received unprecedented attention from the central government. With the successive promulgation of national energy-saving policies, energy-saving has set off an upsurge in the whole society. [0003] In this energy-saving upsurge, energy-saving glass film has become the biggest highlight of the new economic growth. Looking at the glass film market in China, whether it is the construction industry, the automobile industry, or IT products, the potential demand for glass film is amazing, so it is of great strategic...

Claims

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Application Information

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IPC IPC(8): B32B27/18B32B27/08B32B33/00C08J7/05
CPCB32B27/08B32B27/18B32B33/00B32B2307/3065B32B2307/304B32B2307/71B32B2307/412B32B2439/00B32B2457/00B05D5/00B05D7/50C08J7/042B05D2201/00B05D2252/10C08J2367/02C08J2429/14C08J2467/02C08J2483/04C08J7/0427C08J7/05B05D1/005B05D1/02
Inventor 陈建峰韩兴威曾晓飞王洁欣陈国术
Owner BEIJING UNIV OF CHEM TECH
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